• Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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• 2003.04a
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• pp.135-138
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• 2003

레이더 interferometry 기법을 이용하여 1995년 12월 11일과 12일에 획득된 ERS-1(orbit: 23180, frame 2853), ERS-2(orbit: 03507, frame: 2853) tandem 자료로부터 서해안(강화도-아산만) 지역의 조간대 DEM을 추출하였다. 사용된 SAR 자료는 영상획득 당시의 낮은 조위(ERS-1: 0.89 cm, ERS-2: -0.02 cm), 짧은 시간 간격(1일), 그리고 비교적 긴 기선 간격(270 m 수직 baseline)을 갖기 때문에 조간대 DEM 추출에 매우 적합하였다. 비록 추출된 DEM의 정확도 평가는 수행되지 않았지만 기존에 광학영상으로부터 추출된 남양만 지역의 waterline과 시각적으로 단순 비교될 수 있었다. 보다 정밀한 정확도 평가는 본 연구에서 사용한 자료와 같은 날 획득된 곰소만 지역의 자료(frame: 2886)를 사용하여 waterline 방법으로 추출된 DEM 및 현장 측량자료를 이용하여 수행될 것이다. Temporal 그리고 baseline decorrelation 등을 무시하고 SAR 영상의 위상측정 오차만을 이용하여 계산된 고도 정밀도는 SNR 20 dB에서 약 0.57 m이다.

• Food Science of Animal Resources
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• v.41 no.1
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• pp.59-70
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• 2021

A method for simultaneous detection of fipronil (F) and its metabolites fipronil desulfinyl (FD), fipronil sulfide (FS), fipronil sulfone (FSO) in chicken eggs was applied and validated. It includes single-step, cheap, effective, rugged, safe-based method (SinChERS) for sample preparation and ultra high performance liquid chromatography coupled with mass spectrometry (UHPLC-MS/MS) for chemical analysis. Results suggested that formic acid enhanced the recovery of 4 target residues and 1% supplementation to acetonitrile gained higher recoveries than that of 5%. SinChERS integrated extraction and clean-up steps into one, with shorter time (1.5 h) to operate and higher recoveries (97%-100%) than HLB, Envi-Carb-NH2 and quik-easy-cheap-effective-rugged-safe method (QuEChERS), and it consumed the smallest volume of extracting solvent (10 mL) as QuEChERS. Quantitative analyses using external standard method suggested the linear ranges of 4 target compounds were 1-20 ㎍/L with R2 >0.9947. The limit of detection (S/N>3) and quantification (S/N>10) were 0.3 ㎍/kg and 1 ㎍/kg. Recoveries ranged from 89.0% to 104.4%, and the relative standard deviations (n=6) at 1, 10, and 20 ㎍/kg were lower than 6.03%. Thirty batches of domestic eggs (500 g each) were detected by the established SinChERS-based UHPLC-MS/MS and no target residues were detected in all samples. The method developed in this study is a rapid, sensitive, accurate and economic way for multi-residue analysis of fipronil and its metabolites in eggs.

• Korean Journal of Remote Sensing
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• v.34 no.1
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• pp.17-24
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• 2018

Grounding line of a glacier or ice shelf where ice bottom meets the ocean is sensitive to changes in the polar environment. Recent rapid changes of grounding lines have been observed especially in southwestern Antarctica due to global warming. In this study, ERS-1/2 and Sentinel-1A Synthetic Aperture Radar (SAR) image were interferometrically acquired in 1996 and 2015, respectively, to monitor the movement of the grounding line in the western part of Ronne Ice Shelf near the Antarctic peninsula. Double-Differential Interferometric SAR (DDInSAR) technique was applied to remove gravitational flow signal to detect grounding line from the interferometric phase due to the vertical displacement of the tide. The result showed that ERS-1/2 grounding lines are almost consistent with those from Rignot et al. (2011) which used the similar dataset, confirming the credibility of the data processing. The comparison of ERS-1/2 and Sentinle-1A DDInSAR images showed a grounding line retreat of $1.0{\pm}0.1km$ from 1996 to 2015. It is also proved that the grounding lines based on the 2004 MODIS Mosaic of Antarctica (MOA) images and digital elevation model searching for ice plain near coastal area (Scambos et al., 2017), is not accurate enough especially where there is a ice plain with no tidal motion.

