• Title/Summary/Keyword: EDX

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Dissolution Resistance Property of Modified Asphalt Waterproofing Sheet Coated with Polyamide Film by SEM-EDX Analysis (폴리아마이드 필름이 코팅된 개량 아스팔트 방수시트의 SEM-EDX 분석을 통한 유기용제 저항성 확인)

  • An, Ki-Won;Yoo, Jae-Yong;Oh, Sang-Keun
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.5
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    • pp.437-444
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    • 2017
  • In the composite waterproofing method in which a polyurethane coating waterproofing material is applied on the modified asphalt waterproofing sheet, the organic solvent is diluted in the coating waterproofing material in order to improve the workability. However, since the organic solvent is not volatilized before the curing of the polyurethane coating waterproofing material, the organic solvent causes dissolution of asphalt layer, thereby causing oil leakage. As a result, a polyamide film having a high dissolution resistance property was laminated on modified asphalt sheet, and through testing the dissolution resistance was visually confirmed and quantitative analysis of the polyamide film by SEM-EDX analysis was also used to confirmed the dissolution resistance of the polyamide film.

Identification Factor Development of Particulate Matters Emitted from Coal-fired Power Plant by FE-SEM/EDX Analysis (FE-SEM/EDX 분석법을 이용한 석탄화력발전소에서 배출되는 입자상물질의 확인자 개발)

  • Park, Jeong-Ho
    • Journal of Environmental Science International
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    • v.26 no.12
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    • pp.1333-1339
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    • 2017
  • Coal-fired power plants emit various Particulate Matter(PM) at coal storage pile and ash landfill as well as the stack, and affect the surrounding environment. Field Emission Scanning Electron Microscopy and Energy Dispersive X-ray analyzer(FE-SEM/EDX) were used to develop identification factor and the physico-chemical analysis of PM emitted from a power plant. In this study, three samples of pulverized coal, bottom ash, and fly ash were analyzed. The pulverized coal was spherical particles in shape and the chemical composition of C-O-Si-Al and C/Si and C/Al ratios were 200~300 on average. The bottom ash was spherical or non-spherical particles in shape, chemical composition was O-C-Si-Al-Fe-Ca and C/Si and C/Al ratios were $4.3{\pm}4.6$ and $8.8{\pm}10.0$. The fly ash was spherical particles in shape, chemical composition was O-Si-Ai-C-Fe-Ca and C/Si and C/Al ratios were $0.5{\pm}0.2$ and $0.8{\pm}0.5$.

Analysis of rifle and pistol primer gunshot residue using SEM-EDX (SEM-EDX에 의한 소총과 권총의 뇌관화약잔사 분석)

  • Jeon, Chung-Hyun;Park, Sung-Woo
    • Analytical Science and Technology
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    • v.23 no.3
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    • pp.322-329
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    • 2010
  • Primer gunsot residues (GSR) obtained from K1A and K2 rifles, and K5 pistol were analysed with scanning electron microscopy/energy dispersive X-ray spectrometry (SEM-EDX) as basic data in firearm accidents. Ammunition of 5.56 mm is employed for K1A and K2 rifles and 9.0 mm for a K5 pistol. The analyses of morphology, size, particle number, elemental ratio were performed for primer GSR prepared after shooting 3 times. The detected content was Ba>Pb>Sb in most GSR particles but Sb>Pb>Ba or Pb>Sb>Ba in some particles. In the statistical result of composition ratio of elements, the particles with more Sb than Ba were detected in most primer GSR from a K5 pistol, 3~8 times more than K1A and K2 rifles. This results can be employed to discriminate gun type between rifles and pistols. Furthermore, the size and the number of particles can be applied to access the type of guns.

Development of Source Profiles for Asbestos and Non-asbestos Fibers by SEM/EDX (SEM/EDX를 이용한 석면 및 비석명의 오염원분류표 개발)

  • Choi, Young-A;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.718-726
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    • 2007
  • There are many varieties of asbestos: chrysotile, crocidolite, amosite, tremolite, actinolite, and anthophylite. These are widely used in construction materials, brake lining, textile, and so on. Even though non-asbestos fibers such as glassfiber and rockwool have manufactured because asbestos causes asbestosis, lung cancer, mesothelioma, etc., some bad effects of non-asbestos have been also reported. PCM (phase contrast microscopy) and PLM (polarized light microscopy) have been used to qualitatively analyze asbestoses. These techniques have serious drawbacks when identifying and separating various asbestoses. Recently scanning electron microscopy (SEM) equipped with energy dispersive X-ray analysis (EDX) has been known as an useful tool to analyze airborne particle since it provides physical and chemical information simultaneously. The purpose of the study was to classify both asbestos and non-asbestos fibers and finally to develop their source profiles by using the SEM/EDX. The source profiles characterized by 6 different types of asbestos fibers and 2 types of non-asbestos fibers had been developed by analyzing a total of 380 fibers. Analytical parameters used in this study were length, width, aspect ratio, and shape as physical information, and Na, Mg, Al, Si, K, Ca, Cr, Mn, Fe, and Cu as chemical information. All the parameters were intensively reviewed.

