• Title/Summary/Keyword: E.A. property

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Fluorescence Switching of Conjugated Polyelectrolyte based on Polydiphenylacetylene

  • Lee, W.E.;Kim, J.H.;Sakaguchi, T.;Kwak, G.;Lee, C.L.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.245.1-245.1
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    • 2013
  • Polydiphenylacetylene (PDPA) derivatives are a class of conjugated polymer that contain intramolecular excimer emission originating the intramolecular stack structure. In contrast with conventional conjugated polymer, the fluorescence property of PDPA significantly depends on the intramolecular stack structure. In this regard, herein, we investigated new fluorescence switching mechanism of conjugated polyelectrolyte (CPE) based on PDPA. The developed CPE showed relatively weak fluorescence emission in water, while the polymer exhibited a great fluorescence amplification behavior by electrostatic complex with proteins. In addition, the CPE is highly sensitive to binding with a little protein despite of turn-on type fluorescence response. We found that the fluorescence switching of the CPE closely relate to a perturbation of the intramolecular stack structure. The new fluorescence switching mechanism of the CPE is very useful for protein assays and discrimination and it also would be provide new sensing approaches as basic sensing mechanism.

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Native American Literature and the Question of Universality Focusing on Silko's Ceremony (미국 원주민 문학과 보편성 문제-실코의 『의식』을 중심으로)

  • Kim, Jiyoung
    • English & American cultural studies
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    • v.14 no.2
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    • pp.97-125
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    • 2014
  • This paper delves into the question of universality in Native American Literature focusing on Leslie Marmon Silko's Ceremony, exploring some different definitions of universality and looking at the work in the light of these definitions. In this paper I proposed four possible definitions or faces of universality applicable to the narrative of the oppressed people. Firstly, the colonizers indoctrinate their colonized persons with the colonialists' beliefs through the process of assimilation purposefully imposed in the name of universality. In Ceremony Rocky and Emo are the victims of assimilation including militarization. Secondly, the colonized people hold on to their traditional values in face of colonizers' universalism. In Ceremony Tayo shows an attachment to tribal stories in opposition to whites' lies. Thirdly, the colonized can get together by sharing experiences of violence, occupation, and loss of their land and language, forming a bond of "commonality" among them. In Ceremony the story of a medicine man, Betonie, suggests oneness of victims against the evil power of destroyers represented by nuclear bombs. Fourthly and lastly, the universal consists in the subject's trial and practice attempting to achieve universalism against the existing order, not in the stipulation defining what is universal. In the story Tayo endeavors to retrieve his cattle by transgressing whites' property and makes a hole in the established dichotomy of whites and Indians. In sum, Ceremony as a minor literature shows the developmental aspects of universality, culminating in Tayo's refusal to assimilate himself to whites' lies.

Effect of Local Softening for Spring-back Reduction of Ultra High Strength Steel on Microstructure and Mechanical Properties (스프링백 저감을 위한 초고강도강의 국부적 연화 열처리에 따른 미세조직과 기계적 특성 변화에 관한 연구)

  • Park, S.E.;Park, B.H.;Oh, M.H.;Kang, B.S.;Ku, T.W.
    • Transactions of Materials Processing
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    • v.30 no.3
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    • pp.134-141
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    • 2021
  • In order to improve excessive spring-back behavior as a result of the roll forming process using ultra high strength steel (UHSS) sheet, local softening in region of a partial area expected to be deformed on an initial blank is considered in this study. With SPFC1470 UHSS sheet with initial blank thickness of 1.20mm, the local softening is performed with the following conditions: temperatures of 500℃, 550℃, 600℃ and 650℃, and holding time of 20s, 40s, 80s and 160s. Mechanical properties, such as yield stress and tensile strength, as well as elongation, are evaluated through uniaxial tensile tests, while the microstructural characteristics as a result of local softening are also investigated using the heat-treated specimens. As a result, it is shown that the spring-back behavior of the roll-formed prototype was reduced about by 78.9%, when the local softening at about 500℃ was performed for 160s considering the practical manufacturing condition.

