• Title/Summary/Keyword: Dyeing wastewater treatment

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Improvement of the Biodegradability of Polyvinyl Alcohol by Radiation Treatment (방사선 처리에 의한 폴리비닐 알콜의 생분해도 개선)

  • Jung, Jinho;Park, Nam-Young;Jo, Hun-Je;Lee, Sun-Mi;Kim, Jeong-Gyu
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.241-244
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    • 2004
  • Radiation treatment with gamma-rays and electron-beams was used to remove polyvinyl alcohol(PVA), one of the main components of dyeing wastewater. PVA was effectively decomposed by radiation treatment, thus the removal was near 100 % at an initial PVA concentration of 44 mg/L. However, total organic carbon(TOC) removal was less than 5 % due to lower transformation of PVA to $CO_2$. This directly indicates the radiation treatment alone is not appropriate for the complete decomposition of PVA. In this sense, the improvement of biodegradability($BOD_5/COD$) of PVA by radiation treatment was studied. Both gamma-ray and electron-beam treatments significantly increased the biodegradability of PVA by transforming non-biodegradable PVA to biodegradable by-products. This suggests radiation treatment, especially electron-beam treatment that showed better improvement of biodegradability, can be used as a pre-treatment of biological degradation process of PVA.

Microbe Isolation and Optimization for the Decolorization of Reactive Dye (반응성 염료의 색도 제거를 위한 균주 분리 및 최적화)

  • 신종철;최광근;전현희;김상용;이진원
    • KSBB Journal
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    • v.19 no.3
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    • pp.200-205
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    • 2004
  • For decolorization of various reactive dyes, 13 species of microbes were isolated from dyeing wastewater collected from Banweol industrial complex, Korea. Two strains among them showed good ability for removing celerity during the decolorization test with 5 different reactive dyes. And the optimal growth conditions were pH 7, 35$^{\circ}C$, yeast extract as nitrogen source, glucose as carbon source, and facultative anaerobic condition. As results, when Reactive Red 180 was used, 89 and 87% of decolorization efficiency were able to be obtained by using Bacillus anthracis and Bacillus cereus, respectively. Especially, Bacillus cereus showed good ability for decolorization of Reactive Blue 21, and the ratio was 76% Finally, it was considered that these two strains isolated in this study will be showed high decolorization ability to treat dyeing wastewater.

Reuse Technology Development and Economic Evaluation of Dyeing Wastewater Treatment Sludge (폐수처리슬러지의 재활용기술개발 및 경제성 평가 -B염색조합을 중심으로-)

  • 임재호;이정연
    • Resources Recycling
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    • v.9 no.1
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    • pp.36-43
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    • 2000
  • This study was carried out for treatment and reuse of inorganic sludge from Fenton process at B dyeing wastewater treatment plant. The parameters for pilot-scale treatment system were derived from the results of this study. It was found that $COD_{cl}$ of the treated effluent became lower than 100 mg/l approximately on the optimal reaction condition. 2nd sludge which was generated after redissolving sludge was analyzed, and it showed that reduction ratio of ash in 2nd sludge and total dry sludge weight in comparison with current sludge were 85% and 65%. Also Fe salt in sludge was redissolved about 90~95% of initial Fe by weight. It was estimated almost ₩350,000,000 for sludge reuse process. It was estimated saving of about ₩1,300,000 per day (₩420,000,000 per year) in operating cost based on 30,000 $m^3$/d treatment, which these were about ₩430,000 per day in chemical, ₩1,100,000 per day in sludge transportation and ₩200,000 per day in equipment maintenance. Payback period with interest charge for investment cost was estimated about 10.5 months. Also, net present value (NPV) was ₩792,000,000 and internal rat of return (IRR) was about 110%.

