• Title/Summary/Keyword: EPA method

Search Result 250, Processing Time 0.027 seconds

A Study on the Change of Condensable Particulate Matter by the SO2 Concentration among Combustion Gases (연소 배출가스 중 SO2 농도에 따른 응축성먼지 변화에 관한 연구)

  • Yu, JeongHun;Lim, SeulGi;Song, Jihan;Lee, DoYoung;Yu, MyeongSang;Kim, JongHo
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.34 no.5
    • /
    • pp.651-658
    • /
    • 2018
  • Particulate matter (PM) emitted from fossil fuel-combustion facilities can be classified as either filterable or condensable PM. The U.S. Environmental Protection Agency (EPA) defined condensable PM as material that is in the phase of vapor at the stack temperature of the sampling location which condenses, reacts upon cooling and dilution in the ambient air to form solid or liquid in a few second after the discharge from the stack. Condensable PM passed through the filter media and it is typically ignored. But condensable PM was defined as a component of primary PM. This study investigates the change of condensable PM according to the variation in the sulfur dioxide of combustion gas. Domestic oil boilers were used as the source of emission ($SO_2$) and the level of $SO_2$ concentration (0, 50, 80, and 120 ppm) was adjusted by diluting general light oil and marine gas oil (MGO) that contains sulfur less than 0.5%. Condensable PM was measured as 2.72, 6.10, 8.38, and $13.34mg/m^3$ when $SO_2$ concentration in combustion gas were 0, 50, 80, and 120 ppm respectively. The condensable PM tended to increase as the concentration of $SO_2$ increased. Some of the gaseous air pollutants emitted from the stack should be considered precursors of condensable PM. The gas phase pollutants which converted into condensable PM should reduced for condensable PM control.

A Prediction Model for TVOC and HCHO Emission of Paint Materials (페인트에서 방출되는 TVOC 및 HCHO 방출량 예측모델)

  • Kim, Hyung-Soo;Lee, Kyung-Hoi
    • KIEAE Journal
    • /
    • v.3 no.1
    • /
    • pp.13-20
    • /
    • 2003
  • It is highly recognized that there is need for protection against indoor air pollution, as we realize environmental pollution is growing, For example, in an indoor environment, a person spends more than 80 percent of their time inside the building. Thus, concern about indoor decoration materials is growing, since they cause pollution in the rooms of an apartment, as well as in offices. As the indoor decoration materials become more diverse and lusurious, so the effect of VOCs(Volatile Organic Compounds) and HCHO(Formaldehy) is growing. The indoor decoration materials cause the Sick Building Syndrome, such as headaches, dizziness, or lack of concentraion, and they in turn cause serious deterioration in people's health. In this study, I probed the status of the indoor air pollution and carried on an investigation and analysis about the prevention technique. In doing so, I performed experimental tests and an assessment of the indoor decoration materials of an apartment. I also examined elements of the emitted and the emission. Finally, I examined the character of emissions, by changing environmental conditions, such as the temperature, humidity, and ventilation. With respect to VOCs tests, I applied the method of solid state adsorption using the adsorptive tube, based on the measurement of the American EPA TO-17, ASTM 5116-97, and the measurement of the Japanese Wall Decoration Industrial Association. The tested sample was analyzed by High Performance Liquid Chromatography, after going through the process of dissolvent extraction. As subjects of the test, Paint were selected. The process of this test is as follows; first, I figured out the character of the emission, by measuring the emitted concentration of VOCs and HOHC from the indoor decoration materials of an apartment. Second, I made a small-scale chamber and the test was processed in the chamber in order to suggest an environment-friendly prediction modlel development.