Aerosol Deposition and Behavior on Leaves in Cool-temperate Deciduous Forests. Part 1: A Preliminary Study of the Effect of Fog Deposition on Behavior of Particles Deposited on the Leaf Surfaces by Microscopic Observation and Leaf-washing Technique

  • Watanabe, Yoko;Yamaguchi, Takashi;Katata, Genki;Noguchi, Izumi
    • Asian Journal of Atmospheric Environment
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    • v.7 no.1
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    • pp.1-7
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    • 2013
  • To establish the method for investigating the behavior of aerosol particles deposited on the leaf surface against fog water under natural conditions, scanning electron microscopy with energy-dispersive X-ray (SEM-EDX) analysis and wash water analysis by ion chromatography after the washing treatment were performed using leaves of white birch collected from low part of the tree crown and the top of the tree in Sapporo City, Hokkaido, northern Japan. Each of collected leaves was divided into two parts according to the treatment performed: leaf surface (adaxial side) was 1) untreated, and 2) washed with deionized water with a pipette. In untreated samples, many particles of various shapes, including soil particles and organic debris, were deposited on the surface. Particles containing S were found on the surface of samples collected from only low part of the tree crown. After the washing treatment, SEM-EDX analysis revealed that soil particles and particles containing S had been washed off with water, although some particles such as soil particles and organic debris still remained on the leaf surface. The major anion such as $SO{_4}^{2-}$ was detected in wash water of all samples, although the peak of S in X-ray spectra was not detected from samples collected at top of the tree. The combination of SEM-EDX analysis with wash water analysis indicated that $SO{_4}^{2-}$ was deposited on the leaf surface in dissolved state and/or in state of submicron particles. These results suggested that fog water could remove soil particles and particles containing S and $SO{_4}^{2-}$ from the leaf surfaces, but not all particles. There was no difference in sampling position in the tree crown. Our study suggested that combination with SEM-EDX analysis and wash water analysis would be effective for investigation of the behavior of particles on the leaf surface against fog water.

Removal of Pb2+ ion from aqueous solution Using crab shell treated by acid and alkali (산-염기 처리한 게 껍질에 의한 수풍의 납 이온 제거)

  • 김동석
    • Journal of Environmental Science International
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    • v.12 no.4
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    • pp.469-476
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    • 2003
  • In order to examine the pre-treatment effect of crab shell en Pb$^{2+}$ removal by crab shell in aqueous solution, acid and alkali pre-treated crab shell were used. Electron microscopy techniques such as TEM (transmission electron microscopy) and SEM (scanning electron microscopy), and EDX (energy dispersive X-ray) and FTIR (Fourier transform infrared) spectrometry techniques were used to investigate the process of Pb$^{2+}$ removal by acid and alkali pre-treated crab shell. The Pb$^{2+}$ removal by acid pre-treated crab shell was much lower than that by untreated crab shell because of the decrease of CaCO$_3$ from the crab shell. However, the Pb$^{2+}$removal by alkali pre-treated crab shell increased compared to that by untreated crab shell. The results were confirmed by TEM, SEM, EDX and FTIR.nd FTIR.

Seasonal Characterization of Particles in Busan Area (부산지역 먼지입자의 계절별 특성)

  • Kang Shin-Mook;Cho Jeong-Goo
    • Journal of environmental and Sanitary engineering
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    • v.20 no.3 s.57
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    • pp.17-26
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    • 2005
  • Many researches were focused on the data which obtained from chemical bulk analysis. It is difficult to evaluate source contribution by wet type chemical bulk analysis. In this study, we have reviewed the characterization of individual particle for source identification. We analyzed by SEM/EDX methods. We have obtained average geometric particle diameter measured by optical diameter which were resulted from SEM/EDX image scan, representative physical diameter of individual particle was $3.38\;{\mu}m\;in\;A,\;3.67\;{\mu}m\;in\;B$. In the result of image analysis at each spots particles, both samples non-sphere shapes, C-rich particles. In consequence of chemical analysis of individual particle, each sampling sites some elements.