• 제목/요약/키워드: El13

검색결과 276건 처리시간 0.022초

Synthesis of certain N-Aryl-N'-(2-pyrimidinyl)guanidine derivatives as potential antimicrobial agents

  • Eisa, H.M.;Tayel, M.A.;Yousif, M.Y.;El-Kerdway, M.M.
    • Archives of Pharmacal Research
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    • 제13권1호
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    • pp.78-81
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    • 1990
  • N-Aryl-N'(4-hydroxy-6-methyl-2-pyrimidinyl)guanidines (IIa-c) were prepared by cyclization of N-arybiguanides (Ia-c) with ethyl acetoacetate. Coupling of compounds (IIa-c) with the appropriate diazotized arylamine gave N-aryl-N'-(5-arylhydrazono-6-methyl-4-oxopyrimidin-2-yl) guanidines (IIIa-f). Whereas, their chlorination with phosphorus oxychloride followed by treatment of N-aryl-N'-(4-Chloro-6-methyl-2-pyrimidinyl)guanidimes (IVac) with the appropriate arylamine afforded the corresponding 4-arylamino derivatives (Vaf). Compounds (IIa-f) were also formed when compounds (1a-c) were treated with ethyl 2-arylhydrazono-3-oxobutyrates. The antimircobial testing of some of the prepared compounds against some pathogenic microorganisms revealed that only two have a marked effect against Escherichia coli.

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Synthesis of certain 2-aminoadmantane derivatives as potential antimicrobial agents

  • Eisa, Hassan M.;Tantawy, Atif S.;El-Kerdawy, Mohamed-M.
    • Archives of Pharmacal Research
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    • 제13권1호
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    • pp.74-77
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    • 1990
  • N-(2-Amamantyl)-N-(5-arylhydrazono-6-methyl-4-oxopyrimidin-2-yl) guanidines (IIIa, b), 2-(2-admantyl-amino)-4-amino-s-triazine (IVa) and its 6-chloromethyl derivative (IVb) were prepared by cylization of 1-(2-admantyl) biguanide HCl (I) with ethyl 2-arylhydrazono-3-oxobutyrates (II), ethyl formate and ethyl chloroacetate, respectively. Where 1-(2-admantyl)-3-(4, 5-dioxo-2-imidazolidinylidene)guanidine (V) was used as intermediate for the synthesis of amides (VIIa, b), hydrazide (VIII) and azomethine derivatives (IX, b) of alkyl 2-(2-admantyl-amino)-4-amino-2-triazine-6-carboxylates (VI a, b). The antimicrobial testing of the prepared compounds proved that compound 1Xb was the most active. It showed a marked bacteriostatic effect against Staphylococcus aureus and Bacillus subtilis.

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Carbon nanotube antennas analysis and applications: review

  • El-sherbiny, Sh.G.;Wageh, S.;Elhalafawy, S.M.;Sharshar, A.A.
    • Advances in nano research
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    • 제1권1호
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    • pp.13-27
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    • 2013
  • Carbon nanotube characterized by additional inductive effect as compared with the traditional conductors like copper wires of the same size. Consequently, carbon nanotubes have high characteristic impedance and slow wave propagation in comparison with traditional conductors. Due to these characteristics, carbon nanotubes can be used as antenna. In view of this, we describe and review the present research progress on carbon nanotube antennas. We present different analysis models and results which are developed to investigate the characteristics of CNT antennas. Then we conclude by summarizing the characteristics of CNT antennas and specifying the operating frequency limit.

Euler-Maruyama Numerical solution of some stochastic functional differential equations

  • Ahmed, Hamdy M.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제11권1호
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    • pp.13-30
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    • 2007
  • In this paper we study the numerical solutions of the stochastic functional differential equations of the following form $$du(x,\;t)\;=\;f(x,\;t,\;u_t)dt\;+\;g(x,\;t,\;u_t)dB(t),\;t\;>\;0$$ with initial data $u(x,\;0)\;=\;u_0(x)\;=\;{\xi}\;{\in}\;L^p_{F_0}\;([-{\tau},0];\;R^n)$. Here $x\;{\in}\;R^n$, ($R^n$ is the ${\nu}\;-\;dimenional$ Euclidean space), $f\;:\;C([-{\tau},\;0];\;R^n)\;{\times}\;R^{{\nu}+1}\;{\rightarrow}\;R^n,\;g\;:\;C([-{\tau},\;0];\;R^n)\;{\times}\;R^{{\nu}+1}\;{\rightarrow}\;R^{n{\times}m},\;u(x,\;t)\;{\in}\;R^n$ for each $t,\;u_t\;=\;u(x,\;t\;+\;{\theta})\;:\;-{\tau}\;{\leq}\;{\theta}\;{\leq}\;0\;{\in}\;C([-{\tau},\;0];\;R^n)$, and B(t) is an m-dimensional Brownian motion.

