• 한국GIS학회:학술대회논문집
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• 한국GIS학회 2003년도 공동 춘계학술대회 논문집
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• pp.135-138
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• 2003

레이더 interferometry 기법을 이용하여 1995년 12월 11일과 12일에 획득된 ERS-1(orbit: 23180, frame 2853), ERS-2(orbit: 03507, frame: 2853) tandem 자료로부터 서해안(강화도-아산만) 지역의 조간대 DEM을 추출하였다. 사용된 SAR 자료는 영상획득 당시의 낮은 조위(ERS-1: 0.89 cm, ERS-2: -0.02 cm), 짧은 시간 간격(1일), 그리고 비교적 긴 기선 간격(270 m 수직 baseline)을 갖기 때문에 조간대 DEM 추출에 매우 적합하였다. 비록 추출된 DEM의 정확도 평가는 수행되지 않았지만 기존에 광학영상으로부터 추출된 남양만 지역의 waterline과 시각적으로 단순 비교될 수 있었다. 보다 정밀한 정확도 평가는 본 연구에서 사용한 자료와 같은 날 획득된 곰소만 지역의 자료(frame: 2886)를 사용하여 waterline 방법으로 추출된 DEM 및 현장 측량자료를 이용하여 수행될 것이다. Temporal 그리고 baseline decorrelation 등을 무시하고 SAR 영상의 위상측정 오차만을 이용하여 계산된 고도 정밀도는 SNR 20 dB에서 약 0.57 m이다.

• 한국축산식품학회지
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• 제41권1호
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• pp.59-70
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• 2021

A method for simultaneous detection of fipronil (F) and its metabolites fipronil desulfinyl (FD), fipronil sulfide (FS), fipronil sulfone (FSO) in chicken eggs was applied and validated. It includes single-step, cheap, effective, rugged, safe-based method (SinChERS) for sample preparation and ultra high performance liquid chromatography coupled with mass spectrometry (UHPLC-MS/MS) for chemical analysis. Results suggested that formic acid enhanced the recovery of 4 target residues and 1% supplementation to acetonitrile gained higher recoveries than that of 5%. SinChERS integrated extraction and clean-up steps into one, with shorter time (1.5 h) to operate and higher recoveries (97%-100%) than HLB, Envi-Carb-NH2 and quik-easy-cheap-effective-rugged-safe method (QuEChERS), and it consumed the smallest volume of extracting solvent (10 mL) as QuEChERS. Quantitative analyses using external standard method suggested the linear ranges of 4 target compounds were 1-20 ㎍/L with R2 >0.9947. The limit of detection (S/N>3) and quantification (S/N>10) were 0.3 ㎍/kg and 1 ㎍/kg. Recoveries ranged from 89.0% to 104.4%, and the relative standard deviations (n=6) at 1, 10, and 20 ㎍/kg were lower than 6.03%. Thirty batches of domestic eggs (500 g each) were detected by the established SinChERS-based UHPLC-MS/MS and no target residues were detected in all samples. The method developed in this study is a rapid, sensitive, accurate and economic way for multi-residue analysis of fipronil and its metabolites in eggs.

• 대한원격탐사학회지
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• 제34권1호
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• pp.17-24
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• 2018

Grounding line of a glacier or ice shelf where ice bottom meets the ocean is sensitive to changes in the polar environment. Recent rapid changes of grounding lines have been observed especially in southwestern Antarctica due to global warming. In this study, ERS-1/2 and Sentinel-1A Synthetic Aperture Radar (SAR) image were interferometrically acquired in 1996 and 2015, respectively, to monitor the movement of the grounding line in the western part of Ronne Ice Shelf near the Antarctic peninsula. Double-Differential Interferometric SAR (DDInSAR) technique was applied to remove gravitational flow signal to detect grounding line from the interferometric phase due to the vertical displacement of the tide. The result showed that ERS-1/2 grounding lines are almost consistent with those from Rignot et al. (2011) which used the similar dataset, confirming the credibility of the data processing. The comparison of ERS-1/2 and Sentinle-1A DDInSAR images showed a grounding line retreat of $1.0{\pm}0.1km$ from 1996 to 2015. It is also proved that the grounding lines based on the 2004 MODIS Mosaic of Antarctica (MOA) images and digital elevation model searching for ice plain near coastal area (Scambos et al., 2017), is not accurate enough especially where there is a ice plain with no tidal motion.

