• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.5-5
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• 2011

The research and development of hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV) and electric vehicle (EV) are intensified due to the energy crisis and environmental concerns. In order to meet the challenging requirements of powering HEV, PHEV and EV, the current lithium battery technology needs to be significantly improved in terms of the cost, safety, power and energy density, as well as the calendar and cycle life. One new technology being developed is the utilization of composite cathode by mixing two different types of insertion compounds [e.g., spinel $LiMn_2O_4$ and layered $LiMO_2$ (M=Ni, Co, and Mn)]. Recently, some studies on mixing two different types of cathode materials to make a composite cathode have been reported, which were aimed at reducing cost and improving self-discharge. Numata et al. reported that when stored in a sealed can together with electrolyte at $80^{\circ}C$ for 10 days, the concentrations of both HF and $Mn^{2+}$ were lower in the can containing $LiMn_2O_4$ blended with $LiNi_{0.8}Co_{0.2}O_2$ than that containing $LiMn_2O_4$ only. That reports clearly showed that this blending technique can prevent the decline in capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and related structural phase transitions for these composite cathodes. In this presentation, we will report our in situ x-ray diffraction studies on this mixed composite cathode material during charge-discharge cycling. The mixed cathodes were incorporated into in situ XRD cells with a Li foil anode, a Celgard separator, and a 1M $LiPF_6$ electrolyte in a 1 : 1 EC : DMC solvent (LP 30 from EM Industries, Inc.). For in situ XRD cell, Mylar windows were used as has been described in detail elsewhere. All of these in situ XRD spectra were collected on beam line X18A at National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory using two different detectors. One is a conventional scintillation detector with data collection at 0.02 degree in two theta angle for each step. The other is a wide angle position sensitive detector (PSD). The wavelengths used were 1.1950 ${\AA}$ for the scintillation detector and 0.9999 A for the PSD. The newly installed PSD at beam line X18A of NSLS can collect XRD patterns as short as a few minutes covering $90^{\circ}$ of two theta angles simultaneously with good signal to noise ratio. It significantly reduced the data collection time for each scan, giving us a great advantage in studying the phase transition in real time. The two theta angles of all the XRD spectra presented in this paper have been recalculated and converted to corresponding angles for ${\lambda}=1.54\;{\AA}$, which is the wavelength of conventional x-ray tube source with Cu-$k{\alpha}$ radiation, for easy comparison with data in other literatures. The structural changes of the composite cathode made by mixing spinel $LiMn_2O_4$ and layered $Li-Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ in 1 : 1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to ~5.2 V vs. $Li/Li^+$, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component only. When the cell voltage reaches at ~4.0 V vs. $Li/Li^+$, lithium extraction from the spinel $LiMn_2O_4$ component starts and becomes the major contributor for the cell capacity due to the higher rate capability of $LiMn_2O_4$. When the voltage passed 4.3 V, the major structural changes are from the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, while the $LiMn_2O_4$ component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel $LiMn_2O_4$ component, with much less changes in the layered $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research. More detailed discussion will be presented at the meeting.

• Journal of Aquaculture
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• v.21 no.4
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• pp.317-324
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• 2008

This study estimated the genetic parameters and breeding values for the growth-related traits of the 1st generation produced in 2005. The heritability of body weight, total length, body height, body shape and condition factor of 180 days old olive flounders Paralichthys olivaceus, the 1st generation of selection, was estimated as 0.564, 0.590, 0.588, 0.306 and 0.332, respectively. And reproductivity of genetic evaluation for crossing superior flounders and inferior ones was tested using the subsequent generation produced in 2006 based on the breeding values of 1st generation. In the least-squares means of body weight and total length for each group of crossing, the values of crossing group between superior flounders ($S{\times}S$) showed $145.6{\pm}1.8\;g$ and $22.4{\pm}0.1\;cm$, respectively. The values of crossing group between superior and inferior flounders ($S{\times}I$) showed $133.2{\pm}2.5\;g$ and $22.1{\pm}0.1\;cm$, respectively. The values of crossing group between inferior flounders ($I{\times}I$) showed $114.0{\pm}2.1\;g$ and $21.08{\pm}0.12\;cm$, respectively. In the results, flounders are determined as appropriate selective breeding fish with the high heritability of flounders in early ages at 180 days old, and the reproductivity of genetic evaluation was also high.

