• 한국의류학회지
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• 제35권1호
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• pp.115-124
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• 2011

This study provides an eco-friendly dyeing processing for chitosan fiber using Oenothera odorata jacquin as a dye. The effects of chemical mordants (Al, Cu, Fe) and natural mordant (Chestnut shell) on the color change for dyed chitosan fibers were measured by K/S values, L, $a^*$, $b^*$, H, V, C values, color fastness, and antimicrobial activity. The results are as follows. Dyeing conditions of Oenothera odorata jacquin on chitosan fibers were optimized to $70^{\circ}C$, 30 minutes and 200% on weight of fabric (o.w.f.). The pre-mordant concentration of aluminium (Al), copper (Cu) and iron (Fe) of chitosan fibers was optimized to 3% (o.w.f.) and 1% (o.w.f.), respectively. The post-mordant concentration of chemicals, such as Al, Cu and Fe, on chitosan was determined to 1% (o.w.f.). The hue of chitosan fibers by chemical mordants was measured to be reddish & yellow. The pre-mordant concentration of Chestnut shell of chitosan was optimized to 70% (o.w.f.). The post-mordant concentration of Chestnut shell on chitosan was determined to be 50% (o.w.f.). The hue of chitosan fibers by Chestnut shell mordant was measured to be reddish & yellow. The wet cleaning fastness of chitosan fibers was improved by a pre-mordant that used chemical mordants. In the case of the Chestnut shell mordant, the wet cleaning fastness was improved by a post-mordant. The dry cleaning fastness of chitosan fibers was excellent regardless of mordants and mordant methods. The antimicrobial activity of the chitosan fiber was shown at 99.9% and its excellent qualities remained after the dyeing and mordant processing.

• 한국의류산업학회지
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• 제21권4호
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• pp.509-514
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• 2019

Cotton fabrics were treated with gelatin to enhance dyeability and color strength when using Caesalpinia sappan dye. Gelatin was used as the protein and a pad-dry- cure method was used for the treatment process (2, 4, 6, 8, 10, 12, 14g/l concentration). Pretreated fabrics were mordanted with 10% alum. Fabrics were then dyed with freeze-dried sappan wood water extract powder form. Dyed samples were assessed in regards to dyeing behavior and color fastness. Comparing untreated and gelatin treated samples from the SEM images indicated that the Gelatin treatment (10g/l) resulted in an enhanced surface roughness that was relative to that of untreated cotton. Padding cotton with gelatin at 6g/l concentration afforded dyed fabrics with a 2 times increase in the K/S value over that of untreated fabrics. All dyed samples were red color with a significant enhancement in the sample color strength (K/S) being observed for pretreated samples. pH values favor dye absorption with pH 7 yielding the highest color strength. Dyeing at an elevated temperature resulted in a lower color strength and reddish-dull color. Longer dyeing times created greater color strengths for untreated and gelatin treated cotton. Increased dye concentrations resulted in higher K/S values for both gelatin treated and untreated cotton. As for color fastness, gelatin treated and untreated cotton fabrics dyed with sappan wood extract showed a relatively low rating in washing fastness (color change 1 rating), light fastness (1 rating), and rubbing fastness (wet:1-2, dry:3-4 rating).

• 한국의류학회지
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• 제48권4호
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• pp.707-728
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• 2024

This study aimed to assess the colorizing properties of bacterial cellulose (BC) using plant-based dyes, namely spinach, beet, and banana peel, and determine the dyeing conditions of each dye based on color strength (K/S) values. Tannic acid and walnut shell powder were utilized as bio-mordants, and their effects on the dyeability of BC were compared to metallic mordants. Additionally, the type of mordant and the mordanting method were assessed according to their rubbing fastness and dry-cleaning fastness. The K/S values of the colorized and mordanted BCs were also compared to examine their mordanting conditions. Finally, the mordanting conditions for spinach, beet, and banana peel dyeing were selected as post-mordanting with tannic acid, meta-mordanting with tannic acid, and post-mordanting with walnut shell powder, respectively. Based on the results, the selected mordanting conditions improved both rubbing fastness and dry-cleaning fastness of BCs to grade 5, and the light fastness achieved grade 4-5. The tensile strength and flexibility of the dyed BCs were also enhanced and comparable to that of untreated cowhide leather.

• 한국염색가공학회지
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• 제26권3호
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• pp.165-172
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• 2014

Novel super hydrophobic orange dyes having maximum absorption band at 450-500nm were synthesized to dye polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers, using 4-alkylanilines and ${\beta}$-naphthol. Their absorption spectra at visible range showed almost the same, which meant that the alkyl substituents introduced to chromophore did not affect on color appearance of the dyes. Considering both color strength and wash fastness, the decyl-substituted dye was determined as the optimum one practically. From the dyeing results at various conditions, the optimum dyeing was $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing 4-5 for both fibers. Light fastness was also acceptable giving rating 3-4 for polypropylene fibers and rating 3 for ultra high molecular weight polyethylene fibers.

