• Title/Summary/Keyword: Elastomeric polymer

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Highly Stretchable and Sensitive Strain Sensors Fabricated by Coating Nylon Textile with Single Walled Carbon Nanotubes

  • Park, Da-Seul;kim, Yoonyoung;Jeong, Soo-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.363.2-363.2
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    • 2016
  • Stretchable strain sensors are becoming essential in diverse future applications, such as human motion detection, soft robotics, and various biomedical devices. One of the well-known approaches for fabricating stretchable strain sensors is to embed conductive nanomaterials such as metal nanowires/nanoparticles, graphene, conducting polymer and carbon nanotubes (CNTs) within an elastomeric substrate. Among various conducting nanomaterials, CNTs have been considered as important and promising candidate materials for stretchable strain sensors owing to their high electrical conductivity and excellent mechanical properties. In the past decades, CNT-based strain sensors with high stretchability or sensitivity have been developed. However, CNT-based strain sensors which show both high stretchability and sensitivity have not been reported. Herein, highly stretchable and sensitive strain sensors were fabricated by integrating single-walled carbon nanotubes (SWNTs) and nylon textiles via vacuum-assisted spray-layer-by-layer process. Our strain sensors had high sensitivity with 100 % tensile strain (gauge factor ~ 100). Cyclic tests confirmed that our strain sensors showed very robust and reliable characteristic. Moreover, our SWNTs-based strain sensors were easily and successfully integrated on human finger and knee to detect bending and walking motion. Our approach presented here might be route to preparing highly stretchable and sensitive strain sensors with providing new opportunity to realize practical wearable devices.

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A Study of Friction Characteristics in Magneto-Rheological Elastomer (자기유변탄성체 액츄에이터의 마찰특성 연구)

  • Lee, Deuk-Won;Lee, Chul-Hee;Kim, Cheol-Hyun;Cho, Won-Oh
    • Tribology and Lubricants
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    • v.27 no.4
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    • pp.213-217
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    • 2011
  • In this study, friction characteristics using elastomeric actuator with Magneto-rheological (MR) materials are identified. Typically, Magneto-rheological materials are divided into two groups by MR fluid in fluid state and MR elastomer in solid state like rubber. The stiffness characteristics of Magneto-rheological material can be changed as magnetic field is applied. MR fluid has been applied to various industry fields such as to brake, clutch, damper, engine mount and etc. However, MR fluid has been used under the sealed condition to prevent leaking issues. In order to overcome these problems, MR elastomer that has same property as MR fluid has been developed and studied. MR elastomer mainly consists of polymer material such as natural rubber or silicon rubber with particles that can be polarized with magnetic field. And it is called as a smart material since its stiffness and damping characteristics can be changed. In this study, MR elastomer is produced and pin-on-disc tests are carried out to identify the friction characteristics of the material. Several test conditions are applied to evaluate the feasibility to use as a smart actuator in the field of vibration control.

In situ reduction of gold nanoparticles in PDMS matrices and applications for large strain sensing

  • Ryu, Donghyeon;Loh, Kenneth J.;Ireland, Robert;Karimzada, Mohammad;Yaghmaie, Frank;Gusman, Andrea M.
    • Smart Structures and Systems
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    • v.8 no.5
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    • pp.471-486
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    • 2011
  • Various types of strain sensors have been developed and widely used in the field for monitoring the mechanical deformation of structures. However, conventional strain sensors are not suited for measuring large strains associated with impact damage and local crack propagation. In addition, strain sensors are resistive-type transducers, which mean that the sensors require an external electrical or power source. In this study, a gold nanoparticle (GNP)-based polymer composite is proposed for large strain sensing. Fabrication of the composites relies on a novel and simple in situ GNP reduction technique that is performed directly within the elastomeric poly(dimethyl siloxane) (PDMS) matrix. First, the reducing and stabilizing capacities of PDMS constituents and mixtures are evaluated via visual observation, ultraviolet-visible (UV-Vis) spectroscopy, and transmission electron microscopy. The large strain sensing capacity of the GNP-PDMS thin film is then validated by correlating changes in thin film optical properties (e.g., maximum UV-Vis light absorption) with applied tensile strains. Also, the composite's strain sensing performance (e.g., sensitivity and sensing range) is also characterized with respect to gold chloride concentrations within the PDMS mixture.

