• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.11a
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• pp.140.2-140.2
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• 2004

• 발명특허
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• v.33 no.7
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• pp.68-71
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• 2008

• Korean Journal of Materials Research
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• v.11 no.12
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• pp.1074-1079
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• 2001

To study the distribution of boron and the boron effect for nucleation of graphite in high carbon steel, neutron induced autoradiography method is used. High carbon steel is easy to make the graphitization by addition of boron. It is easy to analysis of boron distribution using neutron radiography with neutron fluence of $1.9$\times${\times}10^{13}/cm^2$in the boron added high carbon steel. By the neutron induced autoradiography technique, it was found that the distribution of boron depended on boron content, graphitiging temperature and time. And by the analysis of secondary ion mass spectroscopy (SIMS) and electron probe micro analysis (EPMA), boron or boride were acted at nucleation site of graphite in high carbon steel.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.192-197
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• 1998

사용후핵연료는 열전도도가 극히 불량하다. 그러므로 지금까지는 파단면을 관찰하거나 또는 성분분석을 위해 EPMA을 이용할 때는 시편 표면을 Au나 란소 등으로 증착시키고 있다 그러나 사용후 핵연료에서는 강력한 방사선이 방출되므로 시편의 증착처리는 핫셀(hot cell)에서 원격조정기(manipulator)를 사용하여 수행하므로 많은 어려움이 있다. 특히 시편 표면의 Au나 탄소의 증착시에는 균일한 증착이 필요한데, 핫셀내에 설치한 기기는 유지 보수의 어려움으로 양호한 진공도 유지가 어려워 시편 표면의 균질한 증착은 문제점으로 되어 있다. 이에 본 연구에서는 이산화우라늄 소결체를 표면의 증착처리 없이도 파단면 관찰이나 성분 분석을 할 수 있는 방법을 연구하여 silber paint법을 개발하였다. 특히 탄소가 미량 함유된 시편을 탄소 증착처리를 하면 증착된 탄소와 시편에 함유된 탄소를 분리해야 하는 어려운 점이 있으므로 이러한 경우에는 silber paint 법이 아주 편리하다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2009.11a
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• pp.311-312
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• 2009

가압 경수로에서 53,000 MWd/tU으로 연소된 사용후 핵연료의 PCI 영역에 대해 방사선 차폐형 성분 분석기기( Shielded EPMA)를 사용하여 반경방향에 대한 성분분포를 분석하였다. PCI 영역에서 산화층의 두께는 13um 이었으며, 핵분열생성물의 침투 두께는 시료에서 약 10 um 이내로 나타났다. 이 두께에 침투된 핵종의 총 농도는 1~2 wt%로 관찰되었다. 주요핵종은 Cs 0.5~0.7 wt%, Mo 0.2~0.3 wt%, Pd, Ru, Nd, Ce등이 0.1~0.2 wt% 로 관찰되었다.

• Nuclear Engineering and Technology
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• v.21 no.4
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• pp.341-345
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• 1989

The distribution behaviors of beryllium which may produce a deleterious damage in the zircaloy cladding have been investigated by the X-ray line scanning of EPMA. The results obtained are as follows; 1) The alloy phase formed by the brazing contains ~6.3 mass % of beryllium. 2) The beryllium diffusion in the base metal (cladding and bearing pad) is recognized only in the range ~5 $\mu$m from the brazing interface.

• Journal of the Korean Ceramic Society
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• v.23 no.2
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• pp.55-63
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• 1986

In variuos physcial and chemical cause of damage of refractories for steel makin the clarification of the wear mechanism of brick is situated on important factor. In the present paper the wear mechanism of high alumina brick for the arc-furnace roof were inves-tigated by means of XRD, EPMA. SEM and microscopy. The results obtained were summerized as follows : (1) The altered layers which exist in high alumina brick used for arc-furnace roof were verified by mineral chemical analysis and EPMA. (2) The diffusion of materials combined with slag dust and iron oxide from furnace atmosphere in high basic process from hot face to interior was verified. (3)Activation energy for the synthesized slag permeated into the unused brick texture was 47-51 kcal per mole.

• Journal of the Korean Ceramic Society
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• v.33 no.6
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• pp.623-630
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• 1996

A Sol-gel derived ferroelectric PbTiO3 thin film was synthesized by using diethanolamine (DEA) as a comple-xing agent. Surface chemical analyses were examined in order to study the effect of heating temperature on the composition of thin film by EPMA and XPS. A rapid volatilization of lead was observed in the films fired at $700^{\circ}C$ or higher and the ratio of Pb:Ti was found to be 34:66. A depth profile by Ar+ showed that the Ar sputtering decreased Pb amount of inner part of the film resulting in Ti-rich phase near the surface of the film.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1999.10a
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• pp.190-196
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• 1999

Hot forgeability of STD 61 steel was boronzed in boronizing paste mainly consisted of B4C and Na2B4O7 at various temperatures and times. Microhardness and thickness of boride layers were measured and distributions of B, Si, Cr and V on the cross section of specimen were observed by EPMA line analysis. Microscopic examination and results of EPMA showed that the boride layer consisted of two layers outer layer of FeB and inner layer of Fe2B. Microhardness of these boride layers was in the range of Hv 1800~2300. Thickness of boride layer increased with times and temperatures. Si-rich $\alpha$ layer was formed between boride layer and matrix. Element such as Cr concentration as Cr23(B, C)6 beneath the boride layer.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.11a
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• pp.392-393
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• 2003

우리나라의 폐기물 발생총량은 꾸준히 증가추세를 보이는 가운데, 최근 생활폐기물의 처리현황을 보면 재활용이나 소각이 매년 증가하고 있다. 쓰레기 소각율이 높아지고 대형 소각시설이 증가하면서부터 소각 후에 발생하는 도시 소각재의 처리 및 재활용의 문제가 중요한 관심사가 되고 있다. 소각재의 효과적이고 안전한 취급을 위해서는 그것의 화학적 성질에 관한 지식이 중요하다. Kirby and Rimstldt$^{[1]}$ 는 Charlotte (USA)에 소재하는 두 곳의 소각로에서 나온 Municipal Solid Waste (MSW) ash를_체계적으로 분석하여 화학적 조성에 대한 연구를 행한 바 있다. (중략)