• Korean Journal of Veterinary Service
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• v.42 no.4
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• pp.289-296
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• 2019

A novel rapid procedure with liquid chromatography tandem mass spectrometry (LC-MS/MS) detection has been developed by changing various conditions including sample preparation such as QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) methodology. This work has been involved the optimization and validation of detection method for fluoroquinolones which are widespread used in livestock especially in the chicken. Five grams of homogenized chicken muscle were extracted with QuEChERS EN and acetonitrile containing 5% formic acid and cleaned with anhydrous magnesium sulfate and C₁₈ sorbent. The separation was performed on Acquity UPLC HSS T3 (2.1 mm×100 mm, 1.8 ㎛) column. The mobile phase A and B were composed of water containing 0.1% formic acid and acetonitrile containing 0.1% formic acid, respectively. Flow rate was 0.25 mL/min and column temperate was 40℃. LC-MS/MS with multiple reaction monitoring has been optimized for ten fluoroquinolones (ciprofloxacin, danofloxacin, difloxacin, enrofloxacin, marbofloxacin, norfloxacin, ofloxacin, orbifloxacin, pefloxacin and sarafloxacin). The method developed in this study has been presented good linearity with correlation coefficient (R²) of 0.9971~0.9998. LOD and LOQ values ranged from 0.09 to 0.76 ppb and from 0.26 to 2.29 ppb, respectively. The average recoveries were from 77.46 to 111.83% at spiked levels of 10.0 and 20.0 ㎍/kg. Relative standard deviation (%) ranged 1.28~11.90% on intra-day and 3.10~8.38 % on inter-day, respectively. This analysis method was applicable to the livestock residue laboratories and was expected to be satisfactory for the residue surveillance system.

• Journal of Wetlands Research
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• v.8 no.3
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• pp.29-38
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• 2006

Digital Elevation Model (DEM) of intertidal flat can be widely used not only for scientific fields, coastal management, fisheries, ocean safety, military, but also for understanding natural and artificial topographic changes of the tidal flat. In this study, we generated DEM of the Ganghwado southern intertidal flat, the largest tidal flat in the west coast of the Korean Peninsula, using waterline method and interferometric synthetic aperture radar (InSAR). Constructed DEM which applied waterline method to the Landsat-5 TM and Landsat-7 ETM+ images closely expresses overall topographic relief of tidal flat. We found that the accuracy was determined by the number of waterlines which reflect various tidal conditions. The application of InSAR to the ERS-1/2 and ENVISAT images showed that only ERS-1/2 tandem pairs successfully generated DEM in the part of northern Yeongjongdo, but construction of DEM in the other areas was difficult due to the low coherence caused by a lot of surface remnant waters. In the near future, Kompsat-2 will provide satellite images having multi-spectral and high spatial resolution within a relatively short period at different sea levels. Application of waterline method to these images will help us construct a high precision tidal flat DEM. Also, we should develop DEM generation method using single-pass microwave satellite images.

• Korean Journal of Remote Sensing
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• v.21 no.4
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• pp.287-302
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• 2005

Digital Elevation Models (DEMs) were generated by ERS-l/2 and JERS-1 SAR interferometry in Daejon area, Korea. The quality of the DEM's was evaluated by the Ground Control Points (GCPs) in city area where GCPs were determined by GPS surveys, while in the mountain area with no GCPs, a 1:25,000 digital map was used. In order to minimize errors due to the inaccurate satellite orbit information and the phase unwrapping procedure, a Differential InSAR (DInSAR) was implemented in addition to the traditional InSAR analysis for DEM generation. In addition, DEMs from GTOPO30, SRTM-3, and 1:25,000 digital map were used for assessment the resolution of the DEM generated from DInSAR. 5-6 meters of elevation errors were found in the flat area regardless of the usage and the resolution of DEM, as a result of InSAR analyzing with a pair of ERS tandem and 6 pairs of JERS-1 interferograms. In the mountain area, however, DInSAR with DEMs from SRTM-3 and the digital map was found to be very effective to reduce errors due to phase unwrapping procedure. Also errors due to low signal-to-noise ratio of radar images and atmospheric effect were attenuated in the DEMs generated from the stacking of 6 pairs of JERS-1. SAR interferometry with multiple pairs of SAR interferogram with low resolution DEM can be effectively used to enhance the resolution of DEM in terms of data processing time and cost.

