• Title/Summary/Keyword: Effluent organic matter

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Coastal Eutrophication caused by Effluent from Aquaculture Ponds in Jeju (제주연안 육상양식장 밀집지역 주변해역의 영양염 과잉 요인)

  • Koh, Hyuk-Joon;Park, Sung-Eun;Cha, Hyung-Kee;Chang, Dae-Soo;Koo, Jun-Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.4
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    • pp.315-326
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    • 2013
  • This study investigated the temporal-spatial distribution and variations in water quality parameters (temperature, salinity, pH, DO, COD, SPM, DIN, DIP, silicate, TN, TP, and chlorophyll-a) in the coastal area of Jeju, Korea, adjacent to aquaculture ponds (Aewol-ri, Haengwon-ri, Pyosun-ri, and Ilkwa-ri). Data were collected bimonthly from February 2010 to December 2011. A principal component analysis (PCA) identified three major factors controlling variations in water quality during the sampling period. Aquaculture effluent water led to large changes in nutrient levels. The highest nutrient values were observed during the investigation period. The relatively large increase in organic matter at the sampling stations coupled with sea area runoff events during the summer rainy period. Variation in chlorophyll-a concentration was mainly driven by meteorological factors such as air temperature and rainfall in the coastal areas of Aewol and Haengwon. In the coastal areas of Pyosun and Ilkwa, pollution was caused by anthropogenic factors such as discharge of aquaculture effluent water. High nutrient concentrations at the majority of the coastal stations indicate eutrophication of coastal waters, especially within a distance of 300 m and depth of 10m from drainage channels. Coastal eutrophication driven by aquaculture effluent may be harmful inshore. Events such as eutrophication may potentially influence water pollution in aquaculture ponds when seawater intake is detected because of aquaculture effluent water.

Vertical Flow Zeolite-Filled Reed Bed with Intermittent Feeding for Sewage Treatment (수직 흐름 제올라이트 갈대 여과상에 의한 생활하수 처리)

  • Seo, Jeoung-Yoon
    • KSBB Journal
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    • v.22 no.2
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    • pp.102-108
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    • 2007
  • A sewage was treated using a vertical flow zeolite-filled reed bed. The sewage from the student dormitory of Changwon National University was fed into the reed bed for 10 minutes every 6 hours at the hydraulic load of $314L/m^3{\cdot}$day. The filtering height of the reed bed was 100 em and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolite: 0.5$\sim$1 mm and 1$\sim$3 mm in diameter. Annual average removal efficiency was 88 89.9%, $COD_{Cr}$ 86.1 %, $COD_{Mn}$ 81.2%, T-N 34.0%, $NH_4^+$-N 97.3% and T-P 34.6%. T-N of effluent was mostly $NO_3^-$-N and the concentration of $NO_2^-$-N in effluent was lower than 0.1 mg/L. All removal efficiencies did not show a remarkable seasonal change. The ranking of phosphorous fractions fixed to the zeolite in column test was Ca-P > Fe-P > reductant soluble Fe-P > occluded P > saloid P > AI-P at all depths of the filter. All phosphorous fractions except for AI-P reduced at deeper filter layer, while their content ratios increased at deeper filter layer. Organic matter content was the highest at the highest layer (0$\sim$5 cm from the top of the filter) and only small differences were observed at the deeper filter layer than 5 em from the top. Organic matter content increased at all depths of the filter with the operating time.

A Study on Phosphorus and Nitrogen Removal with Unit Operation in the Ferrous Nutrient Removal Process (철전기분해장치(FNR)에서 단위공정에 따른 질소와 인의 제거)

