• Title/Summary/Keyword: Effects of Mo

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The Synthesis of Na0.6Li0.6[Mn0.72Ni0.18Co0.10]O2 and its Electrochemical Performance as Cathode Materials for Li ion Batteries

  • Choi, Mansoo;Jo, In-Ho;Lee, Sang-Hun;Jung, Yang-Il;Moon, Jei-Kwon;Choi, Wang-Kyu
    • Journal of Electrochemical Science and Technology
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    • v.7 no.4
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    • pp.245-250
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    • 2016
  • The layered $Na_{0.6}Li_{0.6}[Mn_{0.72}Ni_{0.18}Co_{0.10}]O_2$ composite with well crystalized and high specific capacity is prepared by molten-salt method and using the substitution of Na for Li-ion battery. The effects of annealing temperature, time, Na contents, and electrochemical performance are investigated. In XRD analysis, the substitution of Na-ion resulted in the P2-$Na_{2/3}MO_2$ structure ($Na_{0.70}MO_{2.05}$), which co-exists in the $Na_{0.6}Li_{0.6}[Mn_{0.72}Ni_{0.18}Co_{0.10}]O_2$ composites. The discharge capacities of cathode materials exhibited $284mAhg^{-1}$ with higher initial coulombic efficiency.

Effects of a Cognitive Enhancement Program combined Silbot on Cognitive Function, Depression, and Dementia Prevention Behavior in Elderly:A Pilot Study (실봇(Silbot)을 병용한 인지강화 프로그램이 노인의 인지기능, 우울 및 치매예방행위에 미치는 효과: 예비연구)

  • Hye-jin Jeong;Eun-Kyoung Han
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.3
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    • pp.402-411
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    • 2023
  • The purpose of this study was to investigate the effects of a cognitive enhancement program combined Silbot on cognitive function, depression, and dementia prevention behavior in the elderly complaining of subjective memory decline. The subjects were 170 elderly people living in Seongnam-si, Gyeonggi-do, and the study was performed at a welfare center. A total of 20 sessions program using Silbot and physical activity was developed and applied, and were evaluated using the Korean version of Montreal Cognitive Assessment (K-MoCA), Geriatric depression Scale(GDS) , and Dementia Prevention Behavior before and after intervention. As a result of the study, the cognitive enhancement program combined Silbot showed statistically significant changes in cognitive function (t=-4.49, p<.001) and depression (t=2.58, p=.023) in the elderly. Therefore, it is expected that the cognitive enhancement program using Silbot will be a useful program that can enhance the cognitive function of the elderly and reduce depression.

Ultrasonic Nonlinearity Measurement in Heat Treated SA508 Alloy: Influences of Grains and Precipitates (열처리된 SA508 합금에서의 초음파 비선형성 측정: 결정립과 석출물 영향)

  • Baek, Seung-Hyun;Lee, Tae-Hun;Kim, Chung-Seok;Jhang, Kyung-Young
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.451-457
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    • 2010
  • In the present study, the influences of grains and precipitates of microstructural evolution on the ultrasonic nonlinearity have been experimentally investigated. The prior-austenite grain and precipitate size are controlled by the variation in austenitizing and tempering conditions in reactor pressure vessel materials of nuclear power plant, SA508 Gr.3 low alloys. The ultrasonic nonlinearity was found to have strong correlations with grains and precipitates since the ultrasonic nonlinear parameter $\beta$ shows decrease trend with coarsening of grains and precipitates. Although the prior-austenite grain size increased, the $\beta$ changed little due to the effects of subgrains, packets and laths. For the preciptate effects, the $\beta$ decreased sharply due to decrease in $Mo_2C$ causing the coherency stain in addition to the precipitate size. The results in this study may provide a potential for characterizing the microstructural evolution, grains and precipitates, by measuring the ultrasonic nonlinearity.

The effects of Se evaporation temperature on CIS absorber layer fabricated by non-vacuum process (Se 증발온도가 비진공 공정으로 제조한 CIS 광흡수층에 미치는 영향)

  • Park, Myoung-Guk;Ahn, Se-Jin;Yoon, Jea-Ho;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.441-443
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    • 2008
  • A non-vacuum process for fabrication of $CuInSe_2$ (CIS) absorber layer from the corresponding Cu, In solution precursors was described. Cu, In solution precursors was prepared by a room temperature colloidal route by reacting the starting materials $Cu(NO_3)_2$, $InCl_3$ and methanol. The Cu, In solution precursors were mixed with ethylcellulose as organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of Cu, In solution with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents and to burn the organic binder material. Subsequently, the resultant CI/Mo/glass sample was selenized in Se evaporation in order to get a solar cell applicable dense CIS absorber layer. The CIS absorber layer selenized at $530^{\circ}C$ substrate temperature for 30 min with various Se gas evaporation temperature was characterized by XRD, SEM, EDS.