Effect of Milk Protein Isolate/κ-Carrageenan Conjugates on Rheological and Physical Properties of Whipping Cream: A Comparative Study of Maillard Conjugates and Electrostatic Complexes

  • Seo, Chan Won;Yoo, Byoungseung
    • Food Science of Animal Resources
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    • v.42 no.5
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    • pp.889-902
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    • 2022
  • With increasing consumer demand for "clean label" products, the use of natural ingredients is required in the food industry. Protein/polysaccharide complexes are considered good alternatives to synthetic emulsifiers and stabilizers for formulating stable emulsion-based foods. Milk protein and carrageenan are widely used to improve the physical properties and stability of dairy food products. In a previous study, milk protein isolate (MPI) was conjugated with 𝛋-carrageenan (𝛋-Car) in a wet-heating system through the Maillard reaction, and the Maillard conjugates (MC) derived from MPI and 𝛋-Car effectively improved the stability of oil-in-water emulsions. Therefore, MPI/𝛋-Car conjugates were used in whipping cream as natural emulsifiers in this study, and the physical and rheological properties of whipping creams stabilized using MPI/𝛋-Car MC and MPI/𝛋-Car electrostatic complexes (EC) were investigated. The whipping creams stabilized with MPI/𝛋-Car MC have lower rheological parameters (ηa,50, K, G', and G'') than those of whipping creams stabilized with MPI/𝛋-Car EC. Although the overrun value was slightly reduced owing to the addition of MPI/𝛋-Car MC, the stability of the whipped creams with MC was effectively improved due to enhanced water-holding ability by conjugation.

Entropy and its Relation with the Property of Molecule, Phase and Component (엔트로피와 분자 특성, 상 및 성분의 관계)

  • Jaeeon Chang
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.116-122
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    • 2023
  • We study the relationship of entropy with the properties of molecules and also with the macroscopic specifications of the system, i.e., component and phase. Understanding different viewpoints of classical mechanics and quantum mechanics for the indistinguishability of molecules belonging to the same component, we discuss a few thermodynamic systems in which the properties of molecules are to be consistent with the component as a macroscopic term of classifying the molecules. With a clear definition of thermodynamic microstate, the drawback of the Boltzmann statistics caused by the distinguishability of molecules is avoided, and the Gibbs paradox of entropy consequently disappears. Corresponding to the characteristics of fluid and solid phases, we investigated the effects of the indistinguishability and the symmetry number of molecules and the number of microstates realized in time on the partition function and the entropy. In particular, we show that crystalline solid can be regarded as a system which does not satisfy the ergodic hypothesis.

Facile Synthesis of Bio-Composite Films Obtained from Sugarcane Bagasse and Cardboard Waste

  • Satish Kumar Singh;Sweety Verma;Himanshu Gupta;Avneesh Kumar Gehlaut;Suantak Kamsonlian;Surya Narain Lal;Ankur Gaur;Sanjeev Maken
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.584-590
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    • 2023
  • In this study, we focus on the recycling of cardboard waste and sugarcane bagasse (SCB) for the preparation of carboxymethyl cellulose (CMC) and its conversion into a biodegradable film. Sodium alginate (SA) was added to form a biodegradable composite film. SA was used to increase film permeability. Glycerol, which is a plasticizer, was used to increase the tensile strength (TS) and film expansion. To characterize the CMC, X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy were used. The addition of olive oil to the CMC-SA matrix highlighted its antimicrobial property against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). A slight decrease in tensile strength was observed with the addition of olive oil (OO), which improved the functional properties of the control films as well as lowered moisture content and water solubility. But considering all other factors, the composite films obtained from sugarcane bagasse and cardboard waste incorporated with olive oil are suitable for applications in the field of food packaging.

Differences in toughness and aging potential of longissimus lumborum muscles between Hanwoo cow, bull and steer

  • Zhen Song;Inho Hwang
    • Journal of Animal Science and Technology
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    • v.65 no.4
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    • pp.865-877
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    • 2023
  • Thirty Hanwoo cattle including bulls, cows, and steers (n = 10 each) were slaughtered and investigated for carcass traits (weight, meat color, fat color, yield index, maturity, marbling score, back-fat thickness, and firmness) and meat quality. The meat quality such as: pH, color, cooking loss, fatty acid, thiobarbituric acid reactive substance, warner-bratzler shear force, tensile tests, and texture profiles were analyzed on longissimus lumborum (LL) muscles of the carcasses at different aging times (3 d and 21 d). The results showed that steers and cows had higher back-fat thickness and marbling score, and a lower firmness (p < 0.001) than bulls. Bulls exhibited a lower meat quality indicating by higher cooking loss, thiobarbituric acid reactive substance content, warner-bratzler shear force and tensile test values (p < 0.01). Regarding the sensory property, the bull meat also had higher hardness, and lower tenderness, juiciness and flavor scores than the cow or steer meat (p < 0.01). Additionally, the bull meat had a higher polyunsaturated fatty acid and a lower monounsaturated fatty acid contents (p < 0.01). With increased aging time, the meat tenderness was improved in all the genders. Taken together, the present study demonstrated that the gender and aging time affected the carcass traits, fatty acid and sensory quality of beef. Postmortem aging could improve the meat tenderness of all genders especially bulls.