• Korean Journal of Animal Reproduction
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• v.22 no.3
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• pp.293-300
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• 1998

The objective of this study was to determine effects of $\beta$-mercaptoethanol ($\beta$-ME) and cyst-eine (CYS) on the development of bovine em-bryos obtained from in vitro matured and fertil-ized oocytes. Cumulus-oocyte-complexes (COC-s) were matured in micro-drop of TCM-199 medium containing 10% FBS, 17$\beta$-Estradiol and FSH-p under paraffin oil at 39$^{\circ}C$ for 24 hrs. The fertilization of COC were induced in Fert-TALP medium supplemented with PHE, heparin, BSA and then the fertilized oocytes were cultured in CR1aa medium for 24 hrs. To investigate the effects of the agents on the development of the embryos, the embryos developed to the late 2-cell stage were cultured in the media with and without $\beta$-ME, CYS for 9 days. In experiment 1, to select appropriate concentration of $\beta$-ME and CYS during whole culture period (9 days), various concentrations of $\beta$-ME and CYS were add ded to the CR1aa medium. Addition of 25TEX>$\mu$M of $\beta$-ME and O.1mM of CYS to the culture medium 1 increase the incidence of embryos developed to the blastocyst. In experiment 2, we evaluated the effects of 25$\mu$M of $\beta$-ME and O.1mM of CYS addition on the blastocyst formation when emb bryos at different stages were exposed to 25$\mu$M $\beta$-ME and O.1mM of CYS. $\beta$-ME and CYS enhanced in vitro development of embryos to the blastocyst stage. The effect was greater in 8-ceII to morula embryos than in embryos fewer than 2-cells at the initiation of treatment. These results suggested that the addition of 25$\mu$M B-ME and O.1mM cysteine enhanced development to the blastocyst and hatching stage of in vitro derived bovine embryos, also addition of $\beta$-ME and cysteine were effective later stage embryo than early embryo development.

• Korean Journal of Poultry Science
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• v.29 no.2
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• pp.141-148
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• 2002

Two experiments were conducted to investigate the effects of supplemental feather digests on the growth of broiler chicks and taurine content in the broiler meat. In experiment 1, a total of 40 broiler chickens(Ros $s_{R}$) were assigned to four dietary treatments: control(T1), regular feather meal(FM) diet(R-FM,T2), NaOH treated FM diet(NaOH-FM,T3), HNO) treated FM diet($HNO_{3}$ -FM, T4). In experiment 2, a total of 70 broiler chickens were assigned to seven dietary treatments: T1 to t4(same as those of Exp. 1), modified $HNO_{3}$ treated FM diet(M- $HNO_{3}$-FM, T5), hair meal diet(HM, T6) and 0.22% cystine supplemented diet(CYS, T7). Feather meals and hair meal were supplemented at the level of 5% in the diet. In experiment 1 and 2, weight gain of chicks frd with R-FM or NaOH-FM tended to be higher than control or $HNO_{3}$ -FM. In experiment 2, weight gain of chicks frd with CYS was the highest followed by R-FM, M-HN $O_3$-FM, NaOH-FM, control, HM and $HNO_{3}$ -FM. In experiment 1, taurine content in breast muscle of chicks fed NaOH-FM was sogmofocamtly higher(P<0.05) than control. In experiment 2, taurine content in breast muscle of chicks fed NaOH-FM and CYS tended to be higher than other groups. Taurine content in leg muscle was significantly different among treatments as NaOH-FM and R-FM being highest followed by M- $HNO_{3}$-FM, CYS, control, $HNO_{3}$ -FM and HM. Taurine content in the liver(Exp. 1 and 2) and heart(Exp. 2) were not significantly affected by the supplemental feather digests. These results indicated that 5% NaOH-FM in the diet was effective in increasing taurine content in breast and leg muscle of broiler chicks.s.

