• Title/Summary/Keyword: E-type 분산염료

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Combination Dyeing of Triacetate/PET Blended Fabric with Disperse Dye (트리아세테이트/PET 혼방 직물의 분산염료 혼합염색)

  • Kim, Myoung Ok;Lee, Jung-Soon
    • Science of Emotion and Sensibility
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    • v.19 no.4
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    • pp.3-12
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    • 2016
  • The aim of this study is to find the optimal combination dyeing condition for the enhancement of dye uptake and union dyeing of the composite material fabric made of triacetate and quick drying PET blended yarn. For the experiment, fabrics were one-bath combination dyed using the mixed dye of E-type disperse dye(C.I Disperse red 50) and S-type disperse dye(C.I. Disperse red 92) to measure dyed fabric's dye exhaustion, dye uptake, color and color difference according to the diverse conditions including dying temperature, time and mixed ratio of the dye. Dye equilibrium of combination dyeing occurred in $100^{\circ}C$, but by comparing dyed fabrics' K/S value and surface color, it was found that $120^{\circ}C$ was where the manifestation of color of triacetate and quick drying PET was identical. Mixed dye exhaustion and dye uptake merely changed as dyeing time increased, but color became more uniform. Therefore, it can be concluded that by using combination dyeing method, and by using the mixed dye which the mixing ratio of S-type dye and E-type dye is appropriately controlled, dye uptake can be improved compared to using single dyeing regardless of the color of E-type dye.

Dyeability of Low-melting Polyester at Low Temperature (LMP 복합사의 저온 염색성)

  • Hwang, Ji-Hyun;Kim, Chang-Nam;Ma, Jin-Suk;Yoon, Nam-Sik
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.49-49
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    • 2012
  • 바닥재 자카드직물에 사용이 예상되는 LMP(low meltig polyester) 복합사는 사염 시 높은 수축율 및 열융착의 가능성 때문에 일반적인 폴리에스테르의 염색조건에서는 염색이 불가하다. 따라서 적정의 수축율 내에서 가능한 염색조건에 대해 고찰하였다. LMP 복합사는 웅진케미컬에서 생산된 Regular PET/LMP(75:25) 260d/48f 원사를 사용하였다. 수축율은 KS K 0215에 준하여 측정하였다. 염색은 E-type 및 S-type(Foron Dark Blue S-WF) 분산염료를 사용하였으며, E-type 중에서는 아조계(Lumacron Blue SERL 200%) 와 안트라퀴논계(Foron Blue E-BL 150)의 2 종류를 사용하였다. 염색된 시료는 현미경 단면사진을 이용하여 염료의 내부확산을 확인하였으며, 환원세정 전후의 K/S 값을 측정하였다. LMP원사의 수축율을 시험한 결과 $90^{\circ}C$에서 9% 정도의 수축율을 나타내어, $90^{\circ}C$ 이상에서는 사염이 어려운 것으로 나타났다. 따라서 염색온도는 $80^{\circ}C$$90^{\circ}C$로 하였다. S-type의 염료를 이용한 경우 $90^{\circ}C$에서 4일 이상 염색해도 염착이 이루어지지 않아 대상 염료에서 제외하였다. E-type 염료인 경우 아조계는 흡진율은 높았으나 내부 regular PET에의 확산이 매우 느리고, 안트라퀴논계는 상대적으로 확산이 빠른 것으로 나타났다. 안트라퀴논계 분산염료는 $80^{\circ}C$에서 내부로의 확산에 4일 이상이 소요되며, $90^{\circ}C$에서는 2일 이상이 소요되었다. 이 후 환원세정에 의한 K/S 값의 변화 및 마찰견뢰도를 시험하였으며, 환원세정 후의 섬유단면 사진을 통해 염료의 migration성을 평가하였다.

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The Dyeing Behavior of PET Bulky Yarn with Disperse Dyes (분산염료에 의한 폴리에스터 Bulky Yarn의 염색거동)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.70-76
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    • 2018
  • The dyeing behaviors of poly(ethylene terephthalate)(PET) bulky yarns, DTY(draw textured yarn) and SSY(latent crimped yarn), were investigated with different energy type disperse dyes compared with those of SDY(spin draw yarn). The maximum exhaustions of E-type disperse Red 60, Blue 56 and Yellow 54 on SSY were 99%, 94% and 93%, respectively. The maximum exhaustions of S-type disperse Red 179, Blue 79 and Orange 30 on SSY were 96%, 97% and 97%, respectively. The K/S values of SSY were significantly higher than those of DTY and SDY in all energy type of disperse dyes. The knit fabric composed of SSY became bulky at the end of high temperature dyeing process because of their thermal shrinkage property due to melt viscosity difference.