• Korean Journal of Remote Sensing
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• v.27 no.5
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• pp.535-542
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• 2011

We extracted a surface displacement map of Canisteo Peninsula and the surrounding area in West Antarctica by applying 4-pass DInSAR technique to two ERS-1/2 tandem pairs and analyzed the surface displacement of glaciers and sea ice. In the displacement map, glaciers showed fast motion pushing the adjoining land-fast sea ice which has the displacement in the same direction as the glacier. Cosgrove ice shelf showed large displacement pushing the adjoining land-fast sea ice as well. Some sea ice indicated the displacement that is opposite to the land-fast sea ice. This was because the type of the sea ice is drift ice that is affected by ocean current. Therefore, we could confirmed the boundary between land-fast sea ice and drift ice. It was difficult to distinguish ice shelf from ice sheet because they showed similarities both in brightness of the SAR images and in fringe rates of the interferograms. However, a boundary between fast-moving ice shelf and stable ice sheet was easily confirmed in the displacement map after the phase unwrapping process.

• Journal of fish pathology
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• v.34 no.2
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• pp.261-269
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• 2021

This study presents the evaluation of sample extraction and purification procedure for the determination of residues of febantel and its metabolites, fenbendazole, oxfendazole and oxfendazole sulfone in rockfish (Sebastes schlegeli) muscle using liquid chromatography-tandem mass spectrometry. Residues of febantel and its metabolites in rockfish muscle were analyzed using each different sample preparation method from Korean Food Standards Codex (KFSC), Food Safety and Inspection Service (FSIS, USA), and the modified FSIS method using QuEChERS kit (FSIS-Q), respectively. Each method was compared for mean recoveries and repeatabilities. Since FSIS-Q showed higher repeatabilities (coefficient of variation, CV of 2.4%~10.9%) than those of FSIS method (CV of 4.6%~17.5%), recoveries from FSIS-Q were compared with those from KFSC method. FSIS-Q showed significantly higher recoveries of 83.1%~110.1% (P < 0.05) than those from KFSC method of 64.7%~107.4%. In addition, FSIS-Q showed a good linearity over the range of 2.5~200 ㎍/kg, and excellent sensitivities with limit of detection of 0.46~0.71 ㎍/kg and limit of quantification of 1.08~2.15 ㎍/kg. Although all the sample preparation methods turned out to be able to meet CODEX guideline for all the compounds, FSIS method and FSIS-Q validated in this study could be applied to screening and quantification for residues of febantel and its metabolites in rockfish muscle with efficient preparation procedures.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.414-417
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• 2008

We have extracted a surface deformation map of a part of Canisteo Peninsula on Amundsen Sea in West Antarctica by applying 4-pass DInSAR technique to two ERS-1/2 tandem pairs obtained on October 21-22, 1995 (diff-pair) and March 9-10, 1996 (topo-pair), and analyzed changes of glaciers, sea ice, ice shelves, and their kinematic interactions. We observed fast motion of glaciers pushing the adjoining sea ice. Some interferometric phases indicate the up-rise of sea ice of which type is thought to be land-fast ice to exert repulsive force against the pushing glacier. There were other glaciers and sea ice that moved to the same direction, suggesting that the sea ice in these regions was land-fast ice weakly harnessed to sea bottom or pack ice not harnessed at all. Several small circular fringes in ice shelves suggested that islands or seamounts on the bottom of ice shelves deterred the movement of ice shelves, resulting in the rise of ice surface.

• The Korean Journal of Pesticide Science
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• v.17 no.4
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• pp.314-334
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• 2013

This study explored an efficient modified Quick, Easy, Cheap, Effective, Rugged and safe (QuEChERS) method combined with liquid chromatography-electrospray ionization with tandem mass spectrometric detection for the analysis of residues of 76 pesticides in brown rice, barley and corn including acidic sulfonylurea herbicides. Formic acid (1%) acid in acetonitrile and dispersive solid phase extractions used for extraction of pesticides and clean-up of the extract respectively. Two fortified spikes at 50 and 200 ng $g^{-1}$ levels were performed for recovery test. Mean recoveries of majority of pesticides at two spike levels ranged from 73.2 to 132.2, 80.9 to 136.8, 66.6 to 143.5 for brown rice, barley and corn respectively with standard error (CV) less than 10%. Good linearity of calibration curves were achieved with $R^2$ > 0.9907 within the observed concentration ranged. The modified method also provided satisfactory results for sulfonylurea herbicides. The method was applied to the determination of residues of target pesticides in real samples. A total of 26 pesticides in 36 out of 98 tasted samples were observed. The highest concentration was observed for tricyclazole at 1.17 mg $kg^{-1}$ in brown rice. This pesticide in two brown rice samples exceeded their MRLs regulated for rice in republic of Korea. Except tricyclazole none of the observed pesticides' concentration was higher than their MRLs. The results reveal that the method is effectively applicable to routine analysis of residues of target pesticides in brown rice, barley and corn.