  • Kim, Soo Bok;Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.39 no.1
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    • pp.83-89
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    • 2013
  • Objectives: The purpose of this experiment was to illuminate the relationship between the phosphorus removal rate of unit operation and the phosphorus removal rate of phosphorus volume loading in the Ferrous Nutrient Removal process, which consists of an anoxic basin, oxic basin, and iron precipitation apparatus. Methods: This study was conducted in order to improve the effect of nitrogen and phosphorus removal in domestic wastewater using the FNR (Ferrous Nutrient Removal) process which features an iron precipitation reactor in anoxic and oxic basins. The average concentration of TN and TP was analyzed in a pilot plant ($50m^3/day$). Results: The removal rate of T-N and T-P were 66.5% and 92.8%, respectively. The $NH_3-N$ concentration of effluent was 2.62 mg/l with nitrification in the oxic basin even though the influent was 17.7 mg/l. The $NO_3$-N concentration of effluent was 5.83 mg/l through nitrification in oxic basin even though the influent and anoxic basin were 0.82 mg/l and 1.00 mg/l, respectively. The specific nitrification of the oxic basin ($mg.NH_3$-Nremoved/gMLVSSd) was 16.5 and specific de-nitrification ($mg.NO_3$-Nremoved/gMLVSSd) was 90.8. The T-P removal rate was higher in the oxic basin as T-P of influent was consumed at a rate of 56.3% in the anoxic basin but at 90.3% in the oxic basin. The TP removal rate (mg.TP/g.MLSS.d) ranged from 2.01 to 4.67 (3.06) as the volume loading of T-P was increased, Conclusions: The test results showed that the electrolysis of iron is an effective method of phosphorus removal. Regardless of the temperature and organic matter content of the influent, the quality of phosphorus in the treated water was both relatively stable and high due to the high removal efficiency. Nitrogen removal efficiency was 66.5% because organic matter from the influent serves as a carbon source in the anoxic basin.

Simulating the Gross Primary Production and Ecosystem Respiration of Estuarine Ecosystem in Nakdong Estuary with AQUATOX (AQUATOX 모델을 이용한 낙동강 하구역의 총일차생산량 및 생물체 호흡량 예측 모델링)

  • Lee, Taeyoon;Hoang, Thilananh;Nguyen, Duytrinh;Han, Kyongsoo
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.3
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    • pp.15-29
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    • 2021
  • The purpose of this study is to establish an ecosystem model that can predict ecosystem fluctuations in the Nakdong estuary, and use this model to calculate total primary production and respiration. AQUATOX model was used as the ecosystem model, and the model was calibrated and verified using the measured data. For the calibration of the model, chlorophyll-a data measured at the Nakdong estuary were used, and the model verification was performed using DO, TN, and TP data. In general, the total primary production and respiration volume vary greatly depending on the season, but the total primary production and respiration in the Nakdong estuary were greatly influenced by the amount of water discharged from Nakdong estuary bank. When the amount of effluent increased, photosynthesis could not be performed due to the loss of phytoplankton living in the lower area, and the total primary production amounted to zero, whereas the respiration increased sharply due to the inflow of organic substances contained in the effluent. The increase in the inflow water means the inflow of organic substances contained in the inflow water, and the organic substances are decomposed by oxidation, reducing dissolved oxygen. Compared with other countries' estuaries, the Nakdong estuary shows the lowest total primary production and because the respiration is larger than the total primary production, the dissolved oxygen is depleted by the oxidation of organic matter.

The Nutrient Removal of Mixed Wastewater composed of Sewage and Stable Wastewater using SBR (SBR을 이용한 하수와 우사폐수로 구성된 혼합폐수의 영양소 제거)

  • 김홍태
    • Journal of Environmental Science International
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    • v.8 no.5
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    • pp.617-623
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    • 1999
  • This study was carried out to obtain the optimal operating parameter on organic matters and nutrient removal of mixed wastewater which was composed of sewage and stable wastewater using SBR. A laboratory scale SBR was operated with An/Ae(Anaerobic/Aerobic) ratio of 3/3, 2/4 and 4/2(3.5/2.5) at organic loading rate of 0.14 to 0.27 kgBOD/$m^3$/d. TCOD/SCOD ratio of mixed wastewater was 3, so the important operating factor depended upon the resolving the particulate parts of wastewater. Conclusions of this study were as follows: 1) For mixed wastewater, BOD and COD removal efficiencies were 93-96% and 85-89%, respectively. It was not related to each organic loading rate, whereas depended on An/Ae ratio. During Anarobic period, the amount of SCOD consumption was very little, because ICOD in influent was converted to SCOD by hydrolysis of insoluble matter. 2) T-N removal efficiencies of mixed wastewater were 55-62% for Exp. 1, 66-76% for Exp. 2, and 67-81% for Exp. 3, respectively. It was found that nitrification rate was increased according to organic concentration in influent increased. Therefore, the nitrification rate seemed to be achieved by heterotrophs. During anoxic period, denitrification rate depended on SCOD concentration in aerobic period and thus, was not resulted by endogenous denitrification. However, the amount of denitrification during anaerobic period were 3.5-14.1 mg/cycle, and that of BOD consumed were 10-40 mg/cycle. 3) For P removal of mixed wastewater, EBPR appeared only Mode 3($3^*$). It was found that the time in which ICOD was converted to VFA should be sufficient. For mode 3 in each Exp., P removal efficiencies were 74, 87, and 81%, respectively. But for 45-48 of COD/TP ratio in influent, P concentration in effluent was over 1 mg/L. It was caused to a large amount of ICOD in influent. However, as P concnetration in influent was increased, the amounts of P release and uptake were increased linearly.

