• Journal of the Korean Society of Clothing and Textiles
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• v.35 no.12
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• pp.1507-1517
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• 2011

Berberine, palmatine, and Phellodendron bark dye was prepared in methanol for HPLC-DAD-MS analysis of liquid dye. Silk was dyed using berberine, palmatine, and Phellodendron bark dye prepared in water. The dye was extracted from the dyed silk using the HCl/methanol/water (2:1:1 v/v/v) solvent system with a slight modification. The liquid dyes and the dye extracted from the silk samples dyed with the three dye sources were examined using the HPLC-DAD-MS analysis to simultaneously detect berberine and palmatine from the plant dye and the dyeings. Colorimetric measurement was carried out using a spectrophotometer to examine the color and the intensities of berberine, palmatine, and Phellodendron bark dyed silk samples. From the liquid dyes, berberine eluted at 5.21 min with the molecular cation m/z=336 and the UV spectrum confirming that the product was berberine. Palmatine eluted at 5.12 min with the molecular cation m/z=352 and the UV spectrum confirming that the product was palmatine. From the silk dyed with berberine and palmatine dye, berberine and palmatine species eluted at 5.35 min and 5.24 min, respectively. From the silk dyed with Phellodendron bark, berberine and palmatine were detected simultaneously at 5.35 min and 5.26 min, respectively. All three dyes had yellow hue while palmatine dyed silk showed the highest hue and chroma. Palmatine dyed silk showed the highest K/S value that indicated the strongest color intensity and the highest dye uptake.

• Textile Coloration and Finishing
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• v.28 no.3
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• pp.175-182
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• 2016

To investigate dyeing behaviors in accordance with dye structure in cold pad batch dyeing of cotton knit, monochlorotriazine-vinylsulfone bifunctional dyes and monofluorotriazine-vinylsulfone bifunctional dyes were prepared. The spectral property and solubility of the dyes were tested and compared with the imported dyes. In addition, exhaustion behaviors of individual and mixed dye solutions were measured to examine the influence of dye structure on dyeing behavior in cold pad batch dyeing. The substantivity, fixation, migration index and half dyeing time were also calculated for further analysis of dyeing behavior of the prepared dyes. As a result, both dyes exhibited the superior solubilities and satisfactory light absorption properties. Also, monofluorotriazine-vinylsulfone bifunctional dyes showed moderate sensitivity to alkalinity and proper kinetic index values compared with the monochlorotriazine-vinylsulfone bifunctional dyes and the imported dyes. The results indicated monofluorotriazine-vinylsulfone bifunctional structure of the dye is suitable for cold pad batch dyeing.

• Textile Coloration and Finishing
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• v.31 no.3
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• pp.155-164
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• 2019

This study comparatively analyzed hair bleaching and degree of damage by the temperature of a heating tool after coloring hair with a permanent, semi-permanent or plant hair dye. According to analysis by spectrophotometer, 'semi-permanent hair dye' was the highest, followed by 'permanent hair dye' and 'plant hair dye' in terms of changes in $L^*$ values. In terms of changes in hair shape when analyzed using FE-SEM, 'semi-permanent hair dye($150^{\circ}C$ or lower)' was the greatest, followed by 'plant hair dye($180^{\circ}C$ or lower)' and 'permanent hair dye($200^{\circ}C$ or lower)'. Therefore, it is reasonable to flat iron hair at low temperature. According to the test, amino acid values gradually decreased in both bleached and colored hair. The results obtained through TGA-based thermal analysis confirmed that as brightness increases, hair moisture contents decrease. This study aimed to protect hair by suggesting a correct use of a flat iron by the hair dye type during hair coloring. It appears that the study results would help hairdressers minimize hair damage by using a hair dye at proper temperature.

• Advances in environmental research
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• v.1 no.2
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• pp.153-166
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• 2012

Decolourization potential of white rot fungal organism, coriolus versicolor, was investigated in a batch reactor, for textile dye industry wastewater. The influence of process parameters like pH, temperature, agitation speed and dye wastewater concentration on the decolourization of textile dye wastewater was examined by using Response surface methodology (RSM). The maximum decolourization was attained at: pH- 6.8, temperature - $27.9^{\circ}C$, agitation speed - 160 rpm and dye wastewater concentration - 1:2. From the analysis of variance (ANOVA) results it was found that, the linear effect of agitation speed and dye wastewater concentration were significant for the decolourization of textile dye wastewater. At these optimized condition, the maximum decolourization and chemical oxygen demand (COD) reduction was found to be 64.4% and 79.8% respectively. Various external carbon sources were tried to enhance the decolourization of textile dye wastewater. It was observed that the addition of carbon source enhances the decolourization of textile dye wastewater. Kinetics of textile dye degradation process was studied by first order and diffusional model. From the results it was found that the degradation follows first order model with $R^2$ value of 0.9430.

• Journal of the Korean Society of Clothing and Textiles
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• v.43 no.2
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• pp.228-242
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• 2019

This research investigated the effect of mordants on the degradation of madder dye in silk when silk was treated by the H2O2/UV condition as a laboratory simulation of burial induced degradation. Alum, iron, and alum/iron composite mordanting methods were applied to silk before dyeing with madder dye. Dye extracted from silk was examined using HPLC-DAD-MS analysis. The abundance of the chromatogram peak at 8.88 min retention time was used as the concentration of alizarin pigment in silk. K/S values, CIE $L^{\ast}a^{\ast}b^{\ast}$ values; in addition, Munsell HVC values were obtained using a spectrocolorimeter. The findings indicated that alizarin degraded most severely in silk mordanted by alum/iron composite mordanting than alum mordanting or iron mordanting. Mordanting with alum alone provided a relatively lower dye fixation at the point of dyeing; however, it provided a better survival of alizarin after 12 hours of degradation treatment.

