• Fire Science and Engineering
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• v.27 no.3
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• pp.1-7
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• 2013

The wildland fire intensity and scale are getting bigger owing to climate change in the world. In the case of domestic, the forest is distributed over approximately 63.7 % of country and the main facilities like a industrial facility or gas facility abuts onto it. Therefore there is potential that the wildland fire is developed to a large-scale disaster. In this study, the effect distances of the radiant heat flux from the crown fire are analysed according to the change of wind velocity. The safety criteria concerning the radiant heat flux to influence on the surrounding were researched to analyse the effect distances. The criteria of radiant heat flux were chosen $5kW/m^2$, $12.5kW/m^2$, $37.5kW/m^2$. WFDS, which is an extension of NIST's Fire Dynamics Simulator, was used to consequence analysis of the forest fire. In order to apply the analysis conditions, it is researched the forest conditions that is generally distributed in domestic region. As the result, the maximum effect distances by radiant heat were showed at the horizontal and vertical direction. When the wind velocity varied from 0 to 10 m/s, the maximum effect distance increased as the wind velocity increases. Interesting point is that the maximum effect distance were shown at the wind velocity of 8 m/s. The maximum effect distance was decreased according as the fuel moisture of trees increase. This study can contribute to analyse quantitative risk about the damage effect of the surrounding facilities caused by wildland fire.

• Analytical Science and Technology
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• v.15 no.5
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• pp.417-426
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• 2002

Inductively Coupled Plasma Dynamic Reaction Cell Quadrupole Mass Spectrometry (ICP-DRC-QMS) was characterized for the detection of the six naturally occurring calcium isotopes. The effect of the operating conditions of the DRC system was studied to get the best signal-to-noise ratio. This experiment shows that the potentially interfering ions such as $Ar^+$, ${CO_2}^+$, ${NO_2}^+$, $CNO^+$ at the calcium masses m/z 40, 42, 43, 44 and 48 were removed by flowing $NH_3$ gas at the rate of 0.7 mL/min $NH_3$ as reactive cell gas in the DRC with a RPq value (rejection parameter) of 0.6. The limits of detection for $^{40}Ca$, $^{42}Ca$, $^{43}Ca$, $^{44}Ca$, and $^{48}Ca$ were 1, 29, 169, 34, and 15 pg/mL, respectively. This method was applied to the determination of calcium in synthetic food digest samples (CCQM-P13) provided by LGC for international comparison. The isotope dilution method was used for the determination of calcium in the samples. The uncertainty evaluation was performed according to the ISO/GUM and EURACHEM guidelines. The determined mean concentration and its expanded uncertainty of calcium was ($66.4{\pm}1.2$) mg/kg. In order to assess our method, two reference samples, Riverine Water reference sample (NRCC SLRS-3) and Trace Elements in Water reference sample (NIST SRM 1643d), were analyzed.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.6
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• pp.73-82
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• 2012

The main and side reactions of the three selective catalytic reduction (SCR) reactions with ammonia over a vanadium-based catalyst have been investigated using synthetic gas mixtures in the temperature range of $170{\sim}590^{\circ}C$. The three SCR reactions are standard SCR with pure NO, fast SCR with an equimolar mixture of NO and $NO_2$, and $NO_2$ SCR with pure $NO_2$. Vanadium based catalyst has no significant activity in NO oxidation to $NO_2$, while it has high activity for $NO_2$ decomposition at high temperatures. The selective catalytic oxidation of ammonia and the formation of nitrous oxide compete with the SCR reactions at the high temperatures. Water strongly inhibits the selective catalytic oxidation of ammonia and the formation of nitrous oxide, thus increasing the selectivity of the SCR reactions. However, the presence of water inhibits the SCR activity, most pronounced at low temperatures. In this study, the experimental results are analyzed by means of a dynamic one-dimensional isothermal heterogeneous plug-flow reactor (PFR) model according to the Eley-Rideal mechanism.

• Journal of the Society of Naval Architects of Korea
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• v.56 no.6
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• pp.515-522
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• 2019

Since Liquefied Natural Gas (LNG) is normally carried at 1.1 bar pressure and at -163℃, special Cargo Containment System (CCS) are used. As LNG carrier is becoming larger, typical LNG insulation systems adopt a method to increase the thickness of insulation panel to reduce sloshing load and Boil-off Rate (BOR). However, this will decrease LNG cargo volume and increase insulation material costs. In this paper, silica aerogel, glass bubble were synthesized in polyurethane foam to increase volumetric efficiency by improving mechanical and thermal performance of insulation. In order to increase dispersibility of particles, ultrasonic dispersion was used. Dynamic impact test, quasi-static compression test at room temperature (20℃) and cryogenic temperature (-163℃) was evaluated. To evaluate the thermal performance, the thermal conductivity at room temperature (20℃) was measured. As a result, specimens without ultrasonic dispersion have a little effect on strength under the compressive load, although they show high mechanical performance under the impact load. In contrast, specimens with ultrasonic dispersion have significantly increased impact strength and compressive strength. Recently, as the density of Polyurethane foam (PUF) has been increasing, these results can be a method for improving the mechanical and thermal performance of insulation panel.

