• Title/Summary/Keyword: Electric conductivity

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Effect of Sintering Temperature on the Thermoelectric Properties of Bismuth Antimony Telluride Prepared by Spark Plasma Sintering (방전플라즈마 소결법으로 제조된 Bismuth Antimony Telluride의 소결온도에 따른 열전특성)

  • Lee, Kyoung-Seok;Seo, Sung-Ho;Jin, Sang-Hyun;Yoo, Bong-Young;Jeong, Young-Keun
    • Korean Journal of Materials Research
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    • v.22 no.6
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    • pp.280-284
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    • 2012
  • Bismuth antimony telluride (BiSbTe) thermoelectric materials were successfully prepared by a spark plasma sintering process. Crystalline BiSbTe ingots were crushed into small pieces and then attrition milled into fine powders of about 300 nm ~ 2${\mu}m$ size under argon gas. Spark plasma sintering was applied on the BiSbTe powders at 240, 320, and $380^{\circ}C$, respectively, under a pressure of 40 MPa in vacuum. The heating rate was $50^{\circ}C$/min and the holding time at the sintering temperature was 10 min. At all sintering temperatures, high density bulk BiSbTe was successfully obtained. The XRD patterns verify that all samples were well matched with the $Bi_{0.5}Sb_{1.5}Te_{3}$. Seebeck coefficient (S), electric conductivity (${\sigma}$) and thermal conductivity (k) were evaluated in a temperature range of $25{\sim}300^{\circ}C$. The thermoelectric properties of BiSbTe were evaluated by the thermoelectric figure of merit, ZT (ZT = $S^2{\sigma}T$/k). The grain size and electric conductivity of sintered BiSbTe increased as the sintering temperature increased but the thermal conductivity was similar at all sintering temperatures. Grain growth reduced the carrier concentration, because grain growth reduced the grain boundaries, which serve as acceptors. Meanwhile, the carrier mobility was greatly increased and the electric conductivity was also improved. Consequentially, the grains grew with increasing sintering temperature and the figure of merit was improved.

Effect of Carbonization Temperature on the Thermal Conductivity and Electric Properties of Carbonized Boards (탄화온도가 탄화보드의 열전도율 및 전기적 성질에 미치는 영향)

  • Oh, Seung-Won;Park, Sang-Bum;Kim, Jong-In;Hwang, Jung-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.1
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    • pp.58-63
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    • 2013
  • This study is a basic research for practical applications of carbonized boards, which measured thermal conductivity and electrical properties of carbonized boards manufactured at different carbonization temperature ($400{\sim}1,100^{\circ}C$) using a medium density fiberboard, particleboard, plywood and wood (Fraxinus rhynchophylla). The highest value of thermal conductivity was 0.1326 m/k at carbonization temperature of $900^{\circ}C$ in the carbonized particleboard. Overall, the higher density of carbonized board, thermal conductivity was faster. As the electrical resistivity decreased with increased carbonization temperature, it was almost close to conductor after carbonization temperature of $1,000^{\circ}C$. When electricity has worked on the carbonized board by high voltage, the current and the electric power increased and surface temperature of carbonized board was high.

Analysis on Wearing Characteristics of Main Wearing Slider for Pantograph According to Precipitation (강수의 영향에 따른 Pantograph 주습판의 마모특성 분석)

  • Kim, Kyung-Seob;Kim, Kwan-Soo;Cho, Kwan-Hyun
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.994-999
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    • 2011
  • The main wearing slider of pantograph is a difference which is considerable to wear phenomenon according to material properties. Especially, Cu-type wearing slider suddenly occurs the abnormal wear by precipitation, this threatens the travelling safety of the train. The abnormal wear by precipitation and arc influences are main factor decided to life time of Cu-type wearing slider and contact wire. Consequently, the application of the main wearing slider with wear resisting capacity, electrical conductivity, resistance arc and lubrication is demanded. In this paper through tribologic approach, overcame abnormal phenomenon of the Cu-type wearing slider by the precipitation and for the economic efficient augmentation by durability improvement and the travelling safety were accomplished. The Cu-type wearing slider which has excellent electric conductivity and arc characteristic but it occurs the normal and abnormal wear phenomenon according the precipitation which changes, respectively. Consequently, this phenomenon grasps fixed quantity according to precipitation, a mileage and wear volume then Fe-type wearing slider compared and analyzed.

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토양안정제에 의한 폐기물 매립장 차수재의 수리전도도 특성

  • 임은진;이재영;이복일
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.390-393
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    • 2002
  • Many researchers have studied for the barrier liner in the landfill that is mixed with clay mineral, native soils and solidified agent. However, they have a littel but problems for safety construction and maintenance as a bottom liner systems in the landfill. In this paper the authors studied the effects on hydraulic conductivity by electric-chemical ion-exchange agent that is a soil stabilization agent(Sulphonated Oil), The application of the soil stabilization agent to meet the hydraulic conductivity of clay liner in landfill is possible if the additive quantity and a proper reaction time is determined relevantly in the laboratory test.

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Synthesis and Electrical Properties of Polypyrrole Nanotubules (Polypyrrole Nanotubules의 합성과 전기적 특성)

  • 조영재;김현철;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.544-547
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    • 2000
  • Polypyrrole (PPy) was chemically synthesized within the pores of nanoporous polycarbonate (PC) Particle Track-etched Membranes (nano-PTM). Hollow tubules are formed because polypyrrole initially deposits on the surface of the pores walls. By running successive syntheses, we have obtained wires (filled tubules). The redox property of PPy nanotubules was investigated by cyclic voltammetry. The redox potential was lowered as much as 0.5V vs. Ag/AgC1, comparing with electrosynthesized PPy film. It suggests that an electron hopping mechanism of PPy nanotubules was improved. Electric conductivity of PPy nanotubules and nanowire was evaluated. We obtained good electric conductivity of PPy nanotubules even in the neutral state. The conductivity and activation energy were $10^1$ order at the room temperature and 25.3 meV respectively.