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Isolation and Culture Characteristics of Strains for Color Removal of Disperse Dyes (분산성 염료의 색도제거를 위한 균주의 분리 및 성장 특성)

  • 조무환;허만우;한명호;강건우
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.25-31
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    • 2000
  • In order to decolorize disperse dyes by using biological treatment process, a strain which has potential ability to degrade disperse dyes was isolated from natural system. To increase the removal efficiency of decolorization in the aqueous solutions, the optimal condition of decolorization by this strain was investigated, and continuous plant test was also developed. The optimal culture conditions of temperature and pH were found to be 4$0^{\circ}C$ and 8.5~9, respectively. When yeast extract was mixed with polypeptone at the mixing ratio of 1:1 as a nitrogen source, decolorization efficiency was highest(93%) among the nitrogen sources. The strain to be screened was excellent to adjust to pH, and it seems to be have ability to control pH needed to growth. The optimal culture conditions in concentration of $MgSO_4\cdot{7H}_2O$ and $KH_2PO_4$ were 0.1%(w/v) and 0.2%(w/v). The result of continuous plant process using wastewater was as following : $COD_{Mn}$ removal efficiency was over than 50%, and this strain was very excellent in decolorization-efficiency for the wastewater of Taegu dyeing complex.

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Photocatalytic Membrane for Contaminants Degradation: A Review (오염물질 분해를 위한 광촉매 분리막: 총설)

  • Kahkahni, Rabea;Patel, Rajkumar;Kim, Jong Hak
    • Membrane Journal
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    • v.32 no.1
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    • pp.33-42
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    • 2022
  • Growing industrialization leads to severe water pollution. Organic effluents from pharmaceuticals and textile industries released in wastewater adversely affect the environment and human health. Presence of antibiotics used for antibacterial treatment in wastewater leads to the growth of drug resistance bacteria, which is very harmful for human being. Various small organic molecules are used for the preparation of organic dye molecules in the textile industries. These molecules hardly degrade, which is present in the wastewater effluents from printing and dyeing industries. In order to address these problems, photoactive catalyst is embedded in the membrane and wastewater are passed through it. Through this process, organic molecules are photodegraded and at the same time, the degraded compounds are separated by the membrane. Titanium dioxide (TiO2) is a semiconductor which behave as excellent photocatalyst. Photocatalytic ability is enhanced by the making its composite with other transition metal oxide and incorporated into polymeric membrane. In this review, the degradation of dye and drug molecules by photocatalytic membrane are discussed.

Organic Wastewater Treatment Using Modified Fenton's Oxidation (변형 펜턴산화법을 이용한 유기폐수의 처리)

  • Kim, Ji Yeon;Yoon, Tai Il;Park, Se Jin
    • Clean Technology
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    • v.5 no.1
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    • pp.49-61
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    • 1999
  • Fenton's oxidation can improve the biodegradability of refractory organic wastewater by generating $OH{\cdot}$ which is one of the most reactive species. Fenton's reagent is used to treat a variety of industrial waste containing a range of toxic organic compounds. But this process cannot be economical because of high chemical cost of $H_2O_2$, ferrous ion solution and high sludge disposal cost. In this study, we proposed a modified Fenton's oxidation process which can reduce the reagent cost and obtain better removal efficiencies with less Fenton's reagents, and have a good potential of sludge recycling. In modified Fenton reaction, ferrous ion solution is adjusted to optimal pH with NaOH. Then it added to the sample and reacted to $H_2O_2$. For the experiment, synthetic wastewater made of phenol, which is one of the typical water pollutants, was used and the ionic strength of this wastewater was controlled by adding $NaHCO_3$. The effects of DO, ionic strength, and $H_2O_2$ dosing methods were investigated. As a result, modified Fenton's treatment efficiencies are better than conventional Fenton's reaction treating leachate and dyeing wastewater. And modified Fenton's treatment efficiencies combined to the sludge recycling for a half of Iron dosage are as good as the conventional Fenton's for a normal Iron dosage.