• Korean Journal of Materials Research
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• v.23 no.9
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• pp.501-509
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• 2013

To evaluate the development of the microstructure and mechanical properties on surface modified and post-heattreated Inconel 718 alloy, this study was carried out. A friction stir process as a surface modification method was employed, and overlap welded Inconel 718 alloy as an experimental material was selected. The friction stir process was carried out at a tool rotation speed of 200 rpm and tool down force of 19.6-39.2 kN; post-heat-treatment with two steps was carried out at $720^{\circ}C$ for 8 h and $620^{\circ}C$ for 6 h in vacuum. To prevent the surface oxidation of the specimen, the method of using argon gas as shielding was utilized during the friction stir process. As a result, applying the friction stir process was effective to develop the grain refinement accompanied by dynamic recrystallization, which resulted in enhanced mechanical properties as compared to the overlap welded material. Furthermore, the post-heat-treatment after the friction stir process accelerated the formation of precipitates, such as gamma prime (${\gamma}^{\prime}$) and MC carbides, which led to the significant improvement of mechanical properties. Consequently, the microhardness, yield, and tensile strengths of the post-heat-treated material were increased more than 110%, 124% and 85 %, respectively, relative to the overlap welded material. This study systematically examined the relationship between precipitates and mechanical properties.

• Journal of Ocean Engineering and Technology
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• v.24 no.5
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• pp.16-21
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• 2010

During the loading/offloading operation of a liquefied natural gas carrier (LNGC) that is moored in a side-by-side configuration with an offshore plant, sloshing that occurs due to the partially filled LNG tank and the interactive effect between the two floating bodies are important factors that affect safety and operability. Therefore, a time-domain software program, called CHARM3D, was developed to consider the interactions between sloshing and the motion of a floating body, as well as the interactions between multiple bodies using the potential-viscous hybrid method. For the simulation of a floating body in the time domain, hydrodynamic coefficients and wave forces were calculated in the frequency domain using the 3D radiation/diffraction panel program based on potential theory. The calculated values were used for the simulation of a floating body in the time domain by convolution integrals. The liquid sloshing in the inner tanks is solved by the 3D-FDM Navier-Stokes solver that includes the consideration of free-surface non-linearity through the SURF scheme. The computed sloshing forces and moments were fed into the time integration of the ship's motion, and the updated motion was, in turn, used as the excitation force for liquid sloshing, which is repeated for the ensuing time steps. For comparison, a sloshing motion coupled analysis program based on linear potential theory in the frequency domain was developed. The computer programs that were developed were applied to the side-by-side offloading operation between the offshore plant and the LNGC. The frequency-domain results reproduced the coupling effects qualitatively, but, in general, the peaks were over-predicted compared to experimental and time-domain results. The interactive effects between the sloshing liquid and the motion of the vessel can be intensified further in the case of multiple floating bodies.

• Journal of Hydrogen and New Energy
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• v.22 no.2
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• pp.152-160
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• 2011

The electromagnetic characteristics of FCEVs (fuel cell electric vehicles) are much different from the existing combustion engine cars as well as hybrid, plug-in-hybrid, and pure electric vehicles due to the high voltage/current generated by a fuel cell stack which uses a compressed hydrogen gas reacted with oxygen. To operate fuel cell stack efficiently, BOP (Balance of Plant) which is consisted of many motors in water pump, air blower, and hydrogen recycling pump as well as inverters for these motors is essential. Furthermore, there are also electric systems for entertainment, information, and vehicle control such as navigation, broadcasting, vehicle dynamic control systems, and so on. Since these systems are connected by high voltage or general cables, EMC (Electromagnetic compatibility) analysis for high voltage and general cable of FCEV is the most important element to prevent the possible electric functional safety errors. In this paper, electromagnetic fields by high voltage and general cables for FCEVs is studied. From numerical analysis results, total time harmonic electromagnetic field strength from high voltage and general cables have difference of 13~16 dB due to ground effect by impedance matching. The EMI results of FECV at 10 m distance shows difference of 41 dB at 30 MHz and 54 dB at 230 MHz compared with only general cable routing.