• Korean Journal of Remote Sensing
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• v.23 no.1
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• pp.65-69
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• 2007

The processes of regional scales in the East Korean coastal waters were investigated by analysis of the Synthetic Aperture Radar (SAR) images taken by the European Research Satellites ERS-1, ERS-2 and Envisat. More than 500 quick look frames taken in 1991-2003 were examined to detect the frames with clearly surface expressions of oceanic phenomena. 26 ERS-1/2 SAR and 11 Envisat wide swath Advanced SAR (ASAR) frames were selected and obtained from the European Space Agency in a form of the precision high-resolution images. The following oceanic phenomena and processes were evident in the radar imagery through the Korean costal waters: fronts, currents, eddies, internal waves, island and ship wakes, oil pollution, etc. They manifested themselves in the field of sea surface roughness, their scale ranged from several tens meters to about 100 km. The most common morphology of these phenomena was a series of contrast dark or light curvilinear lines and bands. The joint analysis of the discussed SAR images with other satellite and in situ data supported and enhanced our interpretation of SAR signatures.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.1124-1126
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• 2003

The processes of regional scales in the East Korean coastal waters were investigated by analysis of the Synthetic Aperture Radar (SAR) images taken by the European Research Satellites ERS-1, ERS-2 and Envisat. More than 500 quick look frames taken in 1991-2003 were examined to detect the frames with clearly surface expressions of oceanic phenomena. 26 ERS-1/2 SAR and 11 Envisat wide swath Advanced SAR (ASAR) frames were selected and obtained from the European Space Agency in a form of the precision high-resolution images. The following oceanic phenomena and processes were evident in the radar imagery through the Korean costal waters: fronts, currents, eddies, internal waves, island and ship wakes, oil pollution, etc. They manifested themselves in the field of sea surface roughness, their scale ranged from several tens meters to about 100 km. The most common morphology of these phenomena was a series of contrast dark or light curvilinear lines and bands. The joint analysis of the discussed SAR images with other satellite and in situ data supported and enhanced our interpretation of SAR signatures.

• The Korean Journal of Pesticide Science
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• v.17 no.4
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• pp.314-334
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• 2013

This study explored an efficient modified Quick, Easy, Cheap, Effective, Rugged and safe (QuEChERS) method combined with liquid chromatography-electrospray ionization with tandem mass spectrometric detection for the analysis of residues of 76 pesticides in brown rice, barley and corn including acidic sulfonylurea herbicides. Formic acid (1%) acid in acetonitrile and dispersive solid phase extractions used for extraction of pesticides and clean-up of the extract respectively. Two fortified spikes at 50 and 200 ng $g^{-1}$ levels were performed for recovery test. Mean recoveries of majority of pesticides at two spike levels ranged from 73.2 to 132.2, 80.9 to 136.8, 66.6 to 143.5 for brown rice, barley and corn respectively with standard error (CV) less than 10%. Good linearity of calibration curves were achieved with $R^2$ > 0.9907 within the observed concentration ranged. The modified method also provided satisfactory results for sulfonylurea herbicides. The method was applied to the determination of residues of target pesticides in real samples. A total of 26 pesticides in 36 out of 98 tasted samples were observed. The highest concentration was observed for tricyclazole at 1.17 mg $kg^{-1}$ in brown rice. This pesticide in two brown rice samples exceeded their MRLs regulated for rice in republic of Korea. Except tricyclazole none of the observed pesticides' concentration was higher than their MRLs. The results reveal that the method is effectively applicable to routine analysis of residues of target pesticides in brown rice, barley and corn.