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Refractory Textile Wastewater Treatment Using Cell-Immobilized Polyethylene glycol Media (PEG 포괄고정화담체를 이용한 난분해성 염색폐수 처리)

  • Han, Duk-Gyu;Cho, Young-Jin;Bae, Woo-Keun;Hwang, Byung-Ho;Lee, Yong-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.345-350
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    • 2006
  • This study investigated the removal of recalcitrant organics in dyeing wastewater using a fluidized bed reactor(FBR) that contained cell-immobilized pellets. The pellets were manufactured and condensing the gel phase by mixing PEG-polymer and cells to form micro-porous PEG-polymer pellets whose size were ${\Phi}\;4mm{\times}H\;4mm$ on average. An industrial activated sludge without any pre-adaptation was used for the cell immobilization because it gave an equivalent removal efficiency to a pre-adapted sludges. The feed was obtained from an effluent of a biological treatment plant, which contained $SCOD_{Cr}$ of 330 mg/L and $SBOD_5$ of 20 mg/L. The $SCOD_{Cr}$ removal efficiency was over 45% and the effluent $COD_{Mn}$ concentration was less than 100 mg/L at HRTs from 6 to 24 hrs. The optimum HRT in the FBR was determined as 12 hrs considering the removal efficiency and cost. When a raw wastewater containing 768 mg/L of $COD_{Cr}$ was fed to the FBR, the effluent $COD_{Cr}$ concentration increased only slightly, giving a 70% of $COD_{Cr}$ removal or a 97% of $BCOD_5$ removal. This indicated that the FBR had an excellent capability of biodegradable organics removal also. In conclusion, the FBR could be applied to textile wastewater treatment in place of an activated sludge process.

Treatment of dyeing wastewater using Moving Bed Bioractor (부유메디아 생물막 공정을 이용한 염색폐수처리)

  • Shin, Dong-Hoon;Lee, Sang-Hun;Ryu, Seung-Han;Park, Jun-Hyung;Jo, Seog-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.110-110
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    • 2011
  • 염색공업 폐수는 그 성분이 일반적으로 매우 복잡하며, 작업공정의 가동 사항에 따라 수질 변동이 큰것이 특징으로, 각 공정에서 배출되는 염료, 보조화학물질, PVA(Polyvinyl alchol), 전분, wax 등이 포함되어 있으며 pH가 높고, 색도로 인해 하천에 방류될 경우 확산성이 높아 미생물에 의한 자정작용을 방해하여 하천의 수중생태계를 파괴할 우려가 있다. 이러한 염색산업에서 발생하는 폐수는 일반적으로 응집침전, 부상분리법 등의 전처리한 후 활성오니공정으로 처리하는 방법이 널리 이용되고 있으나, 이들 처리공정으로는 폐수 속에 포함되어 있는 다양한화학적 구조의 색소성분 및 유해물질을 완벽하게 제거하는 것이 어려운 실정이다. 유기물 함량이 높은 염색폐수를 처리하기 위해 제안된 기술로는 산소활성슬러지법, 유동상 및 고정상 생물막법, 포괄고정화법 등이 있다. 이러한 기술들중 기존의 처리공정을 증축없이도 처리효율을 높일 수 있는 방법으로 담체를 이용한 부유메디아 생물막공정(Moving-Bed BioReactor, MBBR)이 있다. 이공정은 미생물이 부착, 성장할 수 있는 공극율과 비표면적이 큰 담체를 이용하므로 반응조내의 부유 미생물 뿐만 아니라 담체에 고농도로 부착된 부착 미생물에 의해서도 유기물을 제거하기 때문에 다른 공정들에 비해 처리효율이 뛰어나고 기존의 활성슬러지 공정에 비해 갑작스러운 부하변동 및 유독성 폐수유입에 대해서도 안정적으로 운전이 가능한 장점이 있다. 본연구에서는 부유메디아 생물반응기(Moving-Bed BioReactor, MBBR)을 이용하여 염색폐수내 $COD_{Mn}$, 색도 및 난분해성 물질인 PVA 저감에 대한 Lab-scale test 수행하였다. 실험에 사용된 염색폐수의 수질은 평균 pH 13, $COD_{Mn}$ 900 mg/L, SS 135 mg/L, 색도 1,134 [C.U.], PVA 593 mg/L였으며, 2L의 반응기를 사용하여 회분식 실험을 수행였다. 본 실험에서는 호기성 미생물에 의한 염색폐수의 생분해가 유지되는데 필요한 최적의 용존산소 농도와 이에 필요한 공기 폭기량을 결정하기 위하여 i) DO uptake rate측정과 ii) 담체의 충진율, iii) COD/N ratio, iv) Air 유량, v) 담체내 흡착제의 종류, vi) $Ca^{2+}$ 첨가가 염색폐수의 생분해에 미치는 영향을 살펴보았다. 운전시간을 7일로 하여 COD, 색도, PVA 등을 측정한 결과 담체를 첨가한 경우가 담체를 첨가하지 않은 경우 보다 제거효율이 뛰어났다. 특히 충진율 30%(C/N 3)의 경우에서 COD, 색도, PVA의 제거율이 각각 평균 65%, 70%, 60%로 가장 높은 제거효율을 나타내었다.