• 한국의류학회지
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• 제21권4호
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• pp.661-668
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• 1997

The dyeing characteristics of acorn was investigated. The natural Fabrics-cotton, rayon and silk-were dyed repeatedly in the solution extracted from acorn, CuSO4, K2Cr2O7 and brine were used as mordants to improve color fastness. Anti-bacterial property was measured in the dyed and mordant treated fabrics. When the cotton and rayon fabrics were dyed and treated with CuSO4, their colors showed very clear. They also had good color fastness and excellent anti-bacterial property. The dyed silk fabrics had better dye absorption property than the cotton and rayon fabrics without mordant treatment. But the fabrics dyed without mordant treatment had low light fastness. The cotton, rayon and silk fabrics dyed and treated with brine were dark and unclear. An aftertreatment with CuSO4 and K2Cr2O7 made the dyed fabrics darter and more clear.

• 한국염색가공학회지
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• 제25권3호
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• pp.165-171
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• 2013

A new monoazo violet dye optimized for polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers was synthesized and its dyeability was investigated. Two hexyl groups were introduced to coupler, 2,5-dimethoxyaniline, in order to increase hydrophobicity of the dye. The maximum absorption wavelength was appeared at 580nm, which meant that the dye showed violet color. From the dyeing results at various conditions, the optimum dyeing was determined as $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing at least 4 for both fibers. Light fastness was acceptable for polypropylene fibers giving ratings 3~4. However, relatively poor light fastness was obtained in case of ultra high molecular weight polyethylene fibers showing ratings 2.

• 한국염색가공학회지
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• 제22권1호
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• pp.14-20
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• 2010

Squid ink was purified to melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions. The exhaustion dyeing conditions of melanin to wool fabrics were investigated in relation with pH, melanin concentration, dyeing temperature and time. The melanin was dyeable to cotton and wool fabrics but higher dyeability of the wool was observed. A K/S of 7 was obtained on the optimally dyed wool fabrics with 5 % owf melanin under pH 4 at $100^{\circ}C$ for 60 minutes. Color fastness to both washing and rubbing was excellent and color fastness to light was also very good probably due to the polymeric nature of the extracted sepia melanin.

• 한국염색가공학회지
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• 제10권1호
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• pp.1-10
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• 1998

The objectives of this study were to investigate the effects of mordants and dyeing method : on the dyeability and color fastness of the fabrics with the extract from Gardenia. The following results were drawn from the data obtained. 1. The wavelengths of the strongest absolution bands of Amur cork tree, Gardenia extract was 440nm respectively and the wavelengths 440-460nm after the mordants were added in the color extracts(The bands of Gardenia extract shifts to short wavelength side as pH increased.). In all cases, the abosorbancies were increased. 2. The main color substances in extract from Gardenia were expected to be cretin respectively by spectrophotometric and HPLC studies. 3. As to the concentration of color extract for dyeing, about 20g/L was the optimum concentration to dye silk and cotton fabrics with extract. 4. For silk and cotton fabrics dyeing with Gardenia extract, $SnCl_2$ was the best mordants. The K/S values of dyed fabrics were increased gradually as the concentration of mordants increased, and the highest K/S values were obtained at 5-10%. When using the mordanting methods, silk fabric by premordanting and cotton fabric by synmordanting had a greater effect K/S value. 5. The color fastness of fabrics dyed with Gardenia extract against dry cleaning, washing, rubbing and perpiration was improved 1 level or so but light fastness was remained 1 level showing without any effect.

• 한국염색가공학회지
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• 제24권4호
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• pp.270-280
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• 2012

This study examined the dyeing characteristics of five oriental herbs, namely Gardenia jasminoides, Sophora japonica L., Rheum coreanum, Rhus javanica L., Ginkgo biloba L., on fabrics with traditional fermentation using malt. And the properties of Hwangsu (mineral water) of Yeongcheon (Korea)as a mordant in the post-treatment of textile were evaluated. The dyeability and fastness of cotton fabric and silk to light and washing as well as different fermentation periods and temperatures were investigated, and the following results were obtained. The dyeability of the fermented and non-fermented material did not show a significant difference. Fabrics mordanted with Hwangsu generally exhibited a reddish color due to the presence of iron. The dyeing of cotton fabric and silk by fermentation and Hwangsu mordanting were found to be effective on Rhus javanica L. and Rheum coreanum. These results were confirmed through fastness to light 3 of cotton on Rheum coreanum and 3-4 of silk on Rhus javanica L., respectively. The washing fastness of both fabrics dyed with fermented Rhus javanica L. and Rheum coreanum was improved, showing higher K/S value after washing than before washing.

• 한국의상디자인학회지
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• 제5권3호
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• pp.1-6
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• 2003

The purpose of this study was to investigate the dyeability and color fastness of cotton and silk fabrics dyed with extract of Arrowroot leaf princeps. The experimental items were divided into the mordant treatment, component of fabric and kind of mordants. The experimental study was done by laundering, abrasion(dry/wet), perspiration(acid/alkali), light fastness, color difference by C.C.M system and K/S test. The summerized finding reulted from experiment and investigation are suggested as follows : In the C.C.M and K/S test on mordanting method and kind of fabric, that of silk and cotton was the most effective in the pre mordant treatment. In the C.C.M and K/S analysis on 5 mordants, that of silk and cotton was significantly improved when mordants was treatmented. Especially, that of Fe mordanting treatment was higher than Al, Cu, Cr and none. In color fastness on mordants, laundering, perspiration and abrasion fastness showed 4-5 grade but light fastness showed 1-3 grade.