• 대한원격탐사학회지
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• 제23권1호
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• pp.65-69
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• 2007

The processes of regional scales in the East Korean coastal waters were investigated by analysis of the Synthetic Aperture Radar (SAR) images taken by the European Research Satellites ERS-1, ERS-2 and Envisat. More than 500 quick look frames taken in 1991-2003 were examined to detect the frames with clearly surface expressions of oceanic phenomena. 26 ERS-1/2 SAR and 11 Envisat wide swath Advanced SAR (ASAR) frames were selected and obtained from the European Space Agency in a form of the precision high-resolution images. The following oceanic phenomena and processes were evident in the radar imagery through the Korean costal waters: fronts, currents, eddies, internal waves, island and ship wakes, oil pollution, etc. They manifested themselves in the field of sea surface roughness, their scale ranged from several tens meters to about 100 km. The most common morphology of these phenomena was a series of contrast dark or light curvilinear lines and bands. The joint analysis of the discussed SAR images with other satellite and in situ data supported and enhanced our interpretation of SAR signatures.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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• pp.1124-1126
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• 2003

The processes of regional scales in the East Korean coastal waters were investigated by analysis of the Synthetic Aperture Radar (SAR) images taken by the European Research Satellites ERS-1, ERS-2 and Envisat. More than 500 quick look frames taken in 1991-2003 were examined to detect the frames with clearly surface expressions of oceanic phenomena. 26 ERS-1/2 SAR and 11 Envisat wide swath Advanced SAR (ASAR) frames were selected and obtained from the European Space Agency in a form of the precision high-resolution images. The following oceanic phenomena and processes were evident in the radar imagery through the Korean costal waters: fronts, currents, eddies, internal waves, island and ship wakes, oil pollution, etc. They manifested themselves in the field of sea surface roughness, their scale ranged from several tens meters to about 100 km. The most common morphology of these phenomena was a series of contrast dark or light curvilinear lines and bands. The joint analysis of the discussed SAR images with other satellite and in situ data supported and enhanced our interpretation of SAR signatures.

• 농약과학회지
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• 제17권4호
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• pp.314-334
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• 2013

곡물류 모니터링 시료인 현미, 보리, 옥수수 3가지 작물을 대상으로 보편적으로 많이 사용되고 등록된 농약을 조사, 76종을 선정하여 QuEChERS AOAC Official 2007. 01. 법과 변형된 QuEChERS 법으로 LC-MS/MS를 이용하여 회수율 시험을 비교하였다. 1% acetic acid를 사용하여 추출하는 QuEChERS AOAC Official 2007. 01. 법의 0.05, 0.2 mg/kg 회수율 결과는 현미 32.4~139.0%, 보리 24.2~123.7%, 옥수수 29.0~117.2%였고, 그 중 sulfonylurea 계통인 azimsulfuron, ethoxysulfuron, flucetosulfuron, imazosulfuron에 대해 회수율이 낮게 나오는 문제가 있었으며, 이들 농약의 평균 회수율은 53.3%였다. 이런 문제를 해결하기 위해 QuEChERS 법의 추출용매를 1% formic acid가 함유된 acetonitrile 용매로 바꾼 결과, 0.05, 0.2 mg/kg 수준의 회수율은 현미 73.2~132.2%, 보리 80.9~136.8%, 옥수수 66.6~143.5%였으며 변이계수는 모두 10% 미만이었다. 문제시 되었던 sulfonylurea 계통의 농약의 회수율도 53.3%에서 90.5%로 증가하였다. 검출한계(limits of detection, LOD)와 정량한계(limits of quantification, LOQ)는 현미 0.24~1.92, 0.79~65.74 ng/g, 보리 0.12~21.12, 0.36~63.36 ng/g, 옥수수 0.28~100.8, 0.86~302.4 ng/g이었다. 변형한 QuEChERS 법을 모니터링 시료 현미, 보리, 옥수수에 적용하여 98개 시료를 분석한 결과 36개의 시료에서 26종의 농약이 검출되었다. 검출 농도가 가장 높은 농약은 tricyclazole로 1.17 mg/kg로 조사되었다. 변형한 QuEChERS법으로 전처리를 하여 질량분석기 뿐만 아니라 현재 많이 보급된 검출기인 ECD, NPD 및 UPLC에서도 분석이 가능한지 실험하였고, 현미, 보리, 옥수수의 평균 회수율은 ECD는 65.3~130.3%, NPD는 61.6~133.0%로 대부분의 농약들이 잔류농약 검색용을 목적으로 하는 다성분 분석의 기준인 70~130% 이내의 회수율과 30%의 미만의 변이계수 조건을 만족하였다.