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Responses of Rice (Oryza sativa L.) Yield and Percolation Water Qualities to Alternative Irrigation Waters

  • Shin, Joung-Du;Han, Min-Su;Kim, Jin-Ho;Jung, Goo-Bok;Yun, Sun-Gang;Eom, Ki-Cheol;Lee, Myoung-Sun
    • Korean Journal of Environmental Agriculture
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    • v.22 no.3
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    • pp.192-196
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    • 2003
  • Objective of this study was to investigate the influences of harvest index and percolation water quality as irrigated the discharge waters from an industrial and a municipal wastewater treatment plants and seawater (1:5 seawater: tap water) as alternative water resources during tillering stage for drought stress. There were four different treatments such as the discharge water from an industrial (textile dyeing manufacture plant) wastewater treatment plant (DIWT), discharge water from the municipal wastewater treatment plant (DMWT), seawater (1:5) and groundwater as a control. For the initial chemical compositions of alternative waters, it appeared that higher concentrations of COD, $Mn^{2+}$, and $Ni^+$ in DIWT were observed than reused criteria of other country for irrigation, and concentrations of $EC_i$, Cl, and $SO_4$ in seawater were higher than that for irrigation. Harvest index was not significantly different between DIWT and DMWT with different irrigation periods in two soil types, but that of seawater (1:5) is decreased with irrigation periods in clay loam soil and not different between 10 days and 20 days of irrigation periods in sandy loam soil. For percolation water qualities, values of sodium adsorption ratio (SAR) are increased with prolonging the irrigation periods of seawater (1:5) and DIWT, but those of DMWT were almost constant through the cultivation periods regardless of the irrigation period in both soil types. EG of percolation waters is eventually increased with prolonging days after irrigation regardless of irrigation periods in both soil types. Therefore, it might be concluded that there was potentially safe to irrigate the discharge water from municipal wastewater treatment plant relative to harvest index, SAR and $EC_i$ values of the ground water through the rice cultivation period at tillering stage for drought period.

The decolorization treatment of dye solutions by ozone (Ozone을 이용한 염료용액의 탈색 처리)

  • Lee, Soo-Kyung;Cho, Hwan;Jeong, Hee-Cheon
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.17-24
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    • 1996
  • Dye solutions were tested in order to find the optimal condition of ozonation and determine the progress of degradation, i.e., change of the parameters characterizing the dye solutions. From the results of our experiment we can conclude that almost all of the color was removed within a 10 minute time period. An ozone oxidation results in the effective removal of COD(60%). but the elimination of the total organic carbon(TOC) was not successful, only about 15~40% of TOC was removed from dyeing wastewater in 30 minutes. The color removal is much effective in using ozonation method.

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