• Spatial Information Research
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• v.9 no.1
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• pp.1-13
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• 2001

Nowadays, SAR Interferometry is actively being studied as a new technique in topographic mapping using satellite imagery. It extracts height values using phase information derived by two SAR imageries covering same areas. Unlike when using SPOT imagery, it is not affected by atmospheric conditions and time. So to speak, we can say that SAR Interferometry is flexible in imagery acquisitions and can get height data economically over wide area. So, it is expected that SAR Interferometry will be widely using in GIS applications. But, in some area occurring geometric distortion, height data are misjudged or not extracted depending on phase unwrapping algorithms. IN the case of ERS tandem data, the accuracy of height data was worst in mountain area. It is the because of the short incidence angle resulted in layover effect. Of the phase unwrapping algorithms, path-following was better in height accuracy but could not get data in layover area. In this area, we could get height data using Height Sensitivity. In concludion, we could get DEM that maintained the accuracy of path-following method and have overall data across imagery.

• Proceedings of the KSRS Conference
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• 2009.03a
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• pp.190-195
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• 2009

서남극 빙상의 감소 속도는 급격히 가속화되고 있으며, 전 지구적 해수면 상승과 기후변화 예측을 위해 이 지역에 대한 지속적인 관찰이 요구되고 있다. 본 연구에서는 서남극 Canisteo 반도와 주변 지역이 촬영된 2쌍의 ERS-1/2 tandem pair에 4-pass 위상차분간섭기법을 적용하여 위상차분간섭도를 생성하였고, 빙하와 해빙, 그리고 빙붕의 표면 변화를 관찰하였다. 위상차분간섭도에서 센서 방향으로의 변위를 추출한 결과 해안 빙하와 그에 인접한 정착빙은 같은 방향의 움직임을 나타냈다. 특히 빙하와 맞닿은 부분의 정착빙은 그 움직임이 다른 부분에 비해 컸는데, 이는 빙하의 하강 및 유실이 해빙에 영향을 끼치는 것으로 판단된다. 정착빙의 가장자리에 위치한 해빙은 해류의 영향에 기인하는 움직임을 보였으며, 이 해빙의 유형이 부빙 또는 유빙임을 알 수 있었다. 반도 양옆에 위치한 빙붕은 모두 센서 방향으로의 움직임을 보였으나 그 크기에서 차이를 나타냈다. 빙붕의 표면에서는 원형의 국부적 함몰이 다수 관찰되었는데, 이는 남극저층수의 적은 유입으로 인해 형성된 melt pond로 추정된다.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.28 no.5
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• pp.505-513
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• 2010

This study investigate the characteristics of tidal constituents, and long-term mean sea level oscillations at Incheon bay. For this, the conditions of three tide stations around Incheon bay have examined, and carried out harmonic analysis on water level data for periods of about 40 years(1960~2007). Four major tidal constituents($M_2$, $S_2$, $K_1$, $O_1$) of each tide station showed tendency that change over the 18.61year lunar node cycle, and the type of tide at three stations is mainly semi-diurnal tides. And also, the past monthly tidal modulations are especially sensitive to the cumulative year of water level data in accuracy of tidal prediction. In case that regard the detached data at three tide stations as a single time series data of 40 years, the results of analysis on a single time series, long-term mean sea level oscillations and modulations of tidal datum at tide stations appears with a range of about 10cm, respectively. In addition, the predicted tides at the Inchcon harbor by global and regional tide models of OSU(Oregon State University) based on various satellite altimetric(Topex Poseidon, Topex Tandem, ERS, GFO) data are compared with the observed tides by KHOA(the Korea Hydrographic and Oceanographic Administration). The results show that the high resolution regional model is a quite good agreement at coastal shallow water region.