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Growth Behavior of Heteroepitaxial β-Ga2O3 Thin Films According to the Sapphire Substrate Position in the Hot Zone of the Mist Chemical Vapor Deposition System (미스트화학기상증착 시스템의 Hot Zone 내 사파이어 기판 위치에 따른 β-Ga2O3 이종 박막 성장 거동 연구)

  • Kyoung-Ho Kim;Heesoo Lee;Yun-Ji Shin;Seong-Min Jeong;Si-Young Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.5
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    • pp.500-504
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    • 2023
  • In this study, the heteroepitaxial thin film growth of β-Ga2O3 was studied according to the position of the susceptor in mist-CVD. The position of the susceptor and substrate was moved step by step from the center of the hot zone to the inlet of mist in the range of 0~50 mm. It was confirmed that the average thickness increased to 292 nm (D1), 521 nm (D2), and 580 nm (D3) as the position of the susceptor moved away from the center of the hot zone region. The thickness of the lower region of the substrate is increased compared to the upper region. The surface roughness of the lower region of the substrate also increased because the nucleation density increased due to the increase in the lifetime of the mist droplets and the increased mist density. Therefore, thin film growth of β-Ga2O3 in mist-CVD is performed by appropriately adjusting the position of the susceptor (or substrate) in consideration of the mist velocity, evaporation amount, and temperature difference with the substrate, thereby determining the crystallinity of the thin film, the thickness distribution, and the thickness of the thin film. Therefore, these results can provide insights for optimizing the mist-CVD process and producing high-quality β-Ga2O3 thin films for various optical and electronic applications.

Assessing the resilience of urban water management to climate change

  • James A. Griffiths
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.32-32
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    • 2023
  • Incidences of urban flood and extreme heat waves (due to the urban heat island effect) are expected to increase in New Zealand under future climate change (IPCC 2022; MfE 2020). Increasingly, the mitigation of such events will depend on the resilience of a range Nature-Based Solutions (NBS) used in Sustainable Urban Drainage Schemes (SUDS), or Water Sensitive Urban Design (WSUD) (Jamei and Tapper 2019; Johnson et al 2021). Understanding the impact of changing precipitation and temperature regimes due climate change is therefore critical to the long-term resilience of such urban infrastructure and design. Cuthbert et al (2022) have assessed the trade-offs between the water retention and cooling benefits of different urban greening methods (such as WSUD) relative to global location and climate. Using the Budyko water-energy balance framework (Budyko 1974), they demonstrated that the potential for water infiltration and storage (thus flood mitigation) was greater where potential evaporation is high relative to precipitation. Similarly, they found that the potential for mitigation of drought conditions was greater in cooler environments. Subsequently, Jaramillo et al. (2022) have illustrated the locations worldwide that will deviate from their current Budyko curve characteristic under climate change scenarios, as the relationship between actual evapotranspiration (AET) and potential evapotranspiration (PET) changes relative to precipitation. Using the above approach we assess the impact of future climate change on the urban water-energy balance in three contrasting New Zealand cities (Auckland, Wellington, Christchurch and Invercargill). The variation in Budyko curve characteristics is then used to describe expected changes in water storage and cooling potential in each urban area as a result of climate change. The implications of the results are then considered with respect to existing WSUD guidelines according to both the current and future climate in each location. It was concluded that calculation of Budyko curve deviation due to climate change could be calculated for any location and land-use type combination in New Zealand and could therefore be used to advance the general understanding of climate change impacts. Moreover, the approach could be used to better define the concept of urban infrastructure resilience and contribute to a better understanding of Budyko curve dynamics under climate change (questions raised by Berghuijs et al 2020)). Whilst this knowledge will assist in implementation of national climate change adaptation (MfE, 2022; UNEP, 2022) and improve climate resilience in urban areas in New Zealand, the approach could be repeated for any global location for which present and future mean precipitation and temperature conditions are known.

