• 제목/요약/키워드: Effects of Mo

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소결 알루미나의 금속접합 및 접합강도에 관한 연구 (Mo-Mn Metallizing on Sintered Alumina and It합s Bond Strength)

  • 이준;김영태;장성도;손용배
    • 한국세라믹학회지
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    • 제22권6호
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    • pp.58-70
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    • 1985
  • The bond strength of metal to ceramic sealing in Mo-Mn metallizing was investigated by examining the effects of flux composition in alumina ceramics particle size of molybdenum metal powder wet hydrogen atmosphere and temperature in metallizing. The maximum bond strength was obtained when the glass phase filled almost all the microstructural cavities around the interfacial area with few micropores. Such a favorable microstrcutre waas formed and maximum bond strength was observed between 130$0^{\circ}C$. Also the metal to ceramic bond strength was increased using finer molybdenum metal powder than coarse powder. When content of $SiO_2$ in the flux of alumina ceramics was constant metal to ceramic bond strength was improved with increasing the ratio of CaO to MgO in the flux.

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Tightness of the Transition State for the Reactions of Secondary Alkyl Arenesulfonates with Anilines in Acetonitrile

  • 오혁근;권영봉;정동수;이익춘
    • Bulletin of the Korean Chemical Society
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    • 제16권9호
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    • pp.827-831
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    • 1995
  • Kinetic studies on the reactions of five secondary acylic alkyl arenesulfonates with anilines are carried out in acetonitrile at 65.0 ℃. The magnitude of ρXZ determined (ρXZ=0.12-0.13) is slightly greater than that for the alicyclic series (ρXZ=0.11) under the same experimental condition. Ab initio MO results are found to support the slightly tighter transition state expected from the greater magnitude of ρXZ for the acyclic series. Despite the small variations, the magnitude of ρXZ and the theoretical transition state tightness remain relatively constant for the secondary carbon centers. Secondary kinetic isotope effects involving deuterated aniline nucleophiles show a successively smaller kH/kD(<1.0) value for a more sterically crowded reaction center carbon. This is in accord with the later transition state for bond-making predicted by the Bell-Evans-Polanyi principle for the more endothermic nucleophilic substitution reaction. Further support is provided by the results of the AM1 MO calculations on the reactions of secondary alkyl benzenesulfonates with chloride nucleophile.

Effect of Humidity on Friction Characteristics of Automotive Friction Materials

  • Kim, Seong-Jin;Lee, Jae-Young;Jang, Ho
    • KSTLE International Journal
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    • 제2권2호
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    • pp.150-153
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    • 2001
  • The effects of humidity on friction performance of automotive brake materials were studied using a pad-on-disk type friction tester. Three different friction materials based on a simple formulation were investigated by changing the solid lubricant graphite, MoS$_2$, and Sb$_2$S$_3$. Friction materials without solid lubricants were also examined to study the effect of other ingredients in the matrix on humidity. The friction material containing graphite was strongly affected by the humidity showing lower friction coefficient at high humidity level than other conditions. On the other hand, the friction material containing MoS$_2$exhibited higher friction coefficient at initial stage under high humidity level. The friction material without solid lubricant or with Sb$_2$S$_3$ was not affected by humidity conditions. However, the friction material containing barite showed strong speed dependence.

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에어컨 실외기 프로펠러 홴계의 진동소음 평가 및 해석 (Noise & Vibration Evaluation and Analysis for Propeller Fan System of Air Conditioner Outdoor Unit)

  • 박득용;모진용;이진교;구형모;최원석
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2000년도 춘계학술대회논문집
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    • pp.1405-1409
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    • 2000
  • The electro-magnetic noise generated from fan-driving motor is one of important items in view of abnormal noise which affect the quality of air conditioner noise. The electro-magnetic noise of the outdoor unit is identified by the serial experiments for related parts, whose effects are verified to give proper measures for reduced noise level. The weight of fan appears to be the most important factor, and the stiffness of the frame, such as motor bracket is shown to be important also.

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The Effect of Cr and Mo Additions on the Improvement in Microstructural Homogeneity and Mechanical Properties of Ni-containing P/M Steels

  • Wu, Ming-Wei;Hwang, Kuen-Shyang;Huang, Hung-Shang
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.931-932
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    • 2006
  • The microstructures of Ni-containing P/M steels produced by admixed powders or diffusion alloyed powders are usually heterogeneous. To improve the microstructure homogeneity, the effects of Mo and Cr additions in the prealloyed powder form were examined. The results showed that the microstructural homogeneity was improved and superior mechanical properties were achieved with increases in the alloy content, particularly for the Cr. Such a beneficial effect was attained due to the reduction of the repelling effect between Ni and C, as was demonstrated through thermodynamic analysis using the Thermo-Calc software.

