• Title/Summary/Keyword: EVA (Ethylene Vinyl Acetate)

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기능성마이크로스피어의 제조와 응용(I) - TiO2를 함유한 Poly(ethylene-co-vinylacetate) 공중합체의 마이크로스피어 제조 및 그 특성에 관한 연구 (Preparation and Application of Functional Microsphere(I) - A Study on Microsphere Formation and Characteristics of Poly(ethylene-co-vinylacetate) Polymer with TiO2)

  • 이신희;박수민
    • 한국의류산업학회지
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    • 제10권2호
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    • pp.254-259
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    • 2008
  • Poly(ethylene-co-vinylacetate)(EVA) microspheres were prepared by a thermally induced phase separation. The microsphere formation occurred by the nucleation and growth mechanism in the metastable region. The diluents used were toluene. The microsphere formation and growth was followed by the cloud point of the optical microscope measurement. The microsphere size, which was obtained by SEM observation and particle size analyzer, became decreased when the titanium dioxide($TiO_2$) concentration was higher. The deodorizing function of the prepared fabrics was studied by the determination of the decomposing capability for $NH_3$. The deodorant activity of these deodorizing fabrics was measured by chromogenic gas detector tubes. The deodorant activity of $NH_3$ increased with increasing $TiO_2$ concentration of EVA microsphere.

수용성 첨가제를 함유하는 에틸렌초산비닐 매트릭스로부터 5-플루오로우라실의 방출 (Release of 5-Fluorouracil from Ethylene-Vinyl Acetate Matrices Containing Hydrophilic Additives)

  • 오승열;유영미;김승수;신병철;육순흥;이해방
    • Journal of Pharmaceutical Investigation
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    • 제26권4호
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    • pp.281-289
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    • 1996
  • In our previous work, we have studied the effect of lactose and sodium alginate (SA) on the rate of release of 5-fluorouracil (5-FU) from ethylene-vinyl acetate (EVA) matrix. These hydrophilic additives promoted the rate of 5-FU release and the increase in rate was larger when SA was used. Both additives showed better ability to increase the rate than 5-FU itself. In this paper, we extended our study to another hydrophilic additive, Carbopol 940 (CP). Compared to SA or lactose, CP increased the rate of 5-FU release markedly. Release rate increased as the loading amount and the pH of the release medium increased. After release experiment, matrix volume increased up to 15 times of that before release experiment, depending on the amount of CP dispersed in the matrix and the pH of the release medium. On the other hand, the volume of the matrix containing lactose or SA decreased. The weight changes of the dry matrix before and after release experiment imply that CP is not released out of the matrix, to the contrary of lactose and SA. Scanning electron microscope study clearly showed that large cavities and pores are generated on the surface and the inside of the matrix. These results indicate that the mechanism by which CP increases the release rate is quite different from that of monomeric additives such as lactose or SA.

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Cure Characteristics of Foaming EVA Compounds: Influence of EVA Types and Cure Systems

  • Choi, Sung-Seen;Bae, Jong Woo;Kim, Jung-Soo;Han, Dong-Hun
    • Elastomers and Composites
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    • 제51권3호
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    • pp.212-217
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    • 2016
  • Influence of poly(ethylene-co-vinyl acetate) (EVA) types and cure systems on cure characteristics of foaming EVA compounds were investigated. Three kind EVAs with different VA contents were employed. Influence of triallyl cyanurate (TAC) and dicumylperoxide (DCP) content on the cure characteristics were examined. The minimum torque ($T_{min}$) and delta torque (${\Delta}T$) decreased as the VA content increased. The ${\Delta}T$ was increased by adding TAC and by increasing the DCP content. For the foaming EVA compounds without TAC, the cure times such as the minimum cure time ($t_{min}$), scorch time ($t_2$), and optimal cure time ($t_{90}$) did not show a specific trend according to the DCP contents. For the foaming EVA compounds containing TAC, the cure times decreased as the DCP content increased. From the experimental results, it was found that efficienct DCP/TAC ratio for improvement of the crosslink density was 1.1~2.0.