HEALTH RISK ASSESSMENT OF HOUSEHOLD EXPOSURE TO INDOOR RADON IN ASSOCIATION WITH THE DWELLING'S AGE

  • Shahrokhi, Amin;Shokraee, Forough;Reza, Ali;Rahimi, Hasn
    • Journal of Radiation Protection and Research
    • /
    • v.40 no.3
    • /
    • pp.155-161
    • /
    • 2015
  • Radon is a naturally occurring radioactive gas and a major indoor contribution of exposure to ionizing radiation in dwellings. $^{222}Rn$ is a health hazard gas what is responsible for thousand lung cancer deaths every year. In this study, indoor radon concentrations present in thirty representative houses in Mahallat city, Iran, were determined in order to estimate lung cancer risk associated with residential radon exposure. Long-term passive method, using CR-39, was used to measure the radon concentration. The results showed an association between the age of the dwellings and the indoor radon concentration that was found, in that the concentration of radon tended to increase as the age of the dwelling also increased. The indoor radon concentrations were calculated to be within the range of $23{\pm}2$ to $350{\pm}26Bq{\cdot}m^{-3}$, with an average of $158Bq{\cdot}m^{-3}$. The annual effective dose from inhaled radon and its decay products was calculated between $0.8{\pm}0.1$ and $12.3{\pm}0.9mSv{\cdot}y^{-1}$, with an average of $5.5mSv{\cdot}y^{-1}$. By taking into consideration the EPA recommendation and ICRP statement, the average annual risk of lung cancer from inhaled radon was calculated as 0.09%, 0.06%, 0.01%, and 0.03% for current smokers (CS), those who had ever smoked (ES), never smokers (NS) and the general population, respectively.

Estimation of Nutrients Reduction Rates to Prevent Eutrophication on the Hwaong Reservoir (화옹호의 부영양화 방지를 위한 영양염류 삭감률 산정)

  • Kim, Mi-Ah;Kim, Young-Hee;Lee, Hong-Keun;Hwang, Dae-Ho;Kim, Ji-Young
    • Journal of Korean Society on Water Environment
    • /
    • v.20 no.6
    • /
    • pp.589-596
    • /
    • 2004
  • In this study, the reduction rates of nutrients were suggested to prevent eutrophication on the Hwaong reservoir in the year of 2008 and 2012. With EPA's WASP6 model, future water quality were simulated. In 2008, T-N would be 1.36mg/L and T-P 0.100mg/L on average. ; In 2012, T-N 2.66mg/L and T-P 0.128mg/L. With all the water quality management plans that the government authorities are carrying out, these results indicate that the reservoir would be reach the eutrophic or hypertrophic state according to the Vollenweider's trophic states. Therefore, the Hwaong reservoir requires additional plans for nutrients management. Here, the target water quality to prevent eutrophication of the reservoir sets into mesotrophic state ; T-N 0.475mg/L and T-P 0.02mg/L.(median of Vollenweider index for mesotropphic state) The reduction rates of nutrients on Namyang and Eoeun streams were estimated with uniform treatment method to meet the goal. The results showed that nutrients from two streams should be reduced up to 78% in 2008, and 84% in 2012. Since the ratio of T-N/T-P would be higher than 16 at target years, T-N was not considered as the limiting factor and was not reduced.

Investigation of N2O Emission and Reduction Effect from MSW Incineration Plant (도시고형폐기물 소각시설에서 발생하는 N2O 발생량 조사 및 저감효과에 관한 연구)

  • Song, Hyun-Ok;Ko, Jae-Churl;Choi, Sang-Hyun;Kim, Duk-Hyun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.39 no.12
    • /
    • pp.672-678
    • /
    • 2017
  • In this study, municipal solid waste (MSW) has collected 3 times and physico-chemical analysis has done. Nitrous oxide emissions from MSW incineration plant were measured continuously by EPA Method 18 and it was compared with the emission by calculation using the emission factor. The $N_2O$ emission of MSW incineration plant was more than twice as large as the emission by calculation. It was found that the installation of abatement facilities in MSW incineration plant is effective in achieving the greenhouse reduction targets and it can be ensure economical efficiency through emission trading system.