• 분석과학
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• 제36권5호
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• pp.205-215
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• 2023

In the present study, an analytical method was proposed for detecting trifluralin in aquatic products at trace concentrations. The method employed QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) and gas chromatography coupled with tandem mass spectrometry (GC-MS/MS) as the sample preparation and measurement, respectively. The effect of the aqueous phase volume used in the QuEChERS was demonstrated, and the ratio of 10:10 (mL) between water and acetonitrile phase was used for 5 g of sample. Besides, dSPE using C18 and primary-secondary amine (PSA) was applied to remove the potential interferences from the food matrices, indicating no remarkable analyte loss. The linear range was built up from 0.50 ㎍ L^-1 to 3.0 ㎍ L^-1 (R² = 0.9993). Other criteria, i.e., repeatability (RSD_r = 0.86-1.96 %), reproducibility (RSD_R = 1.09-2.01 %), and recovery (over 90 %), were in accordance with Appendix F of AOAC (2016) for method performance. Although no trifluralin was detected for the commercial samples (fish, shrimp, and breaded shrimp), the spiked samples performed favorable recoveries and precision.

• 한국동물위생학회지
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• 제34권4호
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• pp.429-439
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• 2011

This article described the comparison of a quick, easy, cheap, effective, rugged and safe (QuEChERS) sample preparation and the classical method established by National Veterinary Research and Quarantine Service (NVRQS) for the determination of pesticide residues in livestock products using GC-tandem mass spectrometry. The classical method by NVRQS used liquid-liquid partioning followed by evaporizing. The modified QuEChERS entailed extraction of 2 g sample with 15 ml acetonitrile containing 1% acetic acid followed by addition of 6 g anhydrous magnesium sulfate and 1.5 g sodium acetate. After centrifugation, 6 ml of the extract underwent a cleanup step (in a technique known as column-based solid phase extraction) using 400 mg each of $C_{18}$ and primary secondary amine sorbents plus 1,200 mg magnesium sulfate. The quantitation of individual pesticides by both methods was based on tissue standard calibration curves with a correlation coefficient in excess of 0.98 for the 24 pesticides. The detection limits by the classical method were ranged 1.3~5.0 ${\mu}g$/kg, with mean recoveries between 76.2% and 114.3% except aldrin (59.3%) and deltamethrin (63.6%). The detection limits by modified QuEChERS were ranged 0.3~6.2 ${\mu}g$/kg, with mean recoveries between 68.0% and 114.3% except dimethipin (152.6%), chlorfenvinphos (138.1%), 4,4-DDT (61.5%), aldrin (60.4%) and chinomethionate (30.3%).

• 한국환경과학회지
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• 제16권3호
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• pp.269-275
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• 2007

The standard emission rate(ERs) of isoprene was quantitatively measured in situ from Quercus mongolica Fischer that dominates more than about 85% of domestic oak trees. The ERs values in spring and summer were similar to 64.4 and 58.1 (${\mu}gC/gdw/hr$), respectively. The ERs in autumn, 7.06(${\mu}gC/gdw/hr$), was about $8{\sim}9$ times lower than those in spring and summer. The coefficient of determination ($r^2$) between ERs and $C_L\;C_T$ ranged from 0.593 to 0.836. The correlation coefficients between the ERs and PAR. the ER and temperature suggested that ERs have strong correlation with PAR(photosynthetically active radiation) and temperature. In addition, the high values of PAR, temperature, and ERs were found in the time zone of $15:00{\sim}17:00$(spring), $15:00{\sim}16:00$(summer), and $14:00{\sim}15:00$(autumn).

• 농약과학회지
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• 제18권4호
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• pp.296-313
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• 2014

토양환경 중 잔류농약 동시분석을 위해 124종의 농약을 대상으로 QuEChERS 전처리와 LC-MS-MS를 이용한 분석법을 개발하고자 하였다. QuEChERS 전처리 과정은 토양시료에 0.2N $NH_4Cl$ 용액 침지하고 1% acetic acid 포함 acetonitrile 용매로 추출 후 $MgSO_4$ 및 NaOAc로 salting out하고 PSA 50 mg, $C_{18}$ 50 mg, $MgSO_4$ 150 mg를 이용해 정제하였다. 분석법의 검증을 위해 양토 및 사양토 두 토양에서 0.005, 0.01, 0.02, 0.1 mg/kg 4수준으로 처리 후 회수율 실험을 실시하였다. 회수율 실험결과 Benfuracarb, Ethiofencarb, Pymetrozine, Pyrethrin 성분을 제외하고 나머지 성분들은 사양토와 양토 모두 70~120%의 적정 회수율을 나타내었으며, 상대표준편차도 20% 이내를 양호한 결과를 나타내었다. 따라서 QuEChERS 전처리 및 LC-MS를 이용한 분석법은 토양 중 잔류농약 다성분동시분석에 적용이 가능할 것으로 판단되었다.