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Changes in Physical Properties and Wood Chemical Components of sawdust medium during Oak Mushroom (Lentinula edodes) Cultivation (표고 재배 중 톱밥 배지의 물리적 성질과 목재 화학성분 변화)

  • Jong-Shin Lee;Seog-Goo Kang;Seung-Min Yang;Jin-Kyoung Kim
    • The Korean Journal of Mycology
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    • v.50 no.4
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    • pp.291-300
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    • 2022
  • In this study, the physical properties of the medium and changes in the wood chemical composition of the sawdust were investigated during the cultivation of oak mushroom sawdust bags, and the following results were obtained. After inoculation, the weight of the medium decreased during the incubation period. It is determined that this is not due to evaporation of moisture containing the medium or decomposition of sawdust, but to decomposition of rice bran, a low molecular substance added to the medium. It was confirmed that the moisture content of the medium was steadily increased during incubation, and it was estimated that the organic substrates such as rice brane in the medium was decomposed by mycelium, and water, one of the decomposition products of organic substrates, caused an increase in the moisture content of the medium. Along with the increase in the harvest of oak mushrooms, the proportion of organic substances such as holocellulose and lignin, the main components of the wood cell wall of sawdust, steadily decreased. In particular, the degradation characteristics of the wood cell wall component of shiitake, which is a white rot fungi, were confirmed by higher lignin reduction rate than that of holocellulose. On the other hand, ash, which is an inorganic material, increased with an increase in the number of mushroom harvests. The increase in the amount of ash in the medium may have been due to the decrease in the organic matter content such as holocellulose and lignin.

Prediction of Soil Moisture using Hydrometeorological Data in Selmacheon (수문기상자료를 이용한 설마천의 토양수분 예측)

  • Joo, Je Young;Choi, Minha;Jung, Sung Won;Lee, Seung Oh
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.5B
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    • pp.437-444
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    • 2010
  • Soil moisture has been recognized as the essential parameter when understanding the complicated relationship between land surface and atmosphere in water and energy recycling system. It has been generally known that it is related with the temperature, wind, evaporation dependent on soil properties, transpiration due to vegetations and other constituents. There is, however, little research concerned about the relationship between soil moisture and these constitutes, thus it is needed to investigate it in detail. We estimated the soil moisture and then compared with field data using the hydrometerological data such as atmospheric temperature, specific humidity, and wind obtained from the Flux tower in Selmacheon, Korea. In the winter season, subterranean temperature showed highly positive correlation with soil moisture while it was negatively correlated from the spring to the fall. Estimation of seasonal soil moisture was compared with field measurements with the correlation of determination, R=0.82, 0.81, 0.82, and 0.96 for spring, summer, fall, and winter, respectively. Comprehensive relationship from this study can supply useful information about the downscaling of soil moisture with relatively large spatial resolutions, and will help to deepen the understanding of the water and energy recycling on the earth's surface.

Cracking Behavior of Concrete Bridge Deck Due to Differential Drying Shrinkage (교량 바닥판 콘크리트의 부등건조수축 균열특성에 관한 연구)

  • Yang, Joo Kyoung;Lee, Yun;Yang, Eun Ik;Park, Hae Geun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4A
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    • pp.329-335
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    • 2009
  • The purpose of this study is to provide the efficient method and guideline of controlling the cracking in bridge deck concrete due to differential drying shrinkage. Drying shrinkage cracking is mainly influenced by the moisture diffusion coefficient that determines moisture diffusion rate inside concrete structures. In addition to the diffusion coefficient, surface coefficient of concrete surface and relative humidity of ambient air simultaneously affect the moisture evaporation from concrete inside to external air outside. Within the framework of cracking shrinkage cracking mechanism, it is necessary to conceive the numerical analysis, which involves these three influencing factors to predict and control the shrinkage cracking of concrete. In this study, moisture diffusion and stress analysis corresponding to drying shrinkage on bridge deck are performed with consideration of diffusion coefficient, surface coefficient, and relative humidity of ambient air. From the numerical results, it is found that cracking behavior due to differential drying shrinkage of bridge deck concrete shows different feature according to three influencing factors and the methodology of controlling of drying shrinkage cracks can be suggested from this study.