Damping characteristics of CFRP strengthened castellated beams

  • Cyril Thomas Antony Raj;Jyothis Paul Elanhikuzhy;Baskar Kaliyamoorthy
    • Steel and Composite Structures
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    • v.49 no.6
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    • pp.685-699
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    • 2023
  • In recent years, Carbon Fibre Reinforced Plastic (CFRP) strengthening is found to be one of the best methods to strengthen steel structures. The fibrous bond can also influence the vibration characteristics of the strengthened element apart from its static strength enhancement property. The main objective of this study is to understand the influence of CFRP strengthening on the dynamic Behaviour of Thin-Webbed Castellated Beams (TWCBs). A detailed experimental investigation was carried out on five sets of beams with varying parameters such as domination of shear (Shear Dominant, Moment Dominant and Moment and Shear Dominant), sectional classification (Plastic and Semi-compact) and perforation geometries (ho/dwratio 0.65 and e/ho ratio 0.3). Free vibration analysis was carried out by exciting the simply supported TWCBs with an impact force generated by a ball dropped from a specific height. Logarithmic decrement method was used to obtain the damping ratio and natural frequencies of vibration were found by Fast Fourier Transform (FFT). Natural frequency showed an increase in a range of 10.5 - 55% for the different sets of castellated beams. An increase of 62.30% was noted in the damping ratio of TWCBs after strengthening which is an indication of improvement in the vibration characteristics of the beam.

TLR10 and Its Unique Anti-Inflammatory Properties and Potential Use as a Target in Therapeutics

  • Faith Fore;Cut Indriputri;Janet Mamutse;Jusak Nugraha
    • IMMUNE NETWORK
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    • v.20 no.3
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    • pp.21.1-21.10
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    • 2020
  • TLRs are pattern recognition receptors (PRRs) whose cytoplasmic signalling domain is similar to that of IL-1. The extracellular domain of TLRs serve as the binding site of pathogen associated molecular patterns. TLRs are found on both plasma and endosomal membranes and they mainly exert their function by activating genes which lead to production of inflammatory factors. The latest TLR to be discovered, TLR10 is a unique TLR which exhibit anti-inflammatory properties. TLR10 is found on the plasma membrane with other TLRs namely TLR1, TLR2, TLR4, TLR5 and TLR6. Studies have revealed that TLR10 is found on the same gene cluster with TLR1 and TLR6 and is also a coreceptor of TLR2. Up to date, TLR10 is the only TLR which exhibit anti-inflammatory property. Previously, TLR10 was thought to be an "orphan receptor" but much recent studies have identified ligands for TLR10. Currently there is no review article on TLR10 that has been published. In this narrative review, we are going to give an account of TLR10, its functions mainly as an anti-inflammatory PRR and its possible applications as a target in therapeutics.

Fabrication and Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell (연료극 지지체식 원통형 고체산화물 연료전지의 제조 및 특성연구)

  • Kim, Eung-Yong;Song, Rak-Hyun;Shin, Dong-Ryul;Lim, Y.E.
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1547-1549
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    • 1999
  • As a preliminary experiment for the development of anode-supported tubular cell with proper porosity, we have investigated the anode substrate and the electrolyte-coated anode tube. The anode substrate was manufactured as a function of carbon content in the range of 20 to 50 vol.%. As the caron content increased, the porosity of the anode substrate increased slightly and the carbon content with proper porosity was obtained at 30 vol.%. The anode tube was fabricated by extrusion process and the electrolyte layer was coated on the anode tube by slurry dipping process. The anode-supported tube was cofired successfully. Their sintered property and microstructure were examined and the porosity of the anode tube was 35%. From the gas permeation test, the anode tube was found to be porous enough for gas supply. On the other hand, the anode-supported tube with electrolyte layer indicated a very low gas permeation rate. This means that the coated electrolyte was dense. Based upon these experimental results. we will fabricate and test the anode-supported tubular cell.

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