• The Korean Journal of Ceramics
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• v.2 no.1
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• pp.39-42
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• 1996

${\alpha}-SiC$ powder with or without the addition of 0.1 wt% of large ${\alpha}-SiC$ partices(seeds) was pressureless-sintered at $1950^{\circ}C$ for 0.5, 2, and 4 h using $Y_3Al_5 O_{12}$ (yttrium aluminum garnet, YAG) as a sintering aid. The materials without seeds had an equiaxed grain struture. In contrast, the materials with seeds sintered for 2 and 4 h had a duplex microstructure with large elongated grains and amall equiaxed grains. Addition of large ${\alpha}-SiC$ seeds into ${\alpha}-SiC$ accelerated the grain growth of some ${\alpha}-SiC$ grains during sintering and resulted in the increased fracture toughness of the sintered materials. The fracture toughnesses of materials with or without seeds sintered for 4 h were 6.6 and $5.2 MPa \;m^{12}$, respectively.

• Journal of Korea Foundry Society
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• v.27 no.3
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• pp.120-125
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• 2007

The microstructure, mechanical properties and melting range of Ni-Cr-Mo based alloys were investigated to develop Be-free Ni-Cr-Mo base dental alloys for Porcelain-Fused-to-Metal Firing(PFM). All as-cast alloys showed dendritic structure. Rockwell hardness of 20Cr7Mo was increased with addition of Si and Ti. On the contrary, it was decreased with addition of Co. The duplex alloying elemental addition such as 3Co + xTi, 2Si + xCo and 2Si + xTi to 20Cr7Mo resulted in much increase of hardness. Rockwell hardness and compressive strength for 20Cr3CoSiTi or 17Cr6CoSiTi alloy that add Si-Ti had similar values compared to the commercial alloys. Melting range for 20Cr3CoSiTi and 17Cr6CoSiTi alloy that add Si-Ti showed similar or lower than commercial alloys. In conclusion, 20Cr3CoSiTi and 17Cr6CoSiTi alloys can be applied for commercial use.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.466-474
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• 2021

A wet type scrubber for merchant vessel uses super austenitic stainless steels with pitting resistance equivalent number (PREN) of 40 or higher for operation in a harsh corrosive environment. However, it is expensive due to a high nickel content. Thus, electrochemical behavior and cavitation erosion characteristics of UNS S32750 as an alternative material were investigated. Microstructure analysis revealed fractions of ferritic and austenitic phases of 48% and 52%, respectively, confirming the existence of ferritic matrix and austenitic island. Potentiodynamic polarization test revealed damage at the interface of the two phases because of galvanic corrosion due to different chemical compositions of ferritic and austenitic phases. After a cavitation test, a compressive residual stress was formed on the material surface due to impact pressure of cavity. Surface hardness was improved by water cavitation peening effect. Hardness value was the highest at 30 ㎛ amplitude. Scanning electron microscopy revealed wave patterns due to plastic deformation caused by impact pressure of the cavity. The depth of surface damage increased with amplitude. Cavitation test revealed larger damage caused by erosion in the ferritic phase due to brittle fracture derived from different strain rate sensitivity index of FCC and BCC structures.

• Journal of Welding and Joining
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• v.32 no.2
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• pp.48-53
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• 2014

This study was carried out to investigate the effect of postweld heat treatment(PWHT, 930, 1080, $1230^{\circ}C$) on the microstructure, phase formation, pitting corrosion and mechanical properties such as hardness, tensile strength and impact values of super duplex stainless steel(UNS S32750) multipass welds. Based on the microstructural examination and X-ray diffraction analysis, it was found that the ${\sigma}$ phase was formed in the welds heat treated at $930^{\circ}C$ in which the ferrite content greatly decreased into 5~10% in the welds. The secondary austenite was formed in the reheated zone of welds and redissolved into ferrite with increasing heat treatment temperatures. The tensile strength and impact values of welds heat treated at $930^{\circ}C$ were the lowest and revealed the brittle fracture surface. The weight loss by pitting corrosion increased with test temperatures. It was confirmed that pitting corrosion occurred mainly in secondary austenite of reheated zones. The postweld heat treatment temperature is recommended to be in the range of $1050{\sim}1150^{\circ}C$.

• Journal of the Korean institute of surface engineering
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• v.54 no.3
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• pp.102-111
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• 2021

The corrosion behaviors of laser-welded super duplex stainless steel tubes with post-weld heat treatment(PWHT) conditions(950, 1000, 1050, 1100 ℃ for 5 and 30 min) were evaluated by electrochemical potentiodynamic polarization and critical pitting temperature measurements. This study showed that the critical metallurgical factors affecting the degradation of corrosion resistance of a steel tube in as-welded condition were the unbalanced phase fraction(ferrite:austenite = 94:4), Cr₂N precipitation, and phase transformation from the austenite phase to ɛ-martensite(via stress-induced phase transformation). The improvement in the corrosion resistance of the welded specimen depends greatly on the PWHT conditions. The specimens after PWHT conducted below 1000 ℃ showed inferior corrosion resistance, caused by precipitation of the sigma phase enriched with Cr and Mo. At 1100 ℃ for a longer duration in PWHT, the ferrite phase grows, and its fraction increases, leading to an unbalanced phase fraction in the microstructure. As a result, pitting can be initiated primarily at the interface between the ferrite/austenite phase, particularly in base metal.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.5
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• pp.55-63
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• 2018

