• 제목/요약/키워드: ESR

검색결과 678건 처리시간 0.033초

Antioxidative Activity of Rice Grain using FI-CL and ESR Methods

  • Chung, Ill-Min;Kim, Kwang-Ho;Ahn, Joung-Kuk;Lee, Si-Kyung;Lee, Jin-Ohk
    • 한국작물학회지
    • /
    • 제46권5호
    • /
    • pp.411-415
    • /
    • 2001
  • Fifty-four Korean native and 28 foreign rice varieties harvested in 1998 and 1999 were examined for antioxidative activity that is measured to a chemiluminescence and superoxide radical intensity, by the flow injection chemiluminescence (FI-CL) system and an electron spin resonance (ESR) spectrophotometer, respectively. In the chemiluminescence measurement by FI-CL, radical scavenger activity did not differ significantly among rice varieties between origin types of rice varieties, and between storage periods. GinSun and Hongchoengdo, colored rice exhibited high electron scavenging effect by ESR. Therefore, these results indicate that the pigments of rice varieties may play important antioxidative roles and that it may be possible to breed rice varieties with higher antioxidative potentials.

  • PDF

전자스핀공명을 이용한 저밀도 폴리에틸렌의 방사선 열화 검지 (Detection of Radiation Degradation of LDPE by ESR Spectroscopy)

  • 김기엽;이청;류부형
    • 한국안전학회지
    • /
    • 제20권1호
    • /
    • pp.81-86
    • /
    • 2005
  • This study has investigated radiation degradation of low density polyethylene(LDPE). Samples were irradiated up to 800kGy using a $Co^{60}\;\gamma-ray$ at a dose rate of 5kGy/hr in the presence of air atmosphere at room temperature. After irradiation, storing for 2 weeks, free radical measurement of LDPE has established by electron spin resonance(ESR). ESR measurement showed that free radical concentration(FRC) was increased with radiation dose and decreased with the time. The radical types showed alkyl, allyl, and peroxy radical with the irradiation, these changed to peroxy radical with the time.

ESR Spectroscopy에 의한 전자선 조사 건조 채소의 검지와 흡수선량 예측 (Detection and Absorbed-Dose Estimation of Electron Beam-Irradiated Dried Vegetable Using ESR Spectroscopy)

  • 권중호;정형욱
    • 한국식품영양과학회지
    • /
    • 제28권4호
    • /
    • pp.882-885
    • /
    • 1999
  • Along with the increasing demands for food irradiation technology, proper detection methods for controlling irradiated foods are required. Dried vegetable(chunggyungchae), which is permitted to be irradiated in Korea, was subjected to a detection study by ESR spectroscopy. Pre established threshold value was successfully applicable to the detection of 50 coded unknown samples of dried clean vege tables, both nonirradiated and electron beam irradiated. Three calibration curves obtained from the samples irradiated at 2.5~15 kGy were not practically adopted to estimate actual absorbed doses ranging from 4 to 7 kGy.

  • PDF

Enhancing Effect of Organic Substances on Hydroxyl Radical Generation During Ozonation of Water: Stopped-Flow ESR Technique

  • Han, Sang-Kuk
    • Bulletin of the Korean Chemical Society
    • /
    • 제25권12호
    • /
    • pp.1907-1910
    • /
    • 2004
  • Generation of hydroxyl radical, one of their major active species in ozonation of water was directly observed with spin-trapping/electron spin resonance (ESR) technique using 5,5-dimethyl-pyrrolidine-1-oxyl (DMPO) as a spin-trapping reagent. Hydroxyl radical was trapped with DMPO as a stable radical, DMPO-OH. 80 mM of ozone produced $1.08{\times}10^{-6}$M of DMPO-OH, indicating that 1.4% of ${\cdot}$OH is trapped with DMPO if ${\cdot}$OH is produced stoichiometrically from ozone. Humic acid suppressed DMPO-OH generation in a dose-dependent manner. Generation rate of DMPO-OH was determined with ESR/stopped-flow measurement. Phenol derivatives increased the amount and generation rate of DMPO-OH, indicating that phenol derivatives enhance·OH generation during ozonation of water.

Electron Spin Resonance Study on the Miscibility of Poly(ethylene glycol) with Cathonic Dodecyl Trimethylammonium Bromide Micelle

  • Kim Jin-Soo;Lee Don-Keun;Kang Young-Soo
    • 한국자기공명학회논문지
    • /
    • 제9권2호
    • /
    • pp.155-162
    • /
    • 2005
  • The interaction of poly(ethylene glycol)(PEG) with cationic dodecyl trimethyl ammonium bromide (DTAB)micelle was studied with electron spin resonance (ESR) by determining line widths of the ESR spectra and coupling constant of nitrogen($A_N$). The degree of ESR line shape change such as line widths and coupling constant indicated that PEG mixes well with DTAB micelle due to a great hydrophobic interaction with surfactant alkyl chains. This suggests that the PEG can be used as non-ionic surfactant to disperse the exposed oil in the ocean.

  • PDF