Fatigue Crack Growth Behavior of NR and HNBR Based Vulcanizates with Potential Application to Track Pad for Heavy Weight Vehicles

  • Kim, Wonho;Kim, Minyoung;Chang, Young-Wook;Shin, Jung-Eun;Bae, Jong-Woo
    • Macromolecular Research
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    • v.11 no.2
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    • pp.73-79
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    • 2003
  • Generally, field performance of elastomeric track pad components has been poor, especially for the medium to heavy tonnage tracked vehicles, which are operated on the hilly cross-country course. The service life of these track pad, is affected not only by the terrain and environmental conditions but also by the speed, cornering, braking, weight of the vehicle, and the track tread design. In this research, modulus, tearing energy, and the rate of crack propagation of vulcanizates are evaluated by changing base materials to improve the service time of track pad. By increasing the contents of carbon black, modulus, tearing energy, and fatigue crack growth resistance of vulcanizates improved. Compared with the NR vulcanizate, the HNBR vulcanizate had a higher value of tearing energy. The rate of crack propagation of vulcanizates using smaller size carbon black was slower than that using larger size carbon black. When the HNBR was blended with the ZSC, the tearing energy of the vulcanizates was a little reduced because of the high modulus but the crack propagation rate was reduced significantly. In the relation between the crack propagation rate and the strain energy release rate, though up to 100% strain were applied to specimens, the slope on the log scale ($\beta$) varied between 1.72 and 2.3 with the kind of elastomer.

Water-Repellent Macroporous Carbon Nanotube/Elastomer Nanocomposites by Self-Organized Aqueous Droplets

  • Lim, Bo-Kyung;Lee, Sun-Hwa;Park, Ji-Sun;Kim, Sang-Ouk
    • Macromolecular Research
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    • v.17 no.9
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    • pp.666-671
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    • 2009
  • Water repellent elastomeric surfaces were fabricated successfully on SBS/MWNT nanocomposites films using the breath figure method and subsequent thermal treatment. The uniformly dispersed CNTs were found to play significant roles in tuning the size and ordering of the macroporous morphology at the nanocomposite surface as well as enhancing the mechanical properties of nanocomposites. In particular, the CNTs dispersed in a nanocomposite solution retarded the coarsening process of aqueous droplets during the breath figure process and decreased the pore size in the finally fabricated film. The water contact angle measurement showed that the double-scale structure comprised of self-organized macropores and surface the roughness induced by a thermal treatment produced a highly water-repellent nanocomposite surface.

Comparative study on carboxylated styrene butadiene rubber composites reinforced by hybrid fillers of rice bran carbon and graphite carbon

  • Fan, Yuan;Li, Qingyuan;Li, Xiangxu;Lee, Dam hee;Cho, Ur Ryong
    • Carbon letters
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    • v.27
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    • pp.72-80
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    • 2018
  • In the present work, a comparative study of the mechanical behavior of two series of elastomeric composites, based on carboxylated styrene butadiene rubber (X-SBR) and reinforced with rice bran carbon (RBC) and graphite, is reported. Hybrid composites of X-SBR filled with RBC-graphite were also investigated in terms of the cure characteristics, hardness, tensile properties, abrasion resistance, and swelling. It was observed that the cure times decreased with the incorporation of a carbon filler whereas the torque difference, tensile strength, tensile modulus, hardness, and swelling resistance increased compared to the neat X-SBR revealing a favorable characteristic of crosslinking. Dynamic rheological analysis showed that the G' values of the composites, upon the addition of RBC-graphite, were changed to some extent. This demonstrates that the presence of a strongly developed network of fillers will ensure a reinforcing characteristic in a polymer matrix.

