• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.8
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• pp.1191-1199
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• 2003

This paper describes to observe the combustion process of only one droplet cluster. In this study, liquid fuel was atomized by ultrasonic wave to form an acoustically levitated droplet cluster. In order to elucidate the detailed structure of burning process of the droplet cluster, laser tomography method was applied. Time-series planar images of fuel droplets were processed and diameter of the each droplet was calculated based on the Mie-scattering theory. Using these data, the modified droplet group combustion number was estimated in time-series. As the result, when the internal droplet group combustion occur, the modified group combustion number dose not decrease monotonically, but show a tow-staged decreasing process. In all case of combustion process, combustion reactions were measured two types that combustion speed was fast and slow. It was casued by difference of concentration degree and droplet size distribution.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.6
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• pp.442-448
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• 2009

To evaluate the combustion mechanism of each droplet cluster downstream of the premixed spray flame, the simultaneous time-series measurements were conducted by using optical measurement system consisting of laser tomography, multi-color integrated Cassegrain receiving optics (MICRO) and phase Doppler anemometer (PDA). Furthermore, the group combustion number of droplet cluster was estimated experimentally, and the combustion mechanism of droplet cluster was examined applying the theoretical analysis. The group combustion number, $G_c$, was experimentally estimated about all droplet cluster verified by planar images, and it was classified into the internal group combustion mode and the external group combustion mode according to the theoretical analysis. It is found that there are cases in which the group combustion number estimated experimentally for droplet cluster agree or disagree with the classification by theoretical analysis. The reason of disagreement is considered due to that the group combustion number was only estimated by the geometrical arrangement of droplets in cluster, and that the actual phenomenon is three-dimensional but the measurement system is two-dimensional.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.6
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• pp.119-126
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• 2004

In order to elucidate the modes of double-droplet combustion speed in premixed spray flame, the difference between flame propagation speed and droplet cluster disappearance speed are experimentally investigated using a premixed spray burner system, It was confirmed that flame speed concerned with premixed-mode combustion in the spray flame was approximately 2.0 m/s in average while mean disappearance speed of droplet clusters, which were dominated by diffusion-mode combustion in downstream of the flame, was evaluated as much as 0.45 m/s. It was clarified that both characteristics of premixed-mode and diffusion-mode combustion in spray flames are of much difference in nature, even though both speed, which are supposed to depend on local properties of the spray itself and flow conditions surrounding droplet clusters, are scattered in experiments.

• Mass Spectrometry Letters
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• v.14 no.4
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• pp.147-152
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• 2023

The increasing demand for two-dimensional imaging analysis using optical or electronic microscopic techniques has led to an increase in the use of simple one-dimensional and two-dimensional mass spectrometry imaging. Among these imaging methods, secondary-ion mass spectrometry (SIMS) has the best spatial resolution using a primary ion beam with a relatively insignificant beam diameter. Until recently, SIMS, which uses high-energy primary ion beams, has not been used to analyze molecules. However, owing to the development of cluster ion beams, it has been actively used to analyze various organic molecules from the surface. Researchers and commercial SIMS companies are developing cluster ion beams to analyze biological samples, including amino acids, peptides, and proteins. In this study, a water droplet ion beam for surface analysis was realized. Water droplets ions were generated via electrospraying in a vacuum without desolvation. The generated ions were accelerated at an energy of 10 keV and collided with the target sample, and secondary ion mass spectra were obtained for the generated ions using ToF-SIMS. Thus, the proposed water droplet ion-beam device showed potential applicability as a primary ion beam in SIMS.

• Journal of Mechanical Science and Technology
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• v.18 no.8
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• pp.1271-1287
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• 2004

In this article, vapor bubble nucleation in liquid and the evaporation process of a liquid droplet at its superheat limit were discussed from the viewpoint of molecular clustering (molecular cluster model for bubble nucleation). For the vapor bubble formation, the energy barrier against bubble nucleation was estimated by the molecular interaction due to the London dispersion force. Bubble nucleation by quantum tunneling in liquid helium under negative pressure near the absolute zero temperature and bubble nucleation on cavity free micro heaters were also presented as the homogenous nucleation processes.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.571-571
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• 2012

We discovered the formation of C60 aggregates in solution by means of photoluminescence spectroscopic study on C60 in solutions. From the in-depth investigation of temperature dependence of the luminescence of C60 in toluene, benzene and CS2 solutions, we reported that the C60 aggregates are formed during cooling at the freezing temperature of these solvents. Furthermore, the C60 aggregates can be changed to stable structures by irradiating with UV pulse-laser (Nd:YAG laser, 355nm). As a consequence, we could obtain nano-scale photo-polymerized C60 clusters, which appear as round-shaped nano- scale particles in high resolution transmission electron-microscopy (HRTEM) images. However, the yield of the nano-scale C60 clusters obtained by this method is too small. So we designed and developed a system to obtain C60 cluster of macroscopic quantity by using ultrasonic nebulizer. In this system, C60 solution was vaporized to several micro-sized droplets in vacuum, resulting in the formation of C60 aggregates by evaporating solvent (toluene). The system was invented to produce nano-scale carbon clusters by the irradiation of UV light upon C60 aggregates in vacuum. We have characterized the products, C60 cluster, obtained from the system by using UV absorption spectra and HPLC spectra. Although the products have a possibility of inclusion various forms of C60 cluster, results support that the product formed from the system by using vaporizer method establishes a new method to obtain C60 cluster in macroscopic quantity. In the presentation, the details of the system and the results of characterization are reported.

• Macromolecular Research
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• v.16 no.2
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• pp.108-112
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• 2008

Matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) analysis of nonpolar polymeric materials is affected by the sample preparation as well as the matrix and cationizing agent. This study examined the influence of silver salt types on the MALDI analysis of polybutadiene (PB). Silver trifluoroacetate (AgTFA), silver benzoate (AgBz), silver nitrate ($AgNO_3$), and silver p-toluenesulfonate (AgTS) were used as the silver salts to compare the MALDI mass spectra of PB. The mixture solution of PB and 2,5-dihydroxybenzoic acid (DHB), as a matrix dissolved in THF, was spotted on the sample plate and dried. A droplet of the aqueous silver salt solution was placed onto the mixture. The mass spectrum with AgBz showed the clear $[M+Ag]^+$ ion distribution of PB while the mass spectrum with AgTFA did not show $[M+Ag]^+$ ions but only silver cluster ions. The mass spectra with $AgNO_3$ and AgTS did not show a clear $[M+Ag]^+$ ion distribution. The difference in the formation of $[M+Ag]^+$ ions of PB depending on the silver salts was attributed to the silver cation transfer reaction between the silver salt and the matrix (DHB). The mass spectrum showed a clear $[M+Ag]^+$ ion distribution of PB when the conjugate acid of the silver salt was less acidic than the matrix.