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Chemical Investigation of the Constitutive Flavonoid Glycosides of the Leaves of Crataegus sinaica

  • El-Mousallamy, Amani M. D.
    • Natural Product Sciences
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    • 제4권2호
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    • pp.53-57
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    • 1998
  • Leaves of Crataegus sinaica Boiss, contain the new C-glycosyl flavone $3"',4”’-di-O-acetyl-2“-O-{\alpha}-rhamnosylvitexin$, together with the hitherto unknown, dihydroflavonol 3-O-xyloside, (2R:3R)-dihydroquercetin-$3-O-{\beta}-xylopyranoside$. The known compounds (+)-catechin, (-)-epicatechin, vicenin-II, $2"-O-{\alpha}-rhamnosylvitexin$, and $4"'-O-acetyl-2"-O-{\alpha}-rhamnosylvitexin$ were also characterized. Structures were established by conventional methods of analysis and confirmed by $^1H-,\;^{13}C-NMR$, and ESI-MS.

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토석류 이동의 레올로지적 특성 (Rheological Characteristics of Debris Flows)

  • 김상규;서홍석
    • 한국지반공학회지:지반
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    • 제13권5호
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    • pp.125-132
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    • 1997
  • 토석류는 다양한 크기의 흙 입자와 물이 고루 섞여 점성을 가진 유체처럼 하방향으로 이동한다는 사실이 관찰되었다. 이 관찰로부터 토석류를 비선행적인 점도를 가진 비뉴톤 유체처럼 거동하는 것으로 간주할 수 있다. 이 논문에서는 토석류의 레올로지적 특성을 규명하기 위해 산사태 현장에서 채취한 시료를 가지고 점도계를 사용하여 일련의 점도시험을 수행하였다. 그 결과, 토석류는 비뉴톤 유체 중 빙함 소성 모델로 거동한다는 사실이 밝혀졌다. 이 모델을 이용하면 토 석류의 이동을 예측할 수 있다.

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Enterococcus faecium 19-46-4에 의한 Cholic Acid의 생산

  • 정은영;김명수;이철훈;김병홍
    • 한국미생물·생명공학회지
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    • 제24권5호
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    • pp.540-545
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    • 1996
  • A facultative anaerobe Enterococcus faecium 19-46-4 was used to study the production of an antimicrobial substance in anaerobic conditions. Major part of the antibiotic activity was found in the culture filtrate of the bacterium. The active compound was extracted by an equal volume of iso-butanol and concentrated in vacuo (at 50$\circ$C) before purification by C-18 liguid column chromatography and HPLC. A chromatographically pure compound was obtained by two passages of HPLC columns, The compound appeared as a pale-yellow powder. The yield was about 2.5 mg 1$^{-1}$ culture filtrate. The compound was named as KIST 194. KIST 194 were identified as cholic acid (3$\alpha$, 7$\alpha$, 12$\alpha$-trihydroxy-5$\beta$-cholan 24-oic acid) based on its physico-chemical properties determined by UV, IR, $^{1}H-NMR, $^{13}$C-NMR, El-MS and LC-MS.

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New Functional Conductive Polymer Composites Containing Nickel Coated Carbon Black Reinforced Phenolic Resin

  • Farid El-Tantawy;Nadia Abdel Aal;Yong Kiel Sung
    • Macromolecular Research
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    • 제13권3호
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    • pp.194-205
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    • 2005
  • The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

대구(大邱) 지역(地域)의 사암(砂岩) 및 규장암(珪長岩)에 대(對)한 분리면(分離面)의 활동성(活動性) (Kinematic properties of discontinuities on the Sandstone and Felsite in Taegu province)

  • 김영기;최일환;정교철
    • 자원환경지질
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    • 제16권4호
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    • pp.257-268
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    • 1983
  • The Cretaceous sandstone and felsite distributed in north-western border part of Taegu city were studied in the viewpoint of engineering geology with an emphasis of their discontinuities. The probability of continuity of sandstone is 0.69 and that of felsite is 0.56. The correlation coefficients of sandstone are 0.52 and 0.54. Those of felsite are 0.47 and 0.48. These values reflect that the rocks have been strongly jointed. $K_0$ value of the sandstone is close to its $K_a$ value and the test suggests that the sandstone has been in active state. On the other hand, $K_0$ value of the felsite is close to its $K_p$ value, which reflects that the felsite has been in passive state, in order to maintain the stability of the sandstone. $\delta$ value should be changed to be less than 13.2.

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Fully Substituted Ethylene as a New Class of Efficient Sky-Blue Emitting Materials for OLEDs

  • Kim, Soo-Kang;Park, Young-Il;Park, Jong-Wook;Kim, Kyung-Soo;Choi, Cheol-Kyu;Lee, Sang-Do
    • Journal of Information Display
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    • 제8권1호
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    • pp.10-13
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    • 2007
  • We synthesized new blue and bluish green emitting materials by using fully substituted ethylene moieties. Multi-layered EL devices were fabricated with synthesized materials and evaluated in terms of emission color and luminescence efficiency. TBBPE[EML 2] device showed bluish-green CIE value of (0.236, 0.412) and 5.02cd/A at $10mA/cm^2$. BPBBPE[EML 3] device also showed sky-blue CIE value of(0.218, 0.355) and 2.31cd/A at $l0mA/cm^2$.