• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.119.2-119.2
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• 2011

Dye-sensitized solar cells (DSSC) are currently attracting wide spread academic and commercial interest for the conversion of sunlight into electricity because of their easy manufacturing process and high efficiency. The solar energy conversion efficiencies of DSSC are strongly dependent on dye molecules adsorbed on the TiO2 surface which used for photosensitization of sun light, since an excited state of dye could inject an electron into the conduction band of semiconductor. We have developed novel organic dyes which have phenothiazine moieties as an electron donor in their charge-transfer chromophore for application of DSSCs. We had synthesized a series of phenothiazine derivatives which have different wave length absorbing chromophore in the molecule with high molar extinction coefficient. The photovoltaic performance of DSSC composed of organic chromophores with broad wavelength absorption property were measured and evaluated by comparison with that of pristine ruthenium dye.

• Proceedings of the KIEE Conference
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• 2008.05a
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• pp.165-166
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• 2008

We investigate characteristics of J-aggregation as take advantage of LB technic. In order to confirm the applications possible for the molecular electronic device, the morphological properties of merocyanine dye were investigated by AFM. $\pi$-A curves investigated the surface pressure of the LB film from a liquid to a solid state ranged between 90 and 100 mN/m. We observed aggregation and it's characteristics by using visible reflection spectroscopy. We have observed morphology of merocyanine dye on gold surface by STM. focuses on results obtained in mercocyanide dye of J-aggregation. When LB films of merocyanine dye are mixed with arachidic acid, J-aggregate formation is exhibited. J-aggregate formation has been serving as typical systems in revealing the physical and structural aspects of nano-sized molecular aggregates constructed as muiltilayers.

• Journal of the Korean Graphic Arts Communication Society
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• v.13 no.1
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• pp.73-91
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• 1995

Spectroscopic and Photoelectric Characteristics in the Cyanine and Merocyanine Dye according to systematically change of their structures were experimentally discussed. As result, in solution, Hetero atoms(X) of Cyanine and Merocyanine dye were participated in resonance X of d obital rather than X of pobital,effected in resonance and contributed in extension of conjugated system. in solid film,new spectra,called eximer-fluorenscence,were appeared in 3-dimensional fluorenscence of high density of Cyanine dye but not of Merocyanine. The activational energy of conductivity in Merocyanine dye was lower than in cyanine, an the contrary,the drift mobility was higher and the former in photoelectric characteristics was more effec-tive than the latter. In this paper,authors invertigated the changes of dye structure by molecular obital method to confirm the results of spectroscopic and photoelectric characteristics in the Cyanine and Merocyanine Dye acco-rding to systematically cally change of their structure, and counted total energy on dihedral angle and dipol miments if dyes in S0 and S1.

• Fibers and Polymers
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• v.5 no.1
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• pp.39-43
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• 2004

Effects of chemical structure of disperse dyes applied to conventional and microdenier polyesters on the dyeing property and washfastness were studied. It was found that washfastness of dyed polyester fabric is closely related to the degree of thermomigration of disperse dye during heatsetting. The bulky disperse dye, which was synthesized by substituting two acetoxy groups of C.I. Disperse Red 82 with two benzoxy groups, showed almost the same amount of absorbed dye by the microdenier polyester as C.I. Disperse Red 82, but the degree of thermomigration was low and subsequent washfastness was excellent. The high grade of washfastness of the bulky disperse dye might be caused by the increased dye-fiber interaction and the reduced mobility.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.157-161
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• 2013

Low priced and environment-friendly natural dye from coumarin- containing plants for the dye sensitized solar cell (DSSC) was developed. Dyes were extracted from cinnamon and angelica that contained coumarin derivatives, and DSSCs employing these dyes were prepared. PV efficiency of 0.75% was obtained from cinnamon dye, which is comparable to the highest efficiency reported in precedent studies about natural dye DSSC. It was confirmed by UV-visible and FT-IR spectroscopy that coumarin derivatives in the plants acted as photosensitive material.

• Fashion & Textile Research Journal
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• v.10 no.5
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• pp.779-783
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• 2008

The main colorant of Morus alba L. fruit is anthocyanin which is a kind of flavonoid group. In this article, the dyeing properties of colorant extracted from Morus alba L. fruit were investigated on some silk fabrics. The results were as follows: The maximum absorbance of Morus alba L. fruit showed at 284 nm, and 516 nm by UV-VIS spectrophotometer. The dye adsorption increased according as dye concentration. The optimal dyeing temperature was $60^{\circ}C$ and the dye equilibrium was reached 40 minutes after dyeing. The highest K/S value of the colorant obtained at bath ratio 40:1. The effect of pH of dye solution showed higher K/S value at acidic than alkaline condition. Almost Mordants except pre-Fe and Sn did not significantly increased dye adsorption. The pre mordanted silk fabrics showed RP, P, and post mordanted ones showed PB, GY. The color fastnesses to light, washing, and perspiration were modified at pre-Sn mordanted samples.

• Journal of Photoscience
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• v.7 no.1
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• pp.9-13
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• 2000

An alternately assembled polycation-anionic dye film was prepared on a precursor assembly of poly(allylamine)hydrochloride (PAH) and poly(sodium styrenesulfonate) (PSS) or of poly (djallyldimethyl)ammonium chloride (PDDA) and PSS. The (PAH/PSS) precursor assembly gave better adsorptivity to the anionic dye than the (PDDA/PSS) one. Four kinds of anionic dyes (EB-T, AR-17 AR-18, AR-27) with different numbers of sulfonate substituents were compared. The extent of dye assembling was higher for the dye with a smaller number of sufonate substituents. Second harmonic generation (SHG) was clearly observed from the films. The SHG signal and the absorption intensity correlated well up to four polycation/dye bilayers, while further assembly did not increase the SHG signal appreciably. Second order nonlinear coefficients for ten bilayer assemblies were the order of pm/V.

• Fashion & Textile Research Journal
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• v.3 no.2
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• pp.168-173
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• 2001

In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

• Journal of the Korean Applied Science and Technology
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• v.14 no.2
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• pp.57-64
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• 1997

The symmetric naphthothiazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, green-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 502nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

• Restorative Dentistry and Endodontics
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• v.8 no.1
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• pp.155-159
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• 1982

The author has studied comparatively the sealing quality of conventional Z.O.E. cement, chloropercha and FR cement by means of penetration of 2% methylene blue solution through the apex of human teeth in 112 cases as the time elapsed. The results were as follows; 1. All the specimen, of which dye immersion time is three days, showed dye penetration of low degree unrelated to the kinds of root canal cement and the degree of dye penetration was increased as the time elapsed. 2. Of all the experimental group, the Z.O.E. cement group showed the lowest degree of dye penetration and the FR filling group showed the highest degree of dye penetration. 3. The degree of dye penetration of FR cement group was higher than that of the Z.O.E. cement group but lower than that of the chloropercha group.