• Title/Summary/Keyword: Effective Viscosity

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Prediction of Residual Layer Thickness of Large-area UV Imprinting Process (대면적 UV 임프린팅 공정에서 잔류층 두께 예측)

  • Kim, Kug Weon
    • Journal of the Semiconductor & Display Technology
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    • v.12 no.2
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    • pp.79-84
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    • 2013
  • Nanoimprint lithography (NIL) is the next generation photolithography process in which the photoresist is dispensed onto the substrate in its liquid form and then imprinted and cured into a desired pattern instead of using traditional optical system. There have been considerable attentions on NIL due to its potential abilities that enable cost-effective and high-throughput nanofabrication to the display device and semiconductor industry. Although one of the current major research trends of NIL is large-area patterning, the technical difficulties to keep the uniformity of the residual layer become severer as the imprinting area increases more and more. In this paper, with the rolling type imprinting process, a mold, placed upon the $2^{nd}$ generation TFT-LCD glass sized substrate($370{\times}470mm^2$), is rolled by a rubber roller to achieve a uniform residual layer. The prediction of residual layer thickness of the photoresist by rolling of the rubber roller is crucial to design the rolling type imprinting process, determine the rubber roller operation conditions-mpressing force & feeding speed, operate smoothly the following etching process, and so forth. First, using the elasticity theory of contact problem and the empirical equation of rubber hardness, the contact length between rubber roller and mold is calculated with consideration of the shape and hardness of rubber roller and the pressing force to rubber roller. Next, using the squeeze flow theory to photoresist flow, the residual layer thickness of the photoresist is calculated with information of the viscosity and initial layer thickness of photoresist, the shape of mold pattern, feeding speed of rubber roller, and the contact length between rubber roller and mold previously calculated. Last, the effects of rubber roller operation conditions, impressing force & feeding speed, on the residual layer thickness are analyzed with consideration of the shape and hardness of rubber roller.

UV-INDUCED POLYMERIZATION OF SIZE-CONTROLLED PLATINUM/POLY[STYRENE-DIVINYLBENZENE-TRI(PROPYLENE GLYCOL) DIACRYLATE] HYDROPHOBIC CATALYST BEADS IN MICROFLUIDICS

  • WEI, JUN;LI, XIANG;SONG, TONG;SONG, ZI-FAN;CHANG, ZHEN-QI;MENG, DA-QIAO
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.738-745
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    • 2015
  • The catalytic exchange of hydrogen isotopes between hydrogen and water has been known to be a very useful process for the separation of tritium from tritiated water. For the process, a highly active hydrophobic catalyst is needed. This study provides an effective fabrication method of size-controlled platinum/poly[styrene-divinylbenzene-tri(propylene glycol) diacrylate] [Pt/poly(SDB-TPGDA)] hydrophobic catalyst beads with a narrow size distribution. Platinum nanoparticles were prepared by ${\gamma}$-ray-induced reduction in the aqueous phase first, and then uniformly dispersed in SDB-TPGDA comonomer after the hydrophobization of platinum nanoparticles with alkylamine stabilizers. The porous Pt/poly(SDB-TPGDA) hydrophobic catalyst beads were synthesized by the UV-initiated polymerization of the mixture droplets prepared in a capillary-based microfluidic system. The size of as-prepared catalyst beads can be controlled in the range of $200-1,000{\mu}m$ by adjusting the flow rate of dispersed and continuous phases, as well as the viscosity of the continuous phase. Sorbitan monooleate and cyclohexanol were used as coporogens to control the porosities of the catalyst beads.

Pseudo-Binary Diffusion Coefficients of Organic Aroma Component - I. The Diffusion Coefficient of Benzaldehyde in Aqueous Sugar Solution - (유기방향물질의 의사 2성분계 확산계수 - 제1보 : 설탕수용액중 Benzaldehyde의 확산계수 -)

  • Kang, An-Soo;Lee, Tae-Hee
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.315-323
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    • 1982
  • The measurement of cell constant in a diaphragm-cell method is the most important factor. In order to get the correct cell constant, the diffusion coefficients of potassium chloride were measured, at various concentration and temperature of potassium chloride solution, and at the stirring rate in the cell. The pseudo-binary diffusion coefficients of organic aroma component (benzaldehyde) in sugar solution has been measured at various concentration and temperature with the cell constant obtained above. Experimental results were compared and discussed with the semi-empirical epuations from literatures. And, especially, the diffusion coefficient of benzaldehyde, $D_{ba}$ for a small solute diffusing in a viscous solvent of larger molecules is proportional to the -0.82 power of the viscosity of aqueous sugar solution, ${\mu}$ at constant temperature, $D_{ba}{\mu}^{0.82}=constant$.