Photovoltaic module의 발전 온도에 따른 EVA 광 특성 연구 (A Study on EVA Optical Characteristics By Generation Temperature of PV module)

  • 우성철;정태희;민용기;강기환;안형근;한득영
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 춘계학술발표대회 논문집
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    • pp.31-35
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    • 2011
  • Photovoltaic modules are well known to be one of the most eco generation of electricity. But usually study solar cell. Otherwise, PV modules are also important in power generation. We have to check other subsidiary materials. In this work benefit of using optically superior encapsulation materials(EVA) in generation temperature is demonstrated. Optical characterization of three EVA products demonstrates reduced transmission in the visible ray region of the solar spectrum. It will have a decisive effect to the module efficiency. Test is shown reduction of reflectance and transmittance. Reflections is dependent on the low iron glass. It can be seen between a specific wave length(240~350mm) about 1%. Transmittance in the entire ray region of light is markedly reduced to depending on the temperature rise. The graph is shown optical properties on EVA. Transmission was reduced. about 1%.

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Flame Retardancy and Electrical Characteristics of LDPE/EVA Blend Involving Mg(OH)2 and Zinc-borate

  • Ryu, Boo-Hyung;Kim, Gyu-Baek;Jung, Sang-Ho;Cho, Young-Suk
    • Transactions on Electrical and Electronic Materials
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    • 제7권6호
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    • pp.309-312
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    • 2006
  • This study shows to blend ethylene vinyl acetate(EVA) and a flame retardant agent, $Mg(OH)_{2}$, and synergists, zinc borate for improving flame retardancy of low density polyethylene(LDPE). And it studied the property of flame retardancy of LDPE/EVA blend by the amount of addition through LOI and TGA, estimated the electrical characteristics such as volume resistivity and breakdown strength. The flame retardancy of LDPE/EVA blend was much improved in case of adding zinc borate with 6phr degree, and the electrical characteristics were more or less decreased depending on increasing the amount of addition. Zinc borate used for improving the flame retardancy of LDPE/EVA blend let the added amount of a flame retardant agent, $Mg(OH)_{2}$ limited, and the electrical characteristics decreased extremely by adding a good deal of $Mg(OH)_{2}$.

EVA Sheet의 Gel Content가 태양전지모듈의 내구성에 미치는 영향 (The Effect of EVA Sheet Gel Content on Photovoltaic Modules Durability)

  • 강기환;박지홍;김경수;유권종;안형근;한득영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.20-21
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    • 2006
  • In this paper, we studied the influence of EVA sheet gel content on photovoltaic module durability. Depending on thermal curing temperature and time during lamination, there are dramatic changes on chemical and physical characteristics. To find the optimum PV module process condition, Glass/EVA/Back Sheet scheme was made. Gel Content, FT-IR spectrum and SEM were used for the detail analysis. From these results, $110^{\circ}C/6min$ and $130^{\circ}C/4min$ lamination condition could be suggested for the best one for durable PV module processing. The further analysis is described in the following paper.

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혼합비에 따른 선형저밀도 폴리에틸렌과 에틸렌비닐아세테이트 블랜드의 전기적 특성 (Electrical Characteristic of Blend with LLDPE and EVA Due to Mixing Ratio)

  • 신종열;이충호;홍진웅
    • 한국전기전자재료학회논문지
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    • 제14권6호
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    • pp.525-532
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    • 2001
  • In this paper, physical properties and electrical characteristics of linear low density polyethylene(LLDPE) films blended with ethylene vinyl acetate(EVA), containing polar groups within it, were investigated to improve defects of polyethylene(PE) such like space charge accumulation and tree growth. Blending method changes super-structure of LLDPE, having a great influence on electrical characteristics. For analysis of physical properties, FTIR, XRD and DSC methods were executed, and for electrical characteristics, volume resistivity and dielectric strength were measured with the varying temperature. From the results, it is confirmed that bled specimens tend to be safe to varying temperature, and specially of 70:30 and 50:50 have a good performance.