A Study of Finishing Conditions influencing Spandex Quality

  • Park, Pyong Ki;Kim, Young Gyun
    • Journal of Korean Society for Quality Management
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    • v.12 no.1
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    • pp.35-44
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    • 1984
  • Spandex is a elastomeric fiber in which the-fiber-forming substance is a long chain polymer consisting of at least 85% segmented polyurethane. In the polyurethanes there are the additional oxygen atoms in the main chains of the molecule. The effect of these oxygen atoms is to make the molecule flexible. From a physical point of view, elasicity and recovery from stretch are the most important properties of polyurethane, so its use had now expanded into many knitting industry. In this paper, we wish to Test the effect of some finishing conditions on the quality of polyurethane.

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Enhanced adhesion properties of conductive super-hydrophobic surfaces by using zirco-aluminate coupling agent

  • Park, Myung-Hyun;Ha, Ji-Hwan;Song, Hyeonjun;Bae, Joonwon;Park, Sung-Hoon
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.387-392
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    • 2018
  • Various technical approaches and concepts have been proposed to develop conductive super-hydrophobic (SH) surfaces. However, most of these approaches are not usable in practical applications because of insufficient adhesion and cost issues. Additionally, durability and uniformity issues are still in need of improvement. The goal of this research is to produce a large-area conductive SH surface with improved adhesion performance and uniformity. To this end, carbon nanotubes (CNT) with a high aspect ratio and elastomeric polymer were utilized as a conductive filler and matrix, respectively, to form a coating layer. Additionally, nanoscale silica particles were utilized for stable implementation of the conductive SH surface. To improve the adhesion properties between the SH coating layer and substrate, pretreatment of the substrate was conducted by utilizing both wet and dry etching processes to create specific organic functional groups on the substrate. Following pretreatment of the surface, a zirco-aluminate coupling agent was utilized to enhance adhesion properties between the substrate and the SH coating layer. Raman spectroscopy revealed that adhesion was greatly improved by the formation of a chemical bond between the substrate and the SH coating layer at an optimal coupling agent concentration. The developed conductive SH coating attained a high electromagnetic interference (EMI) shielding effectiveness, which is advantageous in self-cleaning EMI shielding applications.

A Study on the Optimized Design of O-rings for LPG Filling Unit (LPG 충전노즐에 장착된 O-링의 최적설계에 관한 연구)

  • Kim Chung-Kyun;Kim Do-Hyun
    • Journal of the Korean Institute of Gas
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    • v.10 no.3 s.32
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    • pp.34-40
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    • 2006
  • This paper presents the optimized design of O-rings with a rectangular groove and dovetails, which are strongly related on the sealing performance of LPG filling unit. The computed results on the optimal design are analyzed by non-linear MARC finite element program with Taguchi method. O-rings with 4 different groove models are analyzed for 3 different elastomeric materials. The design parameters are given to polymer materials, groove depth, groove width, and diameter of O-rings. The FEM computed results showed that the affection ratios of O-ring diameter and material property are the most influential parameter among the groove width, groove depth, and compression ratio. Thus, this paper recommends model III for a rectangular groove and model IV for a dovetail groove with a given gas supply pressure of 1.764 MPa.

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Effect of Transoctylene Rubber(TOR) on the Properties of Natural Rubber/isotactic Polypropylene Blends (Transoctylene rubber(TOR)의 첨가가 NR/isotactic PP 블렌드의 물성에 미치는 영향)

  • Yang, Yung-Chul;Nah, Chang-Woon;Chang, Young-Wook
    • Elastomers and Composites
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    • v.36 no.3
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    • pp.188-194
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    • 2001
  • Thermoplastic elastomers based on dynamically vulcanized NR/TOR/PP (rubber/PP=70/30) blends were prepared in a Haake banbury mixer. Effect of TOR content on the mechanical, dynamic mechanical and thermal stability of the rubber/plastic blends was characterized by UTM, DMTA, and TGA. On the addition of trans-polyoctylene rubber(TOR) to the rubber phase, there was a decrease in compression set and increase in tensile properties, hardness and dynamic properties as well as thermal stability or the elastomeric blends. Improvements in the properties were believed to be due to an increase in crosslink density of the rubber phase and increase in homogeneity of the blends.

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