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Effects of Retained Austenite on Mechanical Properties of 2.3%C-26%Cr-1%Ni-0.5%Mo White Cast Iron

  • Yu, Sung-Kon
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.586-592
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    • 1998
  • 2.3%C-26%Cr-1%Ni-0.5%Mo 조성의 아공정 백주철을 여러형태로 열처리를 한 후 잔류오스테나이트함량(Vr), 거시 및 미소경도 그리고 내마찰마모성사이의 상호관계를 연구하였다. 주방상태에서의 Vr가 70.2%인 반면 열처리시편들의 경우 0.3-65.4%의 분포를 나타내었다. 초기마모구간 이외에는 마찰마모량과 마모시간과의 사이에 직선적 관계가 얻어졌으며 그 직선의 기울기(Rw)를 내마모성의 비교시 지표로 사용하였다. Rw는 주방상태에서 $2.77{\times}10^{-2}\;mg/s$로 가장 낮았으며 l173k에서 18ks동안 균질화 열처리만 한 시편의 경우 $4.12{\times}10^{-2}\;mg/s$로 내마모성이 가장 열악하였다. 주방상태에서 내마모성이 가장 좋은 이유는 마찰마모시 오스테나이트가 가공경화를 일으켜 마르텐사이트로 변태되었기 때문으로 여겨진다. 미소경도는 HV 358-HV 756, 거시경도는 이 보다 높은 HV 529-HV 785의 분포를 나타내었는데 이는 거시경도의 측정시 공정탄화물인 $M_7C_3$가 포함되었기 때문이다. 가장 높은 미소 및 거시경도는 1323k에서 7.2ks동안 오스테나이화열처리한 시편에서 얻어졌으며 주방상태의 시편이 가장 낮은 경도치를 나타내었다.

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Semiempirical Molecular Orbital Calculations of the Substituent Effects on Acylations of 3-Cephem Analogues

  • Chang Moon-Ho;Koh Hun-Yeong;Lee Jung-Chull;Lee Yoon Sup
    • Bulletin of the Korean Chemical Society
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    • v.15 no.6
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    • pp.453-455
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    • 1994
  • Semiempirical MO calculations are applied to estimate the substituent effects on acylations of the nonfused N-vinyl-2-amino $\beta-lactams$ having frameworks analogous to 3-cephems. The stabilization energy for the reaction intermediate of the nucleophilic attack by the hydroxide ion is selected as the reactivity index and calculated by AM1 and PM3 methods for the model $\beta-lactams$ with substituents at the C1 and N-vinyl terminal positions. The reactivities are larger for -SH connected to the C1 and strong $\pi-acceptors$ at the N-vinyl terminal implying the large reactivity for known active cephalosporins. Quantum chemical calculation of stabilization energy could be useful in correlating antibiotic activities of many compounds obtained as derivatives of a lead compound.

Studies on Damping Ratio of Nailed Joint Connecting Wall to Floor in Light Frame House (경골목조주택의 벽체-바닥체 못결합부의 감쇠비에 관한 연구)

  • Kim, Kwang-Mo;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.3
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    • pp.65-71
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    • 1996
  • In the design of wood structures, the consideration of the dynamic load effect has been increased. Generally, damping ratio is presented as the method of considering dynamic load effect. So, the relationship between joint type and damping ratio was investigated. It has been known that the joint extremely damp the dynamic load in wood structures. Static test was performed to determine the effects of nail size and friction area on joint strength and stiffness. Joint strength and stiffness were increased with nail size. However, the static properties of joint was not affected by friction area. Cyclic test was performed to determine the effects of nail size, friction area and load magnitude on damping ratio, Damping ratio was affected by all factors. Increasing the width of the bottom plate was suggested as the most adequate method to increase the damping ratio without the reduction of the static properties of the structures.

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The Effects of Substrate, Metal-line, and Surface Material on the Performance of RFID Tag Antenna

  • Cho, Chi-Hyun;Choo, Ho-Sung;Park, Ik-Mo
    • Journal of electromagnetic engineering and science
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    • v.7 no.1
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    • pp.47-52
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    • 2007
  • We investigated the effects of substrate, metal-line, and surface material on the performance of radio frequency identification(RFID) tag antenna using a tag antenna with a meander line radiator and T-matching network. The results showed that readability of the tag antenna with a thin high-loss substrate could be increased so that it was similar to that of a low-loss substrate if the substrate was very thin. The readability of the tag antenna decreased significantly when the metal line was thinner than the skin depth. The readability of the tag also decreased drastically when the tag was attached to high-permittivity high-loss target objects.

Tribological Characteristics with Purity Zirconia of Compression Ring Materials in Piston (피스톤 압축 링 재료의 지르코니아 순도에 따른 트라이볼로지 특성)

  • Oh, Seong-Mo
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.5
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    • pp.91-96
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    • 2006
  • The friction and wear properties of ceramics are very important in the applications to engineering ceramic parts such as seal rings, pump parts, automobile meter parts, and so on. In this study, the effects of each other purity on the mechanical and tribological properties of purity zirconia ceramics were investigated. Also in order to determine the effects of sliding distance, sliding speed, contact load, friction coefficient, the amount of worn out material at a certain time, and the prepared composites were measured. Crystalline phases and microstructure were examined with XRD and SEM. The results show that we obtained the good properties of friction coefficient and wear resistance at the purity 99.5% of zirconia. than this of the purity 95% were great at the wear amount of worn out material.

Effects of Tele-Robotic Task Characteristics on the Choice of Visual Display Dimensionality (텔레로봇 작업의 특성이 시각표시장치의 유형 결정에 미치는 영향 연구)

  • Park, Seong-Ha;Gu, Jun-Mo
    • Journal of the Ergonomics Society of Korea
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    • v.23 no.2
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    • pp.25-36
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    • 2004
  • The effects of task characteristics on the relative efficiency of visual display dimension were studied using a simulated tele-robotic task. Through a conventional method of task analysis. the tele-robotic task was divided into two categories: the task element requiring focused attention (FA task) and the task element requiring global attention (CA task). Time-ta-completion data were collected for a total of 120 trials involving 10 participants. For the CA task. there was no significant difference between the multiple two-dimensional (20) display and the three-dimensional (3D) monocular display. For the FA task. however. the multiple 20 display was superior to the 3D monocular display. The results suggest that the characteristics of a given task have a considerable effect on the choice of display dimensionality and the multiple 3D display is better for human operators to effectively judge depth if the task requires frequent use of focused attention.