• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.460-467
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• 2006

Adsorption experiments for $H_2$, $CO_2$, CO, and their binary mixtures on zeolite 5A were performed by static volumetric method. Experimental data were obtained at temperatures of 293.15, 303.15 and 313.15 K and at pressures to 25 atm. The parameters obtained from single component adsorption isotherm. Multicomponent adsorption equilibria could be predicted and compared with experimental data. Langmuir isotherm, Langmuir-Freundlich isotherm and Dual-Site Langmuir isotherm be used to predict the experimental results for binary adsorption equilibria of $CO_2/CO$ and $H_2/CO_2$ on zeolite 5A. Dual-Site Langmuir isotherm showed the best agreement with the experimental results.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.175-183
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• 2008

Adsorption equilibria of the gases $CO_2$, CO, $CH_4$ and $H_2$ and their binary mixtures on Li-X zeolite (UOP) were obtained by static volumetric method in the pressure range of 0 to 20 bar at temperatures of 293.15, 303.15, and 313.15 K. Using the parameter obtained from single-component adsorption isotherm. Multicomponent adsorption equilibra could be predicted and compared with experimental data. Extended Langmuir isotherm, Extended Langmuir-Freundlich isotherm (L-F) and dual-site Langmuir isotherm (DSL) were used to predict the experimental results for binary adsorption equilibria of $H_2/CO_2$, $H_2/CO$, and $H_2/CH_4$ on Li-X Zeolite. Extended Langmuir-Freundlich isotherm predicted equilibria of $CH_4$ and $H_2$ better than any other isotherm. One the other hand DSL isotherm predicted equilibria of $CO_2$ and CO very well.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.2
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• pp.18-25
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• 2003

The adsorption of co-cationic dual polymer system was investigated as was the fiber dispersion stability of a paper stock suspension. Polyaluminum chloride(PAC) and polyamidoamine epichlorohy-drin(PAE) polymers were used as wet-end additives. The adsorbed amounts of PAE polymer in a wet stock were measured by using polyelectrolytic PCD titration. The sheet forming experiments were carried out in a standard handsheet machine. Fiber dispersion stability and relative retention were evaluated in terms of M/K non-uniformity index and sheet basis weight, respectively. The PAE polymer adsorption of Langmuir-isothermal type decreased with increasing PAC addition level. The combination of the two cationic polymers presumably exerts a site-blocking effect by the low molecular weight PAC which gives a partial charge neutralization at a minimum level of addition. From a thermodynamic view point of PAE adsorption, an increase in adsorption entropy and a decrease in train number suggests that the PAR polymer has an extended conformation structure that potentially leads to an enhancement of the fiber dispersion stability. This conclusion is supported by handsheet experiments that examined the PAC-PAE dual polymer effects on the sheet formation and retention.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.414-422
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• 2008

Adsorption experiments for $H_2$, $CH_4$, CO, $CO_2$ on activated carbon and zeolite 5A were performed by static volumetric method. A 4-bed pressure swing adsorption (PSA) process was to study separation of hydrogen from multi-component mixture gases ($H_2$ 72.2%, $CH_4$ 4.06%, CO 2.03%, $CO_2$ 21.6%). Dual-site langmuir (DSL) isotherm showed good or fair agreement with the experimental results. The optimum height of activated carbon layer was 55 cm with breakthrough results on the packing ratio of activated carbon to zeolite 5A. In PSA process, the effects of the process parameters such as total cycle time ($T_c$), ${\Delta}P$ at the provide purge step and adsorption pressure on the PSA performance were studied experimentally and theoretically.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.783-791
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• 2008

The dynamic characteristics of adsorption using an adsorption bed packed with Li-X zeolite (UOP) were studied through the breakthrough experiments of $H_2/CH_4$ (90:10 vol%), $H_2/CO$ (90:10 vol%) and $H_2/CO_2$ (80:20 vol%) mixtures. Effects of feed flow rate (6.24~10.24 LPM) and adsorption pressure (6.1 bar~10.1 bar) in the Li-X zeolite bed with 2.7 cm of inside diameter and 80 cm of bed length were observed. The smaller feed rate or the higher operating pressure, resulted in the longer of the breakthrough time and the breakthrough curve have tailing due to temperature variance in the bed. The adsorption dynamics of the Li-X zeolite bed were predicted by using LDF model with feed flow and pressure dependent diffusivity. The prediction and experimental data were analyzed with a nonisothermal, nonadiabatic model, dual-site langmuir (DSL) isotherm

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.339-339
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• 2006

In this study, the microvoids in glassy polymers were investigated by Xe sorption and $^{129}Xe$ NMR measurements. Xe sorption isotherms of glassy polymers have been successfully interpreted by the dual-mode sorption model. $^{129}Xe$ NMR chemical shift of the $^{129}Xe$ in the samples show nonlinear low-field shift with increasing sorption amount of Xe because of a fast exchange of Xe atoms between Henry and Langmuir sites, whereas it has showed linear shift against sorption amount of Xe into the Langmuir site. From this Xe-density dependence of the $^{129}Xe$ NMR chemical shift, it has been able to estimate mean size of the microvoids in glassy polymer. It is confirmed that there is correlation between ${C_H}'$ and volume or number of microvoids. From these findings, it is demonstrated that $^{129}Xe$ NMR spectroscopy is a powerful technique to determine the mean size and number of microvoids in glassy polymers.

• Transactions of the Korean hydrogen and new energy society
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• v.13 no.3
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• pp.214-223
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• 2002

Kinetic and effectiveness factors for methanol steam reforming using commercial copper-containing catalysts in a plug flow reactor were investigated over the temperature ranges of $180-250^{\circ}C$ at atmospheric pressure. The selectivity of $CO_2$/$H_2$ was almost 100%, and CO products were not observed under reaction conditions employed in this work. It was indicated that $CO_2$ was directly produced and CO was formed via the reverse water gas shift reaction after methanol steam reforming. The intrinsic kinetics for such reactions were well described by the Langmuir-Hinshelwood model based on the dual-site mechanism. The six parameters in this model, including the activation energy of 103kJ/mol, were estimated from diffusion-free data. The significant effect of internal diffusion was observed for temperature higher than $230^{\circ}C$ or particle sizes larger than 0.36mm. In the diflusion-limited case, this model combined with internal effectiveness factors was also found to be good agreement with experimental data.