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분쇄된 FRP 폐기물을 사용한 폴리머 시멘트 모르타르의 물성 (Physical Properies of Polymer Cement Mortar Using Ground FRP Wastes)

  • 이병기;이범재;황의환;노재성
    • 콘크리트학회지
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    • 제10권5호
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    • pp.217-225
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    • 1998
  • 분쇄한 FRP(Fiver-Reinforced Plastics) 폐기물을 사용한 폴리머 모르타르의 물성에 고나하여 조사하였다. 분쇄한 FRP 폐기물을 시멘트 모르타르의 세골재로 재활용하기 위하여 세골재에 대하여 0~50wt% 치환.사용하였고, FRP 폐기물의 사용으로 나타나는 강도 저하현상을 보완하기 위하여 3종류 폴리머 혼화제의 첨가량을 변화시켜 각종 공시체를 제작하였다. 폴리머 혼화제로서는 styrene-bytadiene rubber(SBR) 라텍스, polyacrylic ester(PAE) 에멀젼 및 ethylene-vinyl acetate(EVA)에멀젼을 사용하였다. 분쇄한 FRP 폐기물을 사용한 시멘트 모르타르에 폴리머 혼화제를 첨가하여 만든 폴리머 시멘트 모르타르는 폴리머 혼화제를 첨가하지 않은 모르타르보다 압축 및 휨강도가 크게 증가하였다. 폴리머 시멘트비 10wt%에서 세골재 대용으로 분쇄한 FRP 폐기물의 적정 치환량은 20wt%로 나타났다. 8$0^{\circ}C$에서 가열양생하여 제조한 폴리머 시멘트 모르타르는 폴리머 시멘트비 10wt%이하에서 표준양생한 모르타르보다 강도가 저하되었다. 폴리머 시멘트 포르타르의 흡수율은 폴리머 시멘트비가 증가함에 따라 크게 감소하였다.

스포츠 마우스가드의 기능성과 안정적인 착용감을 위한 제작 증례 (Fabrication of a sport mouse guard for performance and comfortable wearing)

  • 임중재
    • 대한치과기공학회지
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    • 제42권3호
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    • pp.298-305
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    • 2020
  • Here, we studied the sports mouse guard as an oral device system, to minimize the sports related facial and dental injuries, jawbone fracture and brain injury, and by layering the hardened sheets for improving the activity performance and stable wearing. By pressuring and layering 2 soft- and 1 hard-layers of ethylene vinyl acetate (EVA) thermoplastic materials, for a category of martial art, record sports and leports, here we introduce a methodology for thickness control of layers to protect the teeth and oral structure. A personally customized mouse guard optimized for sports by layering a mixture of soft and hardened sheets is not easily detached during the sporting activity, easy to breathe through, comforts to wear, and also improves the sporting record. A designed EVA thermoplastic material for individual sports is used as the mouth guard, which is stably attached, easily removed, and convenient for breathing through the mouth.

Analysis of Peroxide Curing Agents in EVA Compounds and Vulcanizates

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
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    • 제55권1호
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    • pp.6-12
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    • 2020
  • Poly(ethylene-co-vinyl acetate) compounds and vulcanizates containing dicumyl peroxide (DCP) (HD) were prepared, and the curing agent and reaction products were analyzed using gas chromatography/mass spectrometry (GC/MS). Samples containing trially cyanurate (TAC) and DCP (HDT) were also prepared and analyzed. Some raw DCP were decomposed in the injector region of GC to produce acetophenone. DCP was detected in the HD compound but was not observed in the HD vulcanizate, and instead acetophenone and 2-phenyl-2-propanol were detected. Both DCP and TAC were observed in the HDT compound but not in the HDT vulcanizate, where acetophenone and 2-phenyl-2-propanol were detected. Thus, some of the DCP decomposed during the compounding process. The formation mechanism for acetophenone and 2-phenyl-2-propanol during the crosslinking reaction was identified, and differences in the crosslinking reactions of HD and HDT compounds were discussed.