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A study on electric current variation characteristics during Electrokinetic remediation of kaolinite contaminated by Pb (납으로 오염된 카올린의 Electrokinetic 정화기법 적용시 전류변화 특성에 관한 연구)

  • 김정환;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.302-306
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    • 2000
  • In case of applying electrokinetic remediation, magnitude of electric current is one of major factors for estimation of contaminant transport. In practice, electric current provide determination of electric conductivity based on specimen resistance. Electric current variation is produced during Electrokinetic remediation test. Electric current is decreased by expotential function according to time in condition of constant voltage. This can be interpreted as precipitation effect by OH$^{-10}$ generation in a cathode.

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The Characteristics of Al Thin Films on Ar Plasma Surface Treatment (Al 박막의 Ar 플라즈마 표면처리에 따른 특성)

  • Park, Sung-Hyun;Ji, Seung-Han;Jeon, Seok-Hwan;Chu, Soon-Nam;Lee, Sang-Hoon;Lee, Neung-Hun
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1333-1334
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    • 2007
  • Al thin film was the most popular electrode in semiconductor and flat panel display world, because of its electrical conductivity, selectivity and easy to apply to thin film. However, Al thin films were not good to use on the bottom electrode about the crystalline growth of inorganic compound materials such as ZnO, AlN and GaN, because of its surface roughness and melting points. In this paper, we investigated Ar plasma surface treatment of Al thin film to enhance the surface roughness and electrical conductivity using the reactive ion etching system. Several process conditions such as RF power, working pressure and process time were controlled. In results, the surface roughness showed $15.53\;{\AA}$ when RF power was 100 W, working pressure was 50 mTorr and process time was 10 min. Also, we tried to deposit ZnO thin films on the each Al thin films, the upper conditions showed the best crystalline characteristics by x-ray diffraction.

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Effects of the Particle Electric Conductivity on the Aggregation of Unipolar Charged Nanoparticles (단극하전 나노입자의 응집성장 과정에서 입자의 전기전도도의 효과에 대한 연구)

  • Park, Hyung-Ho;Kim, Sang-Soo;Chang, Hyuk-Sang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.2
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    • pp.173-180
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    • 2003
  • Effects of the electric conductivity of particles were studied for the aggregation process of charged particles with a Brownian dynamic simulation in the free molecular regime. A periodic boundary condition was used for the calculation of the aggregation process in each cell with 500 primary particles of 16 nm in diameter. We considered two extreme cases, a perfect conductor and a perfect nonconductor. The electrostatic force on a particle in the simulation cell was considered as a sum of electrostatic forces from other particles in the original cell and its replicate cells. We assumed that aggregates were only charged with pre-charged primary particles. The morphological shape of aggregates was described in terms of the fractal dimension. The fractal dimension for the uncharged aggregate was D$_{f}$= 1.761. However, the fractal dimension decreased from 1.694 to 1.360 for the case of the perfect conductor, and from 1.610 to 1.476 for the case of the perfect nonconductor, with the increase of the average number of charges on the primary particle from 0.2 to 0.3. These values were smaller than that of the centered charge case.e.

Electrical Properties of $LI_2O-V_2O5-TeO_2$ Glasses for Solid State Electrolyte (전해절용 $Li_2O-V_2O_5-TeO_2$ 계 글라스 세라믹스의 전기적 특성)

  • Lee, Chang-Hee;Park, Jae-Hyeon;Son, Myung-Mo;Lee, Hun-Soo;Gu, Hal-Bon;Park, Hee-Chan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.304-304
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    • 2006
  • Ternary tellurite glassy systems ($Li_2O-V_2O_5-TeO_2$) have been synthesised using Vanadium oxide as a network former and Lithium oxide as network modifier. The addition of a metal oxide makes them electric or mixed electric-ionic conductors, which are of potential interest as cathode materials for solid-state batteries. This glass-ceramics crystallized from the $Li_2O-V_2O_5-TeO_2$ system are particularly interesting, because they exhibit high conductivity (up to $5.63{\times}10^{-5}$ S/cm) at room temperature the glass samples were prepared by quenching the melt on the copper plate and the glass-ceramics were heat-treated at crystallizing temperature determined from differential thermal analysis (DTA). The electric DC conductivity result have been analyzed in terms of a small polaron-hopping model.

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Generation of uniform Fine Droplets Under Spindle Mode in Electrohydrodynamic Atomization (스핀들 모드하의 전기수력학적 미립화를 통한 균일 미세액적 생성)

  • Lee, Sang-Yong;Kim, Myeong-Chan;Kim, Sang-Su;Kim, Yu-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.7
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    • pp.923-932
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    • 2001
  • A series of experiments were conducted to generate fine liquid(water) drops through the electrohydrodynamic atomization process. The atomization mode depended on flow rate and DC voltage input. For water, having electric conductivity larger than 10(sup)-7S/m, the spindle mode turned out to be the only mode to generate uniform-size drops within the range of 30-450 microns that have wide applications. Within this mode, both the uniformity and the fineness of drops were improved at an optimum voltage input for a given flow rate. This optimum voltage increased with increasing of the liquid flow rate. Another important parameter considered was the nozzle material with different electric conductivity and liquid wettability. A stainless-steel nozzle (the material with high electric conductivity and high liquid wettability) and a silica nozzle (the electrically non-conducting material with low liquid wettability) were tested and compared; and more uniform drops could be obtained with the silica nozzle.