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Effect of Ozonation on Removal of Dissolved Organic Matter by Granular Activated Carbon Process (오존공정이 입상활성탄공정에서 용존유기물질의 제거에 미치는 영향)

  • Ahn, Hyo-Won;Chae, Seon-Ha;Wang, Chang-Keun;Lim, Jae-Lim
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.6
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    • pp.601-608
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    • 2008
  • The objective of this study was to evaluate the effect of ozonation as pretreatment on the removal of dissolved or biodegradable organic matter(DOM or BOM), the variance of DOM fractionation, and microbial regrowth by pilot-scale granular activated carbon processes in which adsorption and biodegradability was proceeding due to long time operation. Regardless of point of ozonation applied, GAC processes with ozonation(i.e., Ozonation combined with GAC Filter-adsorber; Pre O$_3$ + F/A, Ozonation combined with GAC adsorber; Post O$_3$ + GAC) compared with GAC processes without ozonation(i.e., GAC Filter-adsorber; F/A, GAC adsorber; GAC) removed approximately 10 to 20% more of DOC, hydrophilic DOM(HPI), BDOC and AOC after long period of operation that biological activity was assumed to happen. Ozonation was not found to have a significant effect on the removal of DOC, but caused the decrease of AOC by approximately 20%. It was found that the fixed bacterial biomass on GAC media did not show a significant difference between the GAC with ozonation and GAC without ozonation as pre-treatment, whereas the HPC of column effluent was more biostable at Post O$_3$ + GAC compared with F/A or GAC.

Characterizing Fluorescence Properties of Dissolved Organic Matter for Water Quality Management of Rivers and Lakes (하천 및 호소 수질관리를 위한 용존 자연유기물질 형광특성 분석)

  • Hur, Jin;Shin, Jae-Ki;Park, Sung-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.940-948
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    • 2006
  • Fluorescence measurements of dissolved organic matter(DOM) have the superior advantages over other analysis tools for applying to water quality management. They are simple and fast and require minimal pretreatment of samples. Fluorescence index($F_{450}/F_{500}$), synchronous spectra, and fluorescence excitation-emission matrices(EEM) of various DOM samples were investigated to discriminate autochthonous/allochthonous composition, protein-like fluorescence, fulvic-like fluorescence, humic-like fluorescence, terestrial humic-like fluorescence by comparing among the real DOM samples of different origins with the help of literature. The samples used included standard purified DOM, lake, river and wastewater treatment effluent. The relative distribution of various DOM composition was derived from the ratios of each fluorescence region. The results were very consistent with those expected from the sample properties. Allochthonous and terrestrial humic-like fluorescence were more prominent in the samples with abundant soil-derived DOM components. In addition, the protein-like fluorescence property was more pronounced in the samples where strong algal or microbial activities were expected. It was also shown that the ratio of protein-like/terrestrial humic-like fluorescence obtained from synchronous spectrum and fluorescence EEM could be used as an indicator for the evaluation of wastewater treatment on the downstream water quality of rivers and for the prediction of the degree of algal/microbial activities in lakes. It is expected that the results of this study will provide the basic information to develop the future water quality management techniques using DOM fluorescence measurements.

GPS-X Based Modeling on the Process of Gang-byeon Sewage Treatment Plant and Design of Recycle Water Treatment Process (GPS-X 기반 모델링에 의한 강변사업소 처리효율 분석 및 반류수 처리 공정 설계)