• Textile Coloration and Finishing
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• v.33 no.4
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• pp.169-181
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• 2021

Five dyes based on phthalocyanine, a dye on azo, and a dye on anhraquinone were prepared from corresponding starting material to investigate the effects of substituent on thermal-stability of dyes which is essentially required to apply to the color filters. Synthesized dyes were confirmed their chemical structure using by 1H-NMR, MASS and Elemental analysis. The thermal-stability was evaluated by the weight reductions measured by TGA analysis comparing to that of conventional C.I. Pigment Blue 15:6. The absorption maxima were measured by UV-VIS spectrophotometer then the effects of substituent on absorption maximum was also investigated.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.12
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• pp.2425-2430
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• 2009

Dye-sensitized solar cell(DSC) is composed of a dye-adsorbed nanoporous $TiO_2$ layer on fluorine-doped tin oxide(FTO) glass substrate, electrolyte, and platinium doped counter electrode. Among these, a dye-absorbed nanoporous $TiO_2$ layer plays an important role in the performance of the DSC because the injected electrons from excited dye molecules move through this layer. And the condition of $TiO_2$ layer such as the morphology and thickness affects on the electron movement. Therefore, the performances and the efficiency of DSC change as the thickness of $TiO_2$ layer is different. Electrochemical Impedance Spectroscopy(EIS) is the powerful analysis method to study the kinetics of electrochemical and photoelectrochemical processes occurring in the DSC especially the injected electron movements. So we analyzed the DSCs with different $TiO_2$ thicknesses by using EIS to understand the influence of the $TiO_2$ thickness to the performance of the DSC clearly. Finally, we got the EIS analysis on the DSC with different $TiO_2$ thickness from the internal resistance of the DSC, the electron life time and the amount of dye molecules.

• Textile Coloration and Finishing
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• v.19 no.2
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• pp.14-23
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• 2007

This research article explores the use of phthalocyanine reactive dye on nylon substrate. The effect of factors such as pH, temperature, liquor ratio and alkali addition on level of dye exhaustion, fixation and total fixation efficiency. Low pH, high temperature and low liquor ratio were found to be suitable conditions for maximum % exhaustion values. The effect of sulphatoethylsulphone(SES) and vinylsulphone(VS) form of the dyes on level of dye fixation was also discussed. The optimized exhaustion (%E), fixation(%F) and total fixation efficiency were determined. Modification of the dyeing process with alkali addition displayed that dye fixation(%) increased by alkali addition. Vinylsulphone(VS) moiety of the dye was found to be superior to. maximum fixation (%F). Appropriate predictable empirical models, relatively a new approach in dyeing processes, were developed incorporating interactions effects of temperature, pH and liquor ratio for predicting % exhaustion, fixation and total fixation efficiency. The significance of the mathematical model developed was ascertained using microsoft excel regression(solver) analysis module. High correlation coefficient was obtained (R2=0.9895 for % exhaustion, R2=0.9932 for fixation, R2=0.9965 for total fixation efficiency) for the model which shows prominent prediction capacity of the model for my conditions. The predictable polynomial equations developed from tile experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

• The International Journal of Costume Culture
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• v.5 no.2
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• pp.53-65
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• 2002

Morphology of polyester fiber was physically modified by solvent treatment. PET fiber was treated with N,N-dimethylformamide (DMF) at 100, 120, $140^{circ}C$ for 10 minutes without tension. The structural changes in the morphology of DMF-induced modified PET fiber were FTIR and SEM analysis. Also dyeing behavior of DMF-treated polyester fibers with various disperse dyes was studied to detect changes of amorphous area in fine structure. DMF treatment resulted in increases in total void content, degree of crystallinity, trans isomer content, chain folding, segmental mobility and molecular packing, but it resulted in decreases in amorphous orientation, intermolecular forces and individual void size through longitudinal shrinkage, lateral welling and removal of oligomers. Void-size distribution could be estimated from the dye uptake with various sizes of disperse dyes. In contrast to the large increases in dye uptake with small dye molecules, there is no and little dye uptake with the bulkiest dye, which means that void size is bigger or smaller than the volume of each dye. Diffusion rates of dye molecules showed increases. This dyeing study revealed that the disperse dyeing is very effective method for characterizing the internal morphology of polyester fiber.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.60.2-60.2
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• 2010

A $TiO_2$ films in dye-sensitized solar cells was fabricated using $TiO_2$ colloidal sol prepared from titanium iso-propoxide used as a starting material by applying the sol-gel method. It was characterized by particle size analyzer, XRD, FE-SEM, and BET analysis. The adsorption isotherms of dye molecule on $TiO_2$ films were obtained at three different temperatures (30, 45, $60^{\circ}C$) and at three different pH (3, 5, 7). The adsorption kinetics of dye molecule on $TiO_2$ films were obtained at three different temperatures (30, 45, $60^{\circ}C$. The adsorption experimental data were correlated with Langmuir isotherm model and pseudo-second-order model. Also the isosteric enthalpies of dye adsorption were calculated by the Clausius-Clapeyron equation. In addition, the adsorption energy distribution functions which describe heterogeneous characteristics of nanocrystalline $TiO_2$ film surface were calculated by using the generalized nonlinear regularization method. We found that efficient adsorption of N719 dye from aqueous solution onto $TiO_2$ films can be successfully achieved by dye adsorption conditions and morphology of $TiO_2$ films.