Electrochemical Behaviors of Hydroquinone on a Carbon Paste Electrode with Ionic Liquid as Binder

  • Sun, Wei;Jiang, Qiang;Yang, Maoxia;Jiao, Kui
    • Bulletin of the Korean Chemical Society
    • /
    • v.29 no.5
    • /
    • pp.915-920
    • /
    • 2008
  • In this paper the electrochemical behaviors of hydroquinone ($H_2Q$) were investigated on a carbon paste electrode using room temperature ionic liquid N-butylpyridinium hexafluorophosphate ($BPPF_6$) as binder (ILCPE) and further applied to $H_2Q$ determination. In pH 2.5 phosphate buffer solution (PBS), the electrochemical response of H2Q was greatly improved on the IL-CPE with a pair of well-defined quasi-reversible redox peaks appeared, which was attributed to the electrocatalytic activity of IL-CPE to the $H_2Q$. The redox peak potentials were located at 0.340 V (Epa) and 0.240 V (Epc) (vs. the saturated calomel electrode, SCE), respectively. The formal potential ($E^0$') was calculated as 0.290 V and the peak-to-peak separation (${\Delta}E_p$) was 0.100 V. The electrochemical parameters of $H_2Q$ on the IL-CPE were further calculated by cyclic voltammetry. Under the selected conditions the anodic peak current was linear with $H_2Q$ concentration over the range from $5.0\;{{\times}}\;10^{-6}$ to $5.0\;{\times}\;10^{-3}\;mol\;L^{-1}$ with the detection limit as $2.5\;{\times}\;10^{-6}\;mol\;L^{-1}$ (3$\sigma$ ) by cyclic voltammetry. The proposed method was successful applied to determination of $H_2Q$ content in a synthetic wastewater sample without the interferences of commonly coexisting substances.

Human Risk Assessment of Perchloroethylene Considering Multi-media Exposure (다매체 노출을 고려한 Perchloroethylene의 인체위해성평가연구)

  • Seo, Jungkwan;Kim, Taksoo;Jo, Areum;Kim, Pilje;Choi, Kyunghee
    • Journal of Environmental Health Sciences
    • /
    • v.40 no.5
    • /
    • pp.397-406
    • /
    • 2014
  • Objectives: Perchloroethylene (PCE) is a volatile chemical widely used as a solvent in the dry-cleaning and textile processing industries. It was evaluated as Group 2 "probably carcinogenic to humans" by the Integrated Risk Information System (IRIS) of the United State Environmental Protection Agency (U.S. EPA) in 2012. In order to provide a scientific basis for establishing risk management measures for chemicals on the national priority substances list, aggregate risk assessment was conducted for PCE, included in the top-10 substances. Methods: We conducted the investigation and monitoring of PCE exposure (e.g., exposure scenario, detection levels, and exposure factors, etc.) and assessed its multi-media (e.g., outdoor air, indoor air, and ground water) exposure risk with a deterministic and probabilistic approach. Results: In human risk assessment (HRA), the level of human exposure was higher in the younger age group. The exposure level through inhalation at home was the highest among the exposure routes. Outdoor air or uptake of drinking water represented less than 1% of total contributions to PCE exposure. These findings suggested that the level of risk was negligible since the Hazard Index (HI) induced by HRA was below one among all age groups, with a maximum HI value of 0.17 when reasonable maximum exposure was applied. Conclusion: In conclusion, it was suggested that despite low exposure risk, further studies are needed considering main sources, including occupational exposure.

Meteorological Field Generation Method for CALPUFF Model

  • Park, Ji-Hoon;Park, Geun-Yeong
    • Journal of Integrative Natural Science
    • /
    • v.11 no.1
    • /
    • pp.30-38
    • /
    • 2018
  • CALPUFF is one of the recommended air pollution models by EPA with AERMOD. It has been used to simulate the ambient concentration of critical air pollutants as well as non-critical pollutants such as persistent organic matters and the organic materials causing odor. In this model, the air pollutants go through dispersion, transportation, chemical reaction, and deposition process. These mechanisms are significantly influenced by meteorological condition. This study produces the meteorological field in three different methods for the simulation of $SO_2$ using CALPUFF: 1) CALMET model by using both ground-level and aerological observation, 2) CALMET model by using MM5 results with NCEP/NCAR reanalyzed data, 3) CALMET model by using MM5 results in which FDDA is applied with NCEP/NCAR reanalyzed data as well as the meteorological data of Korea Meteorological Administration. As a result of CALPUFF model, the resolved concentration of $SO_2$ showed different behaviors in three cases. For the first case, the fluctuation of SO2 concentration was frequently observed while the fluctuation is reduced in the second and third cases. In addition, the maximum concentration of $SO_2$ in the first case was about 2~3 times higher than the second case, and about 4~6 times higher than the third case. These results can be caused by the accuracy of the resolved meteorological field. It is inferred that the meteorological field of the first case could be less accurate than other two cases. These results show that the use of correct meteorological data can improve the result of dispersion model. Moreover, the contribution of various sources such as point, line, and area sources on the ambient concentration of air pollutant can be roughly estimated from the sensitivity analysis.