• Current Research on Agriculture and Life Sciences
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• v.31 no.1
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• pp.45-50
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• 2013

Mutagenesis is used to study gene function and obtain new genetic resources for plant breeding. Soybean is an important oil crop in the world. Thus, to find new genetic resources, a mutation population was developed from the soybean cultivar Pungsannamul using 0.3% ethyl methane sulfonate. The variation of fatty acids was then evaluated among 892 M4 generation mutant lines selected from 3,774 mutant lines. While the wild type Pungsannamul showed 11.6, 3.4, 23.8, 53.3, and 7.8% for palmitic, stearic, oleic, linoleic and linolenic acid, respectively. the fatty acid variations in the mutant lines ranged from 7.4 to 19.7%, 2.2 to 13.0%, 14.7 to 49.0%, 31.8 to 63.9%, and 3.9 to 15.9% with an average of 10.8, 3.8, 25.3, 52.0, and 8.1% for palmitic, stearic, oleic, linoleic and linolenic acid, respectively. Thus, two mutation lines with higher plamitic acid, PE1542 (17.1%) and PE3058 (17.0%), one line with lower stearic acid, PE2166 (1.9%), one line with higher stearic acid, PE977 (12.7%), two lines with higher oleic acid, PE450 (44.4%) and PE2742 (47.7%), and two lines with lower linolenic acid, PE594 (4.6%) and PE1690 (3.7%), were selected from this study. The newly selected fatty acid variants will be good genetic sources for gene function analyses and breeding soybean varieties with altered fatty acids for various industrial and human food applications.

• Koreanishche Zeitschrift fur Deutsche Sprachwissenschaft
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• v.2
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• pp.29-48
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• 2000

Archaismen als sprachliches $Ph\"{a}nomen$, das zeitspezifischen Bewertungen unterliegt, sind bis jetzt in der Sprachwissenschaft wenig beachtet worden. In vorliegender Arbeit werden die $vielf\"{a}ltigen$ archaischen Formen behandelt, die noch heute in einem bestimmten Kontext gebraucht werden. Das Wort Archaismus starnmt von dem griechischen archaios 'altertumlich', und wird $haupts\"{a}chlich$ als Stilmittel der Rhetorik benutzt, um poetische, pathetische oder ironische Effekte hervorzurufen. Unter Archaismus wird em aus verschiedenen $Gr\"{u}nden$ veraltendes und veraltetes Wortgut verstanden, das aber noch im $Bewu{\ss}tsein\;der\;Sprachtr\"{a}ger$ lebt und im gegenwartssprachlichen Text verwendet wird. Ein Instrument zur deskriptiven Erfassung von Archaismen kann das $W\"{o}rterbuch\;sein.\;In\;W\"{o}rterb\"{u}chern$ der deutschen Gegenwartssprache werden Angaben $\"{u}ber$ zeitspezifische Markierungen eines Lexems gemacht: z.B. 'veraltet' , 'veraltend', $'fr\"{u}her'$, 'selten' 'historisch', 'nationalsozialistisch', , 'modern', , modisch , usw. Aber liber Art und Zahl der Markierung einerseits $\"{u}ber$ liber ihre Trennscharfe andererseits besteht noch keineswegs Klarheit. Der Vorgang des Veraltens - der Archaisierung - von Lexemen ist ein $Proze{\ss}$, der schwieriger festzustellen ist als das Aufkommen von neuen $W\"{o}rtern$. Hier sol1 nur eine von verschiedenen Ursachen genannt werden: $W\"{o}rter$ veralten mit ihren Denotaten. Wenn das Denotat aus dem gesellschaftlichen Leben verschwindet, ist auch die Benennung nicht mehr notwendig. Archaismen sind keineswegs auf den lexikalischen Bereich beschrankt, obwohl sie dort am meisten auffallen. Sie treten vielmehr auf allen Strukturebenen, vom Laut bis zum Text, auf: - auf der lautlichen Ebene: Kur/$K\"{u}r$, Melodie/Melodei, $g\"{u}lden$/golden - auf der morphologischen Ebene: gerne, am Tage, geschmecket/ geschmeckt - auf der graphematischen Ebene: That vs. Tat, Capital vs. Kapital - auf der lexikalischen Ebene: Oheim, Knabe, Kerker, Schulmeister - auf der Wortbildungsebene: Afterglauben, $Sch\"{o}ne$, kleineln - auf der syntaktischen Ebene: guten Mutes sein, einer Verbindung halber, $R\"{o}slein$ rot - auf der Textebene: Wollen der Herr unten speisen? Archaismen treten in unterschiedlichen Texten und Textsorten auf. Eine spezielle Funktion haben Archaismen im Sprachkunstwerk. Autoren nutzen sie, urn Zeitkolorit zu schaffen. Im Alltagsleben $k\"{o}nnen$ Archaismen Lebensumstande und -erfahrungen signalisieren. Altes Wortgut wird als kostbarer nationaler Besitz angesehen. Man kann heute immer wieder den $R\"{u}ckgriff\;auf\;\"{a}lteres$ Sprachgut beobachten, entweder urn Vergangenes und Vergessenes neu zu beleben oder urn die jeweilige Gegenwartssprache mit Hilfe yon Archaismen historisch zu vertiefen und gleichzeitig zu erweitern. Archaismen sind somit die sprachlichen Zeugen der Vergangenheit. Zugleich sind Sie auch Zeichen $f\"{u}r$ die 'Gleichzeitigkeit des Ungleichzeitigen' in heutigen Sprachen, weil sie 'kommunikativ mehrere Generationen, kulturell viele Jahrhunderte oder sogar Jahrtausende $\"{u}berbr\"{u}cken\;k\"{o}nnen$'.