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A Study on the Engineering Properties of Micro Fine Hybrid Silicate Grout Materials (마이크로 복합실리카 그라우트재의 공학적 특성에 관한 연구)

  • Chun, Byung-Sik;Kim, Jin-Chun;Choi, Young-Chul;Jung, Jong-Ju;Yoon, Nam-Sik;Shin, Sang-Jae
    • Journal of the Korean GEO-environmental Society
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    • v.2 no.1
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    • pp.67-79
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    • 2001
  • The objective of this study is to determine the engineering properties of micro fine hybrid silicate grout materials that were developed recently. In this study, MSG-N type was mainly used as grout materials, and the chemical components, grain size distribution, mineral characteristics were analyzed. Moreover, the properties of active silica and ordinary portland cement acting as coagulating agent were analyzed and compared with each other. To determine the engineering properties, the bleeding test, viscosity test, coagulation test, examination with naked eye, photographing by using SEM, uniaxial compression test and in-situ application test for reclaimed ground were carried out. A series of test results showed that the strength of micro fine hybrid silicate grout materials was about twice that of ordinary sodium silicate grout materials, and alkali leakage decreased dramatically when MSG method was utilized. Especially, based on the evaluation of the application of the MSG method to field, this method would be very effective in reducing coefficient of permeability due to its excelent permeability.

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Test tool for flow and self-leveling characters of coating materials of siloxane polymer used to semiconductor and electronic parts (반도체와 전자 부품에 사용되는 실록산 고분자 코팅물질의 흐름성 및 자기 퍼짐성 측정 시험장치 연구)

  • Kim, Cheol-Hyun;Cho, Hyeon-Mo;Lee, Myong-Euy
    • Analytical Science and Technology
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    • v.25 no.2
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    • pp.127-132
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    • 2012
  • A test tool for self-leveling and flowing characters of coating materials used to semiconductors and electronic parts, especially for protection of LCD and PDP connectors, was designed, and the test tool was evaluated using polymeric siloxane coating materials which have various viscosities. The test results showed that the designed test tool was effective to measure self-leveling and flowing properties of coating materials. Therefore, considering that the viscosity is not directly correlated with self-leveling and flowing properties, we believe that this test tool will be a very useful tool for measurement instead of classical method using viscosities of coating materials. Particularly, the measurement of self-leveling and flowing properties using the test tool would be expected to be used in the area of selecting suitable protective coating materials for LCD (Liquid Crystal Display), PDP (Plasma Display Panel) and semiconductor connection parts.

A Study on Application of Warm-Mix Quiet Pavement Using Fine-Size Aggregate (소입경 골재를 이용한 중온 저소음 아스팔트 포장의 적용 연구)

  • Jo, Shinhaeng;Baek, Yujin;Kim, Nakseok
    • Journal of the Society of Disaster Information
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    • v.9 no.1
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    • pp.56-64
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    • 2013
  • The study examines the quiet pavement using fine-size aggregates and warm-mix technique to reduce traffic noise. In order to evaluate the quality of pavement, mix design and laboratory tests were carried out. Test results showed that using 10mm aggregates can reduce the cantabro loss compared with 13mm aggregates due to increase contact area between aggregates. Mixing and compaction temperatures of warm mix quiet pavement should be determined by gyratory compactor test because it is used high viscosity asphalt binder. Using warm-mix additive could reduce compaction temperature by about $15^{\circ}C$. Noise measurement and permeability tests were conducted at the test road for evaluation of the field performance. All of quiet pavements meet the standard of permeability and have sufficient porosity. Noise reduction of the quiet pavement using fine-size aggregates is more effective than that using 13mm aggregates. In particular, the effect of noise reduction was noticeable at low speeds.

Preparation of Chemical and Fouling Resistant Semicrystalline Membranes (내식성, 내오염성 결정성 고분자 분리막의 제조)

  • 유종범;송기국;김성수
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.342-349
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    • 2000
  • Hollow fiber membranes were prepared via thermally-induced phase separation process followed by stretching process from isotactic polypropylene and soybean oil system. Various operating parameters were examined in terms of their effects on the structure variation and performances of the membrane, and were optimized. Melt viscosity of the melt sample had influence on the formation of the microfibrils, and addition of nucleating agent increased the nucleation density to enhance the interspherulitic pore formation by stretching. Annealing the membrane at its stretched state relaxed the stress induced by stretching and helped the membrane maintain the stretched structure without shrinking. Solid-liquid Phase separation is more prevalent when the nucleating agent was added, and coagulation bath temperature determined the nucleation density, which affected the pore formation by stretching. In the absence of nucleating agent, nucleation was not effective and liquid-liquid phase separation governed the structure formation, which showed the opposite trend to that of the case with nucleating agent.