Dyeing Properties on Jacquard Fabric for Blind Using Low-melting Flame Retardant Polyester (저융점 난연 폴리에스터를 이용한 블라인드용 자카드 직물의 염색성)

  • Kim, Jeong-Hwa;Lee, Jung Soon;Lee, Sung-Young;Lee, Seung-Gu
    • Journal of the Korean Society of Clothing and Textiles
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    • v.38 no.3
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    • pp.404-414
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    • 2014
  • This study investigates the dyeability and fastness of jacquard fabric for blind using low-melting flame retardant polyester. Two types of jacquard fabric were prepared with a low-melting flame retardant polyester and regular polyester. The low-melting flame retardant polyester has a sheath and a core. The core consists of flame retardant polyester and the sheath consists of low-melting polyester. Disperse red 50 (DR 50), disperse blue 56 (DB 56), disperse yellow (DY 54) of E-type dyes and disperse 92 (DR 92), disperse blue 60 (DB 60), disperse yellow (DY 79) of S-type dyes were used and dyed on jacquard fabrics dependent of dyeing temperature and time. The fastness, dye exhaustion, color strength (K/S value), and colorimetric properties of jacquard fabrics were evaluated. The dyeability of S-type dyes were higher than E-type dyes. The experiments indicated optimum dyeability that the dyeing temperature was $110^{\circ}C$ for E-type dyes and $120^{\circ}C$ for S-type dyes for 40 minutes. The fastness to washing and light were excellent at a 4-5 grade.

The Dyeing Properties of Poly(trimethylene terephthalate) by Disperse Dyes with Different Energy Level (Energy Level이 다른 분산염료를 이용한 Poly(trimethylene terephthalate)섬유의 염색성)

  • 백지연;김정렬;이난형;윤태희;김삼수
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.316-320
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    • 2003
  • In order to investigate the dyeing property of poly trimethylene terephthalate(PTT) fabric, the dyeing of PTT fabric was carried at under condition of different dyeing temperature by using several disperse dyes with different energy level. Particularly, this study discussed the PTT dyeing thermodynamically. Used disperse dyes were selected based on the their chemical structure and energy level. The obtained results were as followings; The dye adsorption of S type disperse dye such as C. I. Disperse Blue 79 increased with increasing dyeing temperature. In a exhaustion rate of PTT fabric with disperse dyes, C. I. Disperse Blue 56 showed higher values than that of C. I. Disperse Orange 29 and Blue 79. For the interpretation of thermodynamic dyeing behavior, the partition coefficient ( K ) and some several thermodynamic parameters such as standard affinity$(-\mu^\circ)$ and heat of dyeing$(\Delta{H}^\circ)$ calculated from the adsorption isotherm. From above results, as the energy level of disperse dye is small, the partition coefficient and standard affinity increased. But the heat of dyeing of PTT fabric with disperse dye showed high negative value in order of E type(C. I. Disperse Blue 56), SE type(C. I. Disperse Orange 29) and S type(C. I. Disperse 79).

A Study on the Dyeing of Polyester Fiber in Alkaline Dyebath ―Dyeing Properties of Disperse dyes According to variation of pH values― (폴리에스테르섬유의 알칼리욕염색에 관한 연구 -pH변화에 따른 분산염료의 염색성을 중심으로-)

  • Sung, Woo Kyung;Ryu, Ki Hyo;Park, Soo Min;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.34-42
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    • 1996
  • This Study was made to investigate alkaline dyeing systems for a new dyeing applicable polyester fibers. Disperse dyes for dyeing of polyester fibers were C.I. Red 60, Blue 56 and Yellow 54 as three primary colors of E type which used widely on the scene. Dyeing properties of dispers dyes on the polyester fibers are discussed according to variation of pH values for application of alkaline dyeing method compared with to ordinary acidic dyebath. Alkaline pH of the dyebath was controlled to pH 9 and 10.5 with buffer solutions using each hydrochloride and disodiumtetraborate, disodiumtetraborate and sodium hydroxide to promote the reproducibility of dyeing. Dyeing properties of dispers dyes on the polyester fibers by alkaline dyeing method compared with to ordinary acidic dyebath were discussed by estimation of color, wash-fastness, bleeding and migration of dyed polyester fabric.

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