  • Shin, Choon Hwan
    • Journal of Environmental Science International
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    • v.25 no.11
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    • pp.1493-1498
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    • 2016
  • The efficiencies of Gang-Byeon sewage treatment facilities, which are based on GPS-X modelling, were analysed and used to design recycle water treatment processes. The effluent of an aeration tank contained total kjeldahl nitrogen (TKN) of 1.8 mg/L with both C-1 and C-2 conditions, confirming that most ammonia nitrogen ($NH_3{^+}-N$) was converted to nitrate nitrogen ($NO_3{^-}-N$). The concentrations of $NH_3{^+}-N$ and $NO_3{^-}-N$ were found to be 222.5 and 227.2 mg/L, respectively, with C-1 conditions and 212.2 and 80.4 mg/L with C-2 conditions. Although C-2 conditions with higher organic matter yielded a slightly higher nitrogen removal efficiency, sufficient denitrification was not observed to meet the discharge standards. For the total nitrogen (T-N) removal efficiency, the final effluent concentrations of T-N were 293.8 mg/L with biochemical oxygen demand (BOD) of 2,500 mg/L, being about 1.5 times lower than that (445.3 mg/L) with BOD of 2,000 mg/L. Therefore, an external carbon source to increase the C/N ratio was required to get sufficient denitrification. During the winter period with temperature less than $10^{\circ}C$, the denitrification efficiency was dropped rapidly even with a high TKN concentration (1,500 mg/L). This indicates that unit reactors (anoxic/aerobic tanks) for winter need to be installed to increase the hydraulic retention time. Thus, to enhance nitrification and denitrification efficiencies, flexible operations with seasons are recommended for nitrification/anoxic/denitrification tanks.

Study on the Removal of Fluorescent Whitening Agent for Paper-mill Wastewater Reuse using the Submerged Membrane Bioreactor(SMBR) with Ozone Oxidation Process (제지폐수 재이용을 위한 침지형 생물막 여과와 오존산화공정(SMBR-Ozone Oxidation Process)에 의한 형광증백제 제거에 관한 연구)

  • Choi, Jang-Seung;Shin, Dong-Hun;Ryu, Seung-Han;Lee, Jae-Hun;Ryu, Jae-Young;Shin, Won-Sik;Lee, Seul-Ki;Park, Min-Soo;Lee, Sang Oh
    • Textile Coloration and Finishing
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    • v.30 no.1
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    • pp.51-61
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    • 2018
  • In this study, effluent water was produced through Submerged Membrane Bio-Reactor(SMBR) process, which is a simple system and decomposes organic matter contained in wastewater with biological treatment process and performs solid-liquid separation, Especially, ozone oxidation treatment process is applied to effluent water containing fluorescent whitening agent, which is a trace pollutant which is not removed by biological treatment, and influences the quality of reused water. The concentration of $COD_{Cr}$ in the SMBR was $449.3mg/{\ell}-COD_{Cr}$, and the concentration of permeate water was $100.3mg/{\ell}-COD_{Cr}$. The removal efficiency was about 70.1%. The amount of ozone required for the removal of the fluorescent whitening agent in the permeated water in SMBR was $6.67g-O_3/min$, and the amount of ozone required to remove $COD_{Mn}$ relative to the permeate water was calculated to remove $0.997mg-COD_{Mn}$ for 1mg of $O_3$.

Impact of Pig Slurry from WangGoong Farm Cluster on Water Quality of the Iksan Stream

  • Choi, Hong-Lim;Suresh, A.;Babu, T.;Mansyur, Mansyur
    • Journal of Animal Science and Technology
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    • v.53 no.6
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    • pp.549-561
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    • 2011
  • Livestock wastewater is being discharged without treatment from Hasen's pig farm cluster in WangGoong (WG) area into the Iksan Stream, eventually flowing into the ManGyung (MG) at the upstream junction. Although it is well known that before discharge, wastewater must satisfy the pig slurry discharge standards; because of ongoing remodeling, proper treatment is not being performed. According to public records, wastewater from the WG pig farm cluster is responsible for 3.6% of MG River pollution and 2.0% of the SaeManGuem (SMG) Reservoir pollution. As a result, upstream water treatment quality has become primary concern for development of the SMG project. All physicochemical constituents and pathogenic microbes, such as chemical oxygen demand ($COD_{Cr}$), biochemical oxygen demand ($BOD_5$), total suspended solids (TSS), total nitrogen (TN), total phosphorous (TP), fecal coliforms, Escherichia coli and Salmonella at the effluent of WG Plant (S-1) exceed the effluent standards. This is mainly due to insufficient wastewater treatment: the WG Plant is under renovation to increase water purification efficiency. By comparing the water quality at the S-7 junction, where the the Iksan Stream (pig farms) and the Wanggoong Stream (no pig farms) merge, it is clear that farming facilities and improper treatment can critically affect surrounding water quality. While it is clear throughout this study that the level of all physicochemical parameters and pathogenic microbes along the Stream decreased due to sedimentation, biodegradation and/or dilution. An alarming problem was discovered: the existence of pathogenic microbe count(E coli, Salmonella) in the lagoon wastewater and the stream water. Not only were high concentrations of these pathogens themselves found, but the potential existence of more serious pathogens could rise to more dangerous conditions.