• The Korean Journal of Quaternary Research
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• v.18 no.2 s.23
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• pp.1-2
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• 2004

The Ilkwang Fault is NNE-striking, elongated 40 Km between Ulsan and Haendae-ku, Busan in southeastem part of the Korean Peninsula(Kim, D.H. et al., 1989; Kim, J.S. et al., 2003). This paper is mainly concemed about the ages of the fault activities especially in the Quatemary, infered from classification of geomorphic surface and trench excavation for the construction of Singori nuclear power plant. The geomorphi surfaces are classified into the Beach and the Alluvial plain, the 10 m a.s.l. Marine terrace, the 20 m a.s.l. Marine terrace, the Reworked surface of 45 m a.s.l. Marine terrace and the Low relief erosional surface, from lower to higher altitude. The Beach and the Alluvial plain are elongated to the Holocene terrace(ist terrace, choi, 2003). The 10 m a.s.l. Marine terrace is correlated to 2nd terrace (MIS 5em 125 Ka. y. B.P., Choi, 1998). The 45 m a.s.l. Marine terace is correlated to the Lower marine terrace (MIS 7,220 Ka. y. B.P., Choi, 2003 or MIS 9,320 y. B.P.) to the Gwanganri terrace(Penultimate interglacial age, 200-200 Ka. Y. B.P., Oh, 1981). The Low relief erosional surface is distributed coastal side, the Reworked surface of 45 m a.s.l. Marine terrace inland side by the Ilkwang Fault Line as the boundary line. But the former is above 10 m higher in relative height than the latter. The 20 m a.s.l. Marine terrace on the elongation line of the Ilkwang Fault reveals no dislocation. A site was trenched on the straight contract line with $N30^{\circ}$ E-striking between the 10 m a.s.l. Marine terrace and the 20 m a.s.l. Marine terrace. Fault line or dislocation was not observable in the trench excavation. Accordingly, the straight contact line is inferred as the ancient shoreline of the 10 m a.s.l. Marine terrace. The Ages of the Fault activities are inferred after the formation of the Ichonri Formation - before the formation of the 45 m a.s.l. Marine terrace (220 Ka. y. B.P. or 320 Ka. y. B.P.). The Low relief erosional surface was an island above the sea-level during the formation of the 45 m a.s.l. Marine terrace in the paleogeography.

• Economic and Environmental Geology
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• v.8 no.1
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• pp.25-56
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• 1975

