• Carbon letters
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• v.9 no.4
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• pp.298-302
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• 2008

Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.

• Macromolecular Research
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• v.10 no.5
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• pp.253-258
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• 2002

The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.6
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• pp.169-174
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• 2012

Electromagnetic interference(EMI) shielding effectiveness(SE) was investigated in of woven fabric made of epoxy/copper-nickel fabrics and nickel coated carbon fiber reinforced acrylonitrile-butadiene-styrene(ABS) composites. The coaxial transmission line method was used to measure the EMI shielding effectiveness of the composites. We designed and constructed a measuring system, consisting of a network analyzer and a device that plays the serves as a sample holder and at the same time as a transmission medium of the incident electromagnetic wave. The measurement of SE were carried out frequency range from 100MHz to 2GHz. It is observed that the SE of the composits is the frequency dependent increase with the increase in nickel coated carbon fibre volume fraction. The nickel coating with 20wt% ABS composite was shown to exhibit up to 60dB of SE. The result that nickel coated carbon fibre ABS composite can be used for the purpose of EMI shielding as well as for some microwave applications.

• Composites Research
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• v.24 no.6
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• pp.25-30
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• 2011

This paper presents an experimental study on the enhancement of electromagnetic shielding (EMI) properties of glass fiber, carbon fiber, and glass-carbon fiber composites by adding layers of multi-walled carbon nanotubes (MWCNTs). In the case of glass-fiber composites, spraying 0.1~0.2 g of MWCNT over a fiber area of $200mm{\times}200mm$ (1.8~3.6 ${\mu}m$ in thickness) resulted in significant improvement in EMI shielding effectiveness (SE). Also, when applying multiple MWCNT layers, it was more effective to place the layers concentrated near the center of the composite rather than spreading them out. On the contrary, inherently conductive carbon fiber and glass-carbon fiber composites did not show appreciable improvement with the addition of MWCNT layers. In order to maximize the effectiveness of carbon nanomaterials as EMI shielding fillers, it is imperative to understand the effect of these materials on various EMI shielding mechanisms and their interactions.

• Applied Chemistry for Engineering
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• v.25 no.3
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• pp.268-273
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• 2014

In this study, multi-walled carbon nanotubes (MWCNT) were treated with nickel by electroless plating method for improving electromagnetic interference (EMI) shielding performance of MWCNT. The physical properties of electroless plated MWCNT were analyzed by using ultra-high resolution scanning electron microscope (UHR-SEM), thermogravimetry (TGA), sheet resistance analyzer and EMI shielding analyzer. EMI shielding efficiencies of nickel electroless plated MWCNT were measured to be 16 dB from 800 MHz band, which was 1.6 times increased compared to that of the activated MWCNT. Also, the average sheet resistance of nickel electroless plated MWCNT was measured to be $70{\Omega}/sq$, which was 56% decreased compared to that of the activated MWCNT. This result could be attributed to the plating morphology on the surface of MWCNT. This result could be attributed to uniformity of plating morphology on the surface, which has more effect on EMI shielding efficiency than the amount of nickel plating.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.19 no.4
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• pp.35-39
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• 2019

The shielding effectiveness (SE) of the EMI spray coating film was measured in a three-dimensional structure. The shielding effectiveness was measured by AST D4935 using coaxial type TEM cell. A standard sample of the cylindrical slab is fabricated to measure the shielding effectiveness using the ASTM D4935. At this time, spray coating was performed by bonding a three-dimensional structure with NAND flash memory to a standard sample. In the case of spray coating, it was uniformly coated not only on the horizontal plane but also on the vertical plane of the three-dimensional structure. As a result of measurement, shielding effectiveness of maximum 59 dB was measured in a three-dimensional structure similar to the case without three-dimensional structure. As a result, it was confirmed that the spray coating can be uniformed even in the three-dimensional structure.

• Composites Research
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• v.35 no.3
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• pp.175-181
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• 2022

Due to the increasing number of wireless communication devices in mmWave frequency bands, there is a high demand for electromagnetic interference (EMI) shielding and heat dissipating materials to avoid device malfunctions. This paper proposes an EMI shielding composite film with a high heat dissipation characteristic. To achieve this, a conductive grid is integrated with a polymer-based composite layer including magnetic and heat dissipating filler materials. A high shielding effectiveness (>40 dB), low reflection shielding effectiveness (<3 dB), high thermal conductivity (>10 W/m·K), thin thickness (<500 ㎛) are simultaneously achieved with a tailored design of composite layer compositions and grid geometries in 5G communication band of 26.5 GHz.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2002.05a
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• pp.44-44
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• 2002

• Journal of Magnetics
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• v.13 no.4
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• pp.173-176
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• 2008

In this study, a new kind of instrument for measuring the magnetic shielding effectiveness (MSE) was developed using a double yoke; one a magnetizing yoke and the other a sensing yoke. Using the developed instrument, the MSE could be measured for a steel sheet specimen in the ELF range, where the magnetic permeability contributes to the MSE at low frequencies and eddy currents contributes to the MSE high frequencies with < 0.1 dB reproducibility. The developed measuring method can be applied to quality control in a steel sheet company producing EMI/EMC shielding materials.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.18 no.4
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• pp.79-83
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• 2018

An accurate method to measure shielding effectiveness(SE) of EMI spray coating film is presented. After high frequency simulating, Circular coaxial standard test fixture is fabricated. A sample of EMI spray coating film was fabricated for insertion into a circular coaxial standard test fixture. The measuring instrument used an Agilent 8722ES vector network analyzer for the SE measurement. The exact SE of copper and silver mixed spray coating sample was measured by the composition of the measuring instrument and the measuring sample. The SE of copper sample was measured at 70 dB and the SE of copper and silver mixed spray coating sample was measured at 60 dB. As a result of the measurement, the reliability of the circular coaxial standard test fixture was confirmed.