• Analytical Science and Technology
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• v.36 no.5
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• pp.205-215
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• 2023

In the present study, an analytical method was proposed for detecting trifluralin in aquatic products at trace concentrations. The method employed QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) and gas chromatography coupled with tandem mass spectrometry (GC-MS/MS) as the sample preparation and measurement, respectively. The effect of the aqueous phase volume used in the QuEChERS was demonstrated, and the ratio of 10:10 (mL) between water and acetonitrile phase was used for 5 g of sample. Besides, dSPE using C18 and primary-secondary amine (PSA) was applied to remove the potential interferences from the food matrices, indicating no remarkable analyte loss. The linear range was built up from 0.50 ㎍ L^-1 to 3.0 ㎍ L^-1 (R² = 0.9993). Other criteria, i.e., repeatability (RSD_r = 0.86-1.96 %), reproducibility (RSD_R = 1.09-2.01 %), and recovery (over 90 %), were in accordance with Appendix F of AOAC (2016) for method performance. Although no trifluralin was detected for the commercial samples (fish, shrimp, and breaded shrimp), the spiked samples performed favorable recoveries and precision.

• Korean Journal of Veterinary Service
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• v.34 no.4
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• pp.429-439
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• 2011

This article described the comparison of a quick, easy, cheap, effective, rugged and safe (QuEChERS) sample preparation and the classical method established by National Veterinary Research and Quarantine Service (NVRQS) for the determination of pesticide residues in livestock products using GC-tandem mass spectrometry. The classical method by NVRQS used liquid-liquid partioning followed by evaporizing. The modified QuEChERS entailed extraction of 2 g sample with 15 ml acetonitrile containing 1% acetic acid followed by addition of 6 g anhydrous magnesium sulfate and 1.5 g sodium acetate. After centrifugation, 6 ml of the extract underwent a cleanup step (in a technique known as column-based solid phase extraction) using 400 mg each of $C_{18}$ and primary secondary amine sorbents plus 1,200 mg magnesium sulfate. The quantitation of individual pesticides by both methods was based on tissue standard calibration curves with a correlation coefficient in excess of 0.98 for the 24 pesticides. The detection limits by the classical method were ranged 1.3~5.0 ${\mu}g$/kg, with mean recoveries between 76.2% and 114.3% except aldrin (59.3%) and deltamethrin (63.6%). The detection limits by modified QuEChERS were ranged 0.3~6.2 ${\mu}g$/kg, with mean recoveries between 68.0% and 114.3% except dimethipin (152.6%), chlorfenvinphos (138.1%), 4,4-DDT (61.5%), aldrin (60.4%) and chinomethionate (30.3%).

• Journal of Environmental Science International
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• v.16 no.3
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• pp.269-275
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• 2007

The standard emission rate(ERs) of isoprene was quantitatively measured in situ from Quercus mongolica Fischer that dominates more than about 85% of domestic oak trees. The ERs values in spring and summer were similar to 64.4 and 58.1 (${\mu}gC/gdw/hr$), respectively. The ERs in autumn, 7.06(${\mu}gC/gdw/hr$), was about $8{\sim}9$ times lower than those in spring and summer. The coefficient of determination ($r^2$) between ERs and $C_L\;C_T$ ranged from 0.593 to 0.836. The correlation coefficients between the ERs and PAR. the ER and temperature suggested that ERs have strong correlation with PAR(photosynthetically active radiation) and temperature. In addition, the high values of PAR, temperature, and ERs were found in the time zone of $15:00{\sim}17:00$(spring), $15:00{\sim}16:00$(summer), and $14:00{\sim}15:00$(autumn).

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.296-313
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• 2014

A QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) multiresidue method was developed for the simultaneous analysis of 124 pesticides in soil by LC-MS. The procedure involved liquid extraction of soil immersed with 0.2N $NH_4Cl$ by acetonitrile with 1% acetic acid, followed by anhydrous $MgSO_4$ and sodium acetate, and dispersive SPE cleanup with $MgSO_4$, primary secondary amine (PSA) and $C_{18}$. The extracts were analyzed with LC-MS/MS in ESI positive mode. Standard calibration curves were made by matrix matched standards and their correlation coefficients were higher than 0.99. Recovery studies for the validation were carried out using two type soils, loam and sandy loam, at four concentration levels (0.005, 0.01, 0.02, and 0.1 mg/kg). The recoveries of pesticides were in the range of 70-120% with < 20% RSD except 4 pesticides, Benfuracarb, Ethiofencarb, Pymetrozine, and Pyrethrin. This result indicated that the method using QuEChERS and LC-MS/MS could be applied for the simultaneous determination of pesticide residues in soils.