Most fluorite deposits of South Korea are distributed in three metallogenic zones namly as: Hwacheon, Hwangangni and Geumsan metallogenic zones. Fluorite deposits of each zone show The characteristic features owing to the geological setting, the structural patterns and their forming processes. deposits of the Hwacheon metallogenic zone are wholly fissure filling hydrothermal veins emThe bedded in shear fractures of the granite gneiss or schists of Precambrian age or in the cooling fractures of the granite and acidic hypabyssal rocks which are assumed to be a differentiated sister rock of the granite. Localization of most fluorite veins of the region is structurally controlled by NW and EW fracture systems and genetically related to the granite intrusion which ascertained as motivating rock of the fluorite mineralization. Fluorites are in most cases accompanied by quartz, chalcedony mainly and rarely agate, calcite, barite and sulphide base metals in some localities. The deposits of the Hwangangni metallogenic zone were formed at the last stage of hydrothermal polymineralization of W, Mo, Cu, Pb, Zn. The majority of the fluorite ore bodies were originated from replacement in limestone beds of Great Limestone Series or in calcareous interbeds of metasediments, whereas some cavity-filling ore bodies were embedded in phyllites and schists of the Ockcheon system and along the fissures in the replaced beds which were originated by volume decrease. The localization of fluorite deposits in this region is genetically related to the Moongyong granite which has been dated as middle Cretaceous, and controlled structurally by the $N20^{\circ}{\sim}50^{\circ}W$ extension fracture system or axial planes of folds, and by faults of NE direction that acted as paths of ore solution. The deposits of the Geumsan metallogenic zone are seemed to be formed through the similar process as that of Hwangangni metallogenic zone, but characteristic distinctions are in that they are more prevailing fracture filling veins and large number of the deposits are localized in roof-pendants or xenolithes of limestone in granites and porphyries. Igneous rocks that presumably motivated the mineraltzation are middle Cretaceous Geumsan granite and porphyries. Metallogenic epoch of the fluorite mineralization of South Korea are puesumably limited in early-middle Cretaceous. Studies of the fluid inclusions in fluorites of the region reveal that the homogenization temperature of the fluorite deposits are as follows: Hwacheon metallogenic zone : $95^{\circ}C{\sim}165^{\circ}C$; Hwangangni metallogenic zone : $97^{\circ}C{\sim}235^{\circ}C$; Geumsan metallogenic zone : $93^{\circ}C{\sim}236^{\circ}C$. Judging from the above results, the deposits of the Hwancheon region were formed at the epithermal stage, and those in the Hwangangni and Geumsan regions, were deposited at epithermal stage preceded by mesothermal mineralization of small scale in which some sulphide minerals were deposited. The analytical data of minor elements in the fluorites reveal that ore solutions of Hwangangni metallogenic zone seemed to be emanated in more acidic stage of magma differentiation than Hwacheon metallogenic zone did.

• The Korean Journal of Pain
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• v.13 no.2
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• pp.149-155
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• 2000

Background: Pulsed radiofrequency (RF) lesioning is a painless procedure and causes no neurodestruction and neuritis-like reaction are common following conventional RF lesioning. There is little data about the effect of pulsed RF especially with regard to its suitability for the treatment of acute pain. The possibility of a placebo effect cannot be ruled out because a double-blind study was not performed in previous studies. There is also no neuropathologic study about pulsed RF. Methods: The rats were anesthetized with sodium pentobarbital (40 mg/kg, i.p.; supplemented as necessary). The common sciatic nerve was exposed by blunt dissection through biceps femoris. Pulsed RF was administered to the common sciatic nerve using a 30 ms/s pulse with for 120 seconds. The temperature reached was no more than $42^{\circ}C$. Analgesia was determined using hot-plate assay shortly and, 3 days and 1 week before, and 2 weeks after operation. Lesions were examined with LM (light microscope) and EM (electron microscope) 2 weeks later. Results: There were no differences in response latencies between the control and experimental group. There were many vacuoles with hyaline bodies in the Schwann cell cytoplasm rather than axon in LM and larger electron dense bodies. No changes were found in the axon or unmyelinated fibers. Only small changes were found in the sheaths of myelinated fibers and Schwann cells. Conclusions: We therefore do think that any analgesic effect of pulsed RF is not a result of block of neural conduction. But rather than it can be attributed to others factors. It was also ineffective as a treatment for acute pain such as that caused by the hot-plate test.

• Journal of KIISE:Software and Applications
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• v.36 no.11
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• pp.936-946
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• 2009

A graph cuts method has recently attracted a lot of attentions for image segmentation, as it can globally minimize energy functions composed of data term that reflects how each pixel fits into prior information for each class and smoothness term that penalizes discontinuities between neighboring pixels. In previous approaches to graph cuts-based automatic image segmentation, GMM(Gaussian mixture models) is generally used, and means and covariance matrixes calculated by EM algorithm were used as prior information for each cluster. However, it is practicable only for clusters with a hyper-spherical or hyper-ellipsoidal shape, as the cluster was represented based on the covariance matrix centered on the mean. For arbitrary-shaped clusters, this paper proposes graph cuts-based image segmentation using mean shift analysis. As a prior information to estimate the data term, we use the set of mean trajectories toward each mode from initial means randomly selected in $L^*u^*{\upsilon}^*$ color space. Since the mean shift procedure requires many computational times, we transform features in continuous feature space into 3D discrete grid, and use 3D kernel based on the first moment in the grid, which are needed to move the means to modes. In the experiments, we investigate the problems of mean shift-based and normalized cuts-based image segmentation methods that are recently popular methods, and the proposed method showed better performance than previous two methods and graph cuts-based automatic image segmentation using GMM on Berkeley segmentation dataset.