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고체윤활용 MoS$_{2}$ Bonded film의 마찰 마모 특성 연구 (The study on the tribological characteristics of the MoS$_{2}$ Bonded film)

  • 류병진;양승호;김성규;유영석;유인석
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1996년도 제23회 춘계학술대회
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    • pp.122-127
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    • 1996
  • In this paper, the effects of the film tinckness, pre-treatment and testing load on. the tribological characteristics have been studied. During the "Ring on-Disk" testing period silica-gel was used to remove the effect of humidity. As a result, increasing the film thickness revealed prolonged wear life, in the case or reasl the testing loads the dynamic friction coefficient was decreased gradually but in regarding the wear life, an intermideate contact pressure (4kgf/mm${2}$) revealed the maximum value. In regarding the surface protuberance friction an intermediate value of area fraction (60%) revealed maximum wear life. In this paper, the qualitative model in regarding the variation of the friction coefficient andworn depth was presented.presented.

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석출물과 전위에 기인한 초음파 비선형성 파라미터 (Ultrasonic Nonlinearity Parameter Due to Precipitate and Dislocation)

  • 김정석;박익근
    • 한국정밀공학회지
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    • 제25권7호
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    • pp.131-138
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    • 2008
  • The microstructural effects on the ultrasonic nonlinearity were investigated in isothermally degraded ferritic 2.25Cr-1Mo steel and low cycle fatigued copper. The variation in ultrasonic nonlinearity (${\beta}/{\beta}_0$) was interpreted as resulting from microstructural changes supported by the electron microscopy and X-ray diffraction, in addition to the mechanical test (Victor's hardness and ductile-brittle transition temperature). The ultrasonic nonlinearity of 2.25Cr-1Mo steel increased abruptly in the initial 1,000 h of degradation, and then changed little due to the coarsening of carbide and precipitation of stable $M_6C$ carbide during isothermal degradation. The ultrasonic nonlinearity of copper increased with the fatigue cycles due to the evolution of dislocation cell substructure.

Sputtered ITO(glass)의 열처리 효과 (Thermal treatment effects of sputtered ITO(glass))

  • 김호수;정순원;구경완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.554-557
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    • 2001
  • Indium Tin Oxide(ITO) thin films have been fabricated by the dc magnetron sputtering technique with a target of a mixture In$_2$O$_3$(90mo1%) and SnO$_2$(10mo1%). We prepared ITO thin films with substrate temperature 200 to 400$^{\circ}C$ and annealing temperature 200 to 500$^{\circ}C$ food polycrystalline-structured ITO films with a low electrical resistivity of 3.4${\times}$10$\^$-4/ Ω$.$cm have been obtained. The visible light transmittance of all obtained films was over 80 %.

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선조철강의 탄화물에 따른 수소지연파괴 거동 분석 (Effects of Carbides on Hydrogen-induced Delayed Fracture for the Energy Saving Wire (ESW))

  • 이진범;강남현;박지태;안순태;박영도;조경목
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 추계학술대회 논문집
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    • pp.139-141
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    • 2009
  • This study analyzed the effect of the microstructure and alloying element on hydrogen-induced delayed fracture properties for the Energy Saving Wire (ESW) developed recently. Specimens were produced with a diameter 6.5mm post to the deformation (0, 10, 20 and 30%), followed by injecting the hydrogen. The experimental results by using GAS chromatography showed that the more hydrogen was emitted for high-carbon steel (0.45%C steel and 0.35%C steel) than low-carbon steel(0.2%C-Cr steel and 0.2%C-Cr-Mo steel). And, 0.45%C steel, 0.35%C steel and 0.2%C-Cr-Mo steel exhibited the crack for 30% deformed specimen. The hydrogen emitted was analyzed with the amount, the spheroidization, and the size of the carbides.

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박판 크리프 수명평가에 마찰계수의 영향 (Effects of Friction Coefficient on Creep Life Assessment of Sheet)

  • 정지용;임지우;금영탁
    • 소성∙가공
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    • 제19권7호
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    • pp.435-440
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    • 2010
  • The creep life of 9Cr1MoVNb steel, in terms of Larson-Miller parameter(LMP), was evaluated by small punch(SP) creep simulation and verified by uniaxial creep test. By employing the elastoplastic FEM(finite element method), the small punch creep behaviors associated with various friction coefficients were simulated to identify a real friction phenomena. The friction coefficient, ${\mu}$=0.7, determined by comparing deflection history was used in the small punch creep simulation to find the equivalent stresses with which the relationship between punch load and uniaxial creep stress was found. The creep life was then predicted by the LMP, which was the relationship among the rupture time, temperature, and stress. Finally, the LMP calculated by SP-creep simulation was compared with that had computed by the uniaxial creep test and fairly matched LMPs were found.