Statistical Analyses of Soil Moisture Data from Polarimetric Scanning Radiometer and In-situ (Polarimetric Scanning Radiometer 와 In-situ를 이용한 토양수분 자료의 통계분석)

  • Jang, Sun Woo;Jeon, Myeon Ho;Choi, Minha;Kim, Tae-Woong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.5B
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    • pp.487-495
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    • 2010
  • Soil moisture is a crucial factor in hydrological system which influences runoff, energy balance, evaporation, and atmosphere. United States National Aeronautic and Space Administration (NASA) and Department of Agriculture (USDA) have established Soil Moisture Experiment (SMEX) since 2002 for the global observations. SMEX provides useful data for the hydrological science including soil moisture and hydrometeorological variables. The purpose of this study is to investigate the relationship between remotely sensed soil moisture data from aircraft and satellite and ground based experiment. C-band of Polarimetric Scanning Radiometer (PSR) that observed the brightness temperature provides soil moisture data using a retrieval algorithm. It was compared with the In-situ data for 2-30 cm depth at four sites. The most significant depth is 2-10 cm from the correlation analysis. Most of the sites, two data are similar to the mean of data at 10 cm and the median at 7 cm and 10 cm at the 10% significant level using the Rank Sum test and t-test. In general, soil moisture data using the C-band of the PSR was established to fit the Normal, Log-normal and Gumbel distribution. Soil moisture data using the aircraft and satellites will be used in hydrological science as fundamental data. Especially, the C-band of PSR will be used to prove soil moisture at 7-10 cm depths.

Antioxidant, anti-inflammatory, and antimicrobial activity of hesperetin and its cyclodextrin inclusion complexes (헤스페레틴(Hesperetin)과 사이클로덱스트린(Cyclodextrin) 포접 복합체의 항산화, 항염증, 항균 활성 )

  • Sung-Sook Choi;Kyung-Ae Lee
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.5
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    • pp.988-1000
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    • 2023
  • Hesperetin(HT) is a potent antioxidant flavonoid aglycone derived from hesperidin(HD). The antioxidant, anti-inflammatory, and antimicrobial activities of HT and its cyclodextrin(CD) inclusion complexes were compared in vitro. HT was prepared by enzymatic hydrolysis of HD, and HT/CD complexes were prepared using 𝛽-cyclodextrin(𝛽-CD) and hydroxypropyl-𝛽-cyclodextrin(HP-𝛽-CD) by solvent co-evaporation method. The solubility of the HT/HP-𝛽-CD inclusion complex increased 93.5-fold compared to HT, and the solubility of HT/𝛽-CD increased 22.5-fold. The HT/HP-𝛽-CD inclusion complex showed a similar effect as HT on radical scavenging activity in antioxidant assays, whereas the HT/𝛽-CD inclusion complex showed slightly lower activity than HT. Cytotoxicity was low in the following order; HT/HP-𝛽-CD, HT/𝛽-CD, and HT in murine macrophage RAW264.7 cells. Treatment with HT and HT/CD inclusion complexes reduced the levels of inflammatory mediators such as nitric oxide(NO), tumor necrosis factor-𝛼(TNF-𝛼) and interleukin-6(IL-6) in the cells. HT and HT/HP-𝛽-CD inclusion complex were more effective than HT/𝛽-CD inclusion complex at relatively low concentrations. Inhibitory effects were tested on skin-pathogenic bacteria, Staphylococcus aureus and Pseudomonas aeruginosa, and they showed an antimicrobial effect on S. aureus in the order of HT = HT/HP-𝛽-CD > HT/𝛽-CD, but they did not show any significant inhibitory effect on P. aeruginosa. In conclusion, HT, the aglycone form of HD, and its CD inclusion complexes showed various biological activities. HT/HP-𝛽-CD inclusion complex, which is the highly soluble form of HT, showed relatively higher activity compared to HT/𝛽-CD inclusion complex.