• Journal of Soil and Groundwater Environment
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• v.17 no.5
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• pp.49-55
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• 2012

A 1.28 L-batch reactor and continuous-flow stirred tank reactor (CFSTR) fed with formate and trichloroethene (TCE) were operated for 120 days and 56 days, respectively, to study the effect of formate as electron donor on anaerobic reductive dechlorination (ARD) of TCE to cis-1,2-dichloroethylene (c-DCE), vinyl chloride (VC), and ethylene (ETH). In batch reactor, injected 60 ${\mu}mol$ TCE was completely degraded in the presence of 20% hydrogen gas ($H_2$) in less than 8 days by anaerobic dechlorination mixed-culture (300 mg-soluble protein), Evanite Culture with ability to completely degrade tetrachloroethene (PCE) and -TCE to ETH under anaerobic conditions. Once the formate was used as electron donor instead of hydrogen gas in batch or chemostat system, the TCE-dechlorination rate decreased and acetate production rate increased. It indicates that the concentration of hydrogen produced in both systems is possibly more close to threshold for homoacetogenesis process. Soluble protein concentration of Evanite culture during the batch test increased from 300 mg to 688 mg for 120 days. Through the protein monitoring, we confirmed an increase of microbial population during the reactor operation. In CFSTR test, TCE was fed continuously at 9.9 ppm (75.38 ${\mu}mol/L$) and the influent formate feed concentration increased stepwise from 1.3 mmol/L to 14.3 mmol/L. Injected TCE was accumulated at 18 days of HRT, but TCE was completely degraded at 36 days of HRT without accumulation of the injected-TCE during the left of experiment period, getting $H_2$ from fermentative hydrogen production of injected formate. Although c-DCE was also accumulated for 23 days after beginning of CFSTR operation, it reached steady-state in the presence of excessive formate. We also evaluated microbial dynamic of the culture at different chemical state in the reactor by DGGE (denaturing gradient gel electrophoresis).

• Journal of the Korean Institute of Gas
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• v.26 no.2
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• pp.49-55
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• 2022

According to reinforce environmental regulations, coal power plants have used selective catalytic reduction using ammonia as a reducing agent to reduce the amount of nitrogen oxide generation. The purpose of the present study was to derive a mixing device for effectively mixing dilute air and ammonia in the ammonia mixing pipe by performing computational fluid dynamic analysis. The mixing effect was compared by analysing the %RMS of ammonia concentration at the down stream cross section in the mixing pipe and the 16 outlets based on the case 1-1 shape, which is an existing mixing pipe without a mixing device. The mixing device was performed by changing the positions of a square plate on the downstream side of the ammonia supply pipe and an arc-shaped plate on the wall of the mixing pipe. In the case of the existing geometry(Case 1-1), the %RMS of ammonia concentration at the 16 outlets was 29.50%. The shape of the mixing device for Case 3-2 had a square plate on the downstream side of the ammonia supply pipe and an arc plate was installed adjacent to it. The %RMS of ammonia concentration for Case 3-2 was 2.08% at 16 outlets and it could be seen that the shape of Case 3-2 was the most effective mixing shape for ammonia mixing.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.362-362
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• 2014

Atomic layer deposition (ALD) can be regarded as a special variation of the chemical vapor deposition method for reducing film thickness. ALD is based on sequential self-limiting reactions from the gas phase to produce thin films and over-layers in the nanometer scale with perfect conformality and process controllability. These characteristics make ALD an important film deposition technique for nanoelectronics. Tantalum pentoxide ($Ta_2O_5$) has a number of applications in optics and electronics due to its superior properties, such as thermal and chemical stability, high refractive index (>2.0), low absorption in near-UV to IR regions, and high-k. In particular, the dielectric constant of amorphous $Ta_2O_5$ is typically close to 25. Accordingly, $Ta_2O_5$ has been extensively studied in various electronics such as metal oxide semiconductor field-effect transistors (FET), organic FET, dynamic random access memories (RAM), resistance RAM, etc. In this experiment, the variations of chemical and interfacial state during the growth of $Ta_2O_5$ films on the Si substrate by ALD was investigated using in-situ synchrotron radiation photoemission spectroscopy. A newly synthesized liquid precursor $Ta(N^tBu)(dmamp)_2$ Me was used as the metal precursor, with Ar as a purging gas and $H_2O$ as the oxidant source. The core-level spectra of Si 2p, Ta 4f, and O 1s revealed that Ta suboxide and Si dioxide were formed at the initial stages of $Ta_2O_5$ growth. However, the Ta suboxide states almost disappeared as the ALD cycles progressed. Consequently, the $Ta^{5+}$ state, which corresponds with the stoichiometric $Ta_2O_5$, only appeared after 4.0 cycles. Additionally, tantalum silicide was not detected at the interfacial states between $Ta_2O_5$ and Si. The measured valence band offset value between $Ta_2O_5$ and the Si substrate was 3.08 eV after 2.5 cycles.