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A Fundamental Study for the Efficient Heating System for Warm In-Place Recycling in Korea (국내 현장중온재생공법의 효율적인 가열공정을 위한 기초연구)

  • Kim, Dae-Hun;Kwon, Soo-Ahn;Lee, Jae-Jun
    • International Journal of Highway Engineering
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    • v.18 no.2
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    • pp.29-36
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    • 2016
  • PURPOSES: The objective of this study is to determine the milling temperature that minimizes the binder-induced damage to the aggregate; this is achieved by evaluating the temperature dependence of the viscosity of the asphalt binder, with the aim of developing an effective heating process for warm in-place recycling. METHODS : The validity of the indoor test was confirmed by conducting an internal heating test based on the on-site heating test. In addition, the adhesive power of the binder was measured at various temperatures ($30^{\circ}C$, $40^{\circ}C$, $50^{\circ}C$, $60^{\circ}C$, $70^{\circ}C$) via three types of measuring methods. RESULTS: The surface temperature spectrum of field test was slight different with that of laboratory test. But, the spectra of inner temperature between the field and the laboratory was almost similar. Also, the adhesion of the asphalt binder was measured from $30^{\circ}C$ to $70^{\circ}C$. The adhesion of the binder was significantly decreased from $60^{\circ}C$. Contrary to other temperature, the adhesion was slightly changed from $60^{\circ}C$ to $70^{\circ}C$. Also the inner temperature between two different heating methods was shown similar temperature spectra. CONCLUSIONS: The pavement heating temperature spectrum of hot in place recycling method was simulated by a laboratory test. Based on this study, the optimum temperature was $60^{\circ}C{\sim}70^{\circ}C$ for reducing aggregate damage during milling process. The susceptibility heating method developed in this study can be maintained the optimum inner temperature range.

Studies on Rheological Properties of Dough and Stability of Frozen Dough (밀가루의 이화학적(理化學的)인 성질(性質) 및 냉동(冷凍)반죽의 안정성(安定性))

  • Suh, Sook Chool;Song, Hyung lk;Chung, Ki Taek
    • Current Research on Agriculture and Life Sciences
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    • v.5
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    • pp.75-80
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    • 1987
  • We investigated physico-chemical properties of hard wheat flours for frozen yeast-raised breadmaking and freezing stability of frozen dough prepared by the straight no-time method. The general Composition of wheat flours were : moisture ; 14.0%, ash ; 0.48%. protein ; 13.15%, and dry gluten ; 13.43%. In farinograph data, development time and water absorption were 5.5 mimutes and 62 %, respectively. Amylograph maximum viscosity was 500 BU. Resistance to extention increased with the time and their extensibility decreased in the extensigraph data. From these results obtained from these physico-chemical properties, it was confirmed that the used wheat flours were most suitable for bread-baking. Considering effect of gassing power on cold storage period and fermentation time, it was effective that dough temperature should be adjusted to $20^{\circ}C$ in order to decrease freezing injury and maintain freezing stability.

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Isolation of Chitin from Crab Shell Waste (게 가공 폐기물로부터 키틴의 분리)

  • 노홍균;이문이
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.1
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    • pp.105-113
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    • 1995
  • Procedures for isolatin of chitin have been developed from crab(Chionoecetes opilio) shell waste with 26. 65% chitin on a dry basis. Optimal conditions for demineralization of crab shell were 1N HCl at ambient temperature for 30min with a solids to solbent ratio of 1 : 15(w/v). Optimal deproteinization involved treatment with 5% NaOH at $65^{\circ}C$ for 1 hr with a solids to solvent ratio of 1 : 15(w/v). Effective decoloration was achieved by bleaching with 0.32% sodium hypochlorite solution for 3min with a solids to solvent ratio of 1 : 10(w/v). Particular attentin was given to characterization of the physicochemical properties of the crab chitin. Chitins, from four different mesh sizes of crab shell, did not show significant differences in nitrogen and ash compositions. Bleaching decreased the viscosity of chitin but did not affect its solubility.

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