An Evaluation of Minimum Explosible Concentration and Explosion Severity of Coal Dust in a Thermal Power Plant (화력발전소용 석탄분진의 최소폭발농도와 폭발강도 평가)

  • Yeosong Yoon;Keun-won Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.4
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    • pp.62-69
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    • 2023
  • The use of low-grade coal is continuously increasing with the development of combustion technology and cost reduction for coal used in thermal power plants . During combustion, the latent heat of evaporation due to moisture is large, and there is a risk of spontaneous combustion and dust explosion during the process of storing and pulverizing coal. This study compared and evaluated the minimum explosive concentration and explosive strength of four types of coal dust-fine, coal dust-coarse, wood pallet+organic dust, and wood chip with coal powder collected from domestic power plant D. The minimum explosive concentration of coal dust was measured according to JIS Z 8818:2002, and the explosion strength was tested according to ASTM E1226 using a Siwek 20 L Chamber Apparatus. As a result of the minimum explosive concentration test, it was found that coal dust-fine has a risk of dust explosion, and since an explosion occurs at a dust concentration of 130 g/m3 of wood chips, it was found that there is a risk of explosion at the lowest dust concentration. According to the dust explosion class standard, Kst is less than 200 bar m/s, and all samples fall under the explosion class St 1, and the dust has a low risk of explosion.

A study on the manufacture of humidity sensors using layered silicate nanocomposite materials (층상 실리케이트계 나노복합 소재 적용 습도센서 제조에 관한 연구)

  • Park, Byoung-Ki
    • Industry Promotion Research
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    • v.9 no.1
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    • pp.31-38
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    • 2024
  • In this study, evaluated the properties of layered silicate-based nanocomposite sensitive film. For the fabrication of nanocomposite materials, we selected organically modified layered silicate materials, specifically Cloisite® and Bentone®, which were treated with quaternary ammonium salts. The impedance of the humidity sensors containing organically modified montmorillonite/hectorite clay decreased with increasing relative humidity(RH%). In the case of the Cloisite® humidity sensor exhibited slightly better impedance linearity and hysteresis compared to the Bentone® 38 humidity sensor. Additionally the impedance of the sensor with Bentone® 38 addition was the lowest when compared to the Cloisite®-modified sensor. Comparing the Cloisite®-modified sensors individually, we observed different moisture absorption characteristics based on the hydrophilic properties of the organic-treated materials. The response speed of Cloisite® 93A tended to be slower due to differences in moisture evaporation rates influenced by the hydrophilic organic components. Based on these results, moisture barriers utilizing organically modified layered silicate materials may exhibit slightly lower moisture absorption properties compared to conventional polymer-based moisture barriers. However, their excellent stability, simple processing, and cost-effectiveness make them suitable for humidity sensor applications.

Distribution Behavior of Natural Radionuclide Pb in Molten Fe to Metal/Slag/Gas Phase (용융 Fe 중 천연방사성핵종 Pb의 금속/슬래그/가스상으로의 분배거동)

  • So-Yeong Lee;Hyeon-Soo Kim;Jong-Hyeon Lee;Ho-Sang Sohn
    • Resources Recycling
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    • v.33 no.2
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    • pp.54-61
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    • 2024
  • When steel contaminated with Pb, produced by the decay of natural radionuclides, is remelted, Pb distributes among the metal, slag, and gas phases. In this study, 5 wt%Pb was added to Fe and melted with CaO-SiO2-Al2O3-MgO slag to investigate Pb's distribution in the metal/slag/gas. As slag basicity ((wt%CaO)/(wt%SiO2)) increased, Pb solubility in Fe slightly increased, while Pb in the slag tended to decrease. Consequently, the slag/metal distribution ratio of Pb decreased with increasing basicity. Thermodynamic calculations revealed that the slag/Fe phase distribution ratio of Pb remained very low irrespective of the activity coefficient of PbO in the slag, consistent with the experimental results. The calculated evaporation rate of Pb in Fe-Pb was approximately 22 times that of Fe; hence, most of the Pb evaporated into the gas phase.