Recently, the use of duplex stainless steel which with a two-phase microstructure (equal mixture of ferrite and austenite) has been increased in a variety of industrial fields due to higher strength leading to weight saving, greater corrosion resistance(particularly, stress corrosion cracking) and lower price. However, currently, stainless steels are not included in the structural materials of Korean Building Code and corresponding design standards are not specified. In this paper, experimental studies have been performed to investigate the structural behaviors of duplex stainless steel (STS329FLD) bolted connection with two bolts for providing the design data. Main variables are shear connection type (single shear and double shear) and end distance parallel to the direction of applied force. Fracture modes at the final step of test were classified into typical block shear fracture, tensile fracture and curling. Curling occurrence in single shear connection led to ultimate strength drop by up to 20%. Test strengths were compared with those by current design specifications such as AISC/AISI/KBC, EC3 and AIJ and proposed equations by existing studies. For specimens with no curling, Clement & Teh's equation considering the active shear plane provided a higher strength estimation accurancy and for specimens with curling, Kim & Lim's equation considering strength reduction by curling was also overly unconservative to predict the ultimate strength of curled connections.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.5 no.4
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• pp.343-350
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• 1995

A Abstract Systematic studies of the effects of crystalline forms of starting powders and p processing variables on the texture of hot - pressed silicon carbide are described. The results I indicate that hot - pressing of $\beta$ - SiC can produce strong textures and composite type duplex microstructure due to the ${\beta} {\rightarrow} {\alpha}$ phase transformation of SiC. The texture variations d during post - annealing have been observed. In the case of using a - SiC as starting pow¬d ders, the degree of preferred orientation by hot - pressing is relatively weak.

• Journal of the Korean Society for Heat Treatment
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• v.11 no.3
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• pp.192-199
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• 1998

This study was carried out to investigate the influence of variations in the temperature and time of isothermal heat treatment, applied stresses and prestrain on the isothermal transformation behavior of ${\gamma}$ and ${\sigma}$ phases and mechanical properties of 25Cr-7Ni-3Mo duplex stainless steel. The precipitation of ${\gamma}$ and ${\sigma}$ phases through isothermal heat treatment showed the type curves with a certain incubation period, the curve migrated to in a short period of time and the amount of precipitation increased with decreasing isothermal heat treatment temperature. Under the state of isothermal transformation, the precipitation of ${\gamma}$ and ${\sigma}$ phases was stimulated by applied stress, with increasing applied stress, the curves migrated to in a short period of time and also observed that the application of stress has a greater influence on the amount of ${\sigma}$ precipitation than that of ${\gamma}$ precipitation. The precipitation of ${\gamma}$ and ${\sigma}$ phases was stimulated by cold and warm rolling before isothermal heat treatment and precipitation of ${\gamma}$ and ${\sigma}$ phases has a greater influence on the warm rolling than cold rolling. The tensile strength and hardness increased with increasing cold and warm rooling reduction ratio.

• Journal of Korea Foundry Society
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• v.20 no.6
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• pp.377-385
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• 2000

Al matrix composites as the most promising MMCs can be expected to be excellent engineering materials in the nearest future. So as to improve material properties of composite, many manufacturing processes have been developed. Among them, squeeze casting process which offers fine microstructure and near-net-shape is one of the most successful MMCs manufacturing processes. But, in case of with subsieve size particles (under 44 ${\mu}m$), it is very difficult to homogeneously distribute particles in matrix of Al matrix composite by various casting processes, including squeeze casting used so far. Duplex process which was developed in previous study was used to distribute the particle of subsieve size more homogeneously in matrix of Al matrix composite. Microstructures, wear and heat resistance characterization of Al-Si-Cu-Mg-(Ni)/SiCp manufactured by duplex process were examined to clarify the effect of manufacturing conditions, particle size of reinforcement and alloying elements. Al matrix composites reinforced with SiCp(10 ${\mu}m$) have the lowest wear amount among composites reinforced with 3 ${\mu}m$, 5 ${\mu}m$ and 10 ${\mu}m$ SiCp. The wear amount of Al matrix composites with 10 wt.% SiCp(3, 5, 10 ${\mu}m$) was decreased according to the increase of the sliding speed because abrasive wear takes place at high sliding speed of 4m/s and worn debris with block type occurs at low sliding speed of 1m/s. As for heat resistance, it is made clear that remarkable heat resistance property can be obtained by addition of Ni element in Al matrix composites.

• Journal of the Korean institute of surface engineering
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• v.48 no.6
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• pp.329-334
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• 2015

The aim of this paper is to determine the proper heat treatment temperature for SDSS tube production without ${\sigma}$-phase precipitation. When Mother steel tube was heat treated at $800^{\circ}C$ temperature, relatively a large amount of ${\sigma}$-phase precipitated and grain refinement of ferrite phase occurred simultaneously. However, in Pilgered and Drawn steel tubes, grain refinement of the ferrite phase did not occur and a small amount of ${\sigma}$-phase precipitated. For all three types of steel tubes, the pitting potential was reduced to 2/5 or less compared with the untreated one and corrosion also occurred in the salt spray test due to the precipitation of ${\sigma}$-phase. When heat treatment temperature was $900^{\circ}C$, grain refinement of the ferrite phase occurred and very little ${\sigma}$-phase precipitated in Pilgered and Drawn steel tubes. But when heat treatment was done at $1,000^{\circ}C$ temperature, all three types of steel tubes had a similar corrosion properties of that of untreated one and also corrosion did not occur in the salt spray test, as ${\sigma}$-phase did not precipitate. Therefore, the optimum heat treatment temperature range is determined to be more than $1000^{\circ}C$ for the SDSS at which corrosion does not occur.