Analysis of the Linkage Effect by Component Technology in Low Impact Development Facilities (저영향개발 시설의 요소기술별 연계 효과 분석)

  • Baek, Jongseok;Lee, Sangjin;Shin, Hyunsuk;Kim, Jaemoon;Kim, Hyungsan
    • Journal of Korean Society on Water Environment
    • /
    • v.35 no.1
    • /
    • pp.35-42
    • /
    • 2019
  • Urbanization has led to extreme changes in land use on urban watersheds. Most cities are becoming residential, commercial and industrial areas, making infiltration and storage of rainfall less favorable. The demand for LID (Low Impact Development) technology is increasing in order to mitigate this water cycle distortion and return to existing hydrological conditions. The LID technique is effective in reducing runoff by permeating the urban impervious area. However, considering the limit of the installation area and the financial requirement of the installation, there is not much research on the linkage of each LID component technology for optimum efficiency according to the appropriate scale. In this study, the effects of the LID facilities applied to the target site were simulated using the SWMM model, suggesting the optimal linkage method considering interconnectivity, and applying the effects as an existing installation of individual facilities. The water balance at the time of application of the LID technology, short-term and long-term rainfall event were compared. Also, the individual application and the linkage application were compared with each other. If each component technology has sufficient processing size, then linkage application is more effective than individual application.

Estimation of citizens' Willing To Pay for water quality improvement on urban rivers (도시하천 수질 개선을 위한 도시민의 지불의사 추정)

  • Kang, Ji Yoon;Kim, Keewook
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2022.05a
    • /
    • pp.463-463
    • /
    • 2022
  • 도시하천은 급속한 경제성장과 개발 등 여건변화에 따라 크게 변화되어왔다. 이에 하천은 본연의 모습과 가치를 잃고 인공적인 모습으로 변해 하천의 주요 기능인 자정작용, 생태계 건강성 유지 등의 기능을 잃고 도시 활동에 따른 오염물질에 노출되어가고 있는 실정이다. 이로 인한 부정적인 영향으로 도시민의 삶의 질과 만족도 또한 하락되고 있다. 본 연구에서는 부산의 대표하천인 수영강을 대상으로 도시하천 수질 개선을 위한 도시민의 지불의사를 추정하였다. 비시장가치를 추정하기 위해 조건부가치측정법(CVM, Contingent Valuation Method)을 적용하여 수질개선에 따른 지불의사(WTP, Willingness To Pay)를 파악하고 경제적 가치를 추정하였다. 가상시나리오는 EPA, water quality ladder의 개념을 이용하여 현재 수영강 수질이 오염된 물(4등급)이라고 가상시장을 설정하고 낚시가 가능한 수준(2등급)까지 개선을 시키고자 할 때의 지불의사를 물었다. 이때 지불수단은 기부금의 형태로 연 1회 향후 5년간 지불기간을 설정하였다. WTP 모형추정은 KDI에서 제시하고 있는 로지스틱분포 함수와 스파이크 모형을 사용하여 WTP를 추정하였다. 스파이크 모형의 추정결과 평균 지불의사액은 12,255원으로 부산광역시 전체 가구 수인 1,392,291가구(2019년)에 적용할 경우 향후 5년간 연 170억 원의 재원을 확보할 수 있는 것으로 나타났다. 지불의사 추정결과 수영강 인접 지역주민의 지불의사가 높게 추정되었고, 부산시민이 수영강을 자연과 생태보전 기능하천으로 인지하고 있음(56.5%)을 고려 할 때, 하천환경개선을 통한 지불의사의 상승은 도시하천 가치 향상이 될 수 있을 것으로 판단된다. 또한 도시민의 기대수준 충족과 더불어 도시하천 가치상승을 위한 부족한 재원까지도 조달 할 수 있는 방안의 기초를 마련 할 수 있을 것이라 판단된다.

  • PDF