• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1165-1169
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• 2011

Second-order rate constants ($k_N$) have been measured spectrophotometrically for nucleophilic substitution reactions of 2,4-dinitrophenyl phenyl thionocarbonate 4 with a series of Z-substituted pyridines in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The Br${\o}$nsted-type plot for the reactions of 4 exhibits downward curvature (i.e., ${\beta}_1$ = 0.21 and ${\beta}_2$ = 1.04), indicating that the reactions proceed through a stepwise mechanism with a change in rate-determining step. It has been found that 4 is less reactive than its oxygen analogue, 2,4-dinitrophenyl phenyl carbonate 3, although the thionocarbonate is expected to be more electrophilic than its oxygen analogue. The $pK_a$ at the center of the Br${\o}$nsted curvature, defined as $pK_a^o$, has been analyzed to be 6.6 for the reactions of 4 and 8.5 for those of 3. Dissection of $k_N$ into the microscopic rate constants $k_1$ and $k_2/k_{-1}$ ratio has revealed that the reactions of 4 result in smaller $k_1$ values but larger $k_2/k_{-1}$ ratios than the corresponding reactions of 3. The larger $k_2/k_{-1}$ ratios have been concluded to be responsible for the smaller $pK_a^o$ found for the reactions of 4.

• Tunnel and Underground Space
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• v.28 no.2
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• pp.142-155
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• 2018

The ${\bigcirc}{\bigcirc}$ mine has irregularly developed stratum around the ore body. The purpose of this study is to array irregular stratum thickness systematically for effective roof bolting and to implement a supporting system corresponding to it. The number of 81 cases combined with stratum thicknesses was limited to 9 cases by robust design. For each case, the load height which can act as a roof load was determined by the characteristics of stratum and RMR. The load range due to the load height is calculated assuming block shaped and arch shape. The support load of the roof bolt was considered as the average load of the two methods. Numerical analysis results of the support design showed that the cable bolt was more effective for the roof supporting fully grouted than the anchoring type. As a result of the construction, it was possible to control the roof, but all of the roof was gradually sinking downward due to the deformation of the side wall of the mine tunnel.

• Earthquakes and Structures
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• v.8 no.5
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• pp.1215-1240
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• 2015

In this paper, the Theory of Plastic Mechanism Control (TPMC) is applied to the seismic design of dual systems composed by moment-resisting frames and Chevron braced frames. The application of TPMC is aimed at the design of dual systems able to guarantee, under seismic horizontal forces, the development of a collapse mechanism of global type. This design goal is of primary importance in seismic design of structures, because partial failure modes and soft-storey mechanisms have to be absolutely prevented due to the worsening of the energy dissipation capacity of structures and the resulting increase of the probability of failure during severe ground motions. With reference to the examined structural typology, diagonal and beam sections are assumed to be known quantities, because they are, respectively, designed to withstand the whole seismic actions and to withstand vertical loads and the net downward force resulting from the unbalanced axial forces acting in the diagonals. Conversely column sections are designed to assure the yielding of all the beam ends of moment-frames and the yielding and the buckling of tensile and compressed diagonals of the V-Braced part, respectively. In this work, a detailed designed example dealing with the application of TPMC to moment frame-chevron brace dual systems is provided with reference to an eight storey scheme and the design procedure is validated by means of non-linear static analyses aimed to check the actual pattern of yielding. The results of push-over analyses are compared with those obtained for the dual system designed according to Eurocode 8 provisions.

• The Journal of the Acoustical Society of Korea
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• v.34 no.6
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• pp.432-443
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• 2015

Coherence describing the similarity between physical quantities of two signals is a very useful tool to investigate the temporal and spatial characteristics of signals propagating in underwater acoustic waveguide. Ambient noise measurements were made by the vertical received array consisting of three hydrophones as part of the KIOST-HYU joint acoustics experiment, and the coherence for the underwater ambient noise was analyzed. In this paper, the coherence results in cases that the generator in the research vessel was off and turned on are presented. The coherence estimated in the case of the generator operation mode are compared to the predictions obtained using the theoretical model with the directional density function dominated by vertical components propagating downward from the ship. In the case of the generator switch-off, the results are compared to the model predictions with directional density function including the effects of sea surface noise and long-distance shipping noise.

• The Journal of Internal Korean Medicine
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• v.16 no.1
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• pp.40-61
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• 1995

This study was performed to investigate concept, systoms, causes of disease, pathogenic mechanisms, therapies and precriptions about senile constipation through the successive medical literature, recent chinese medical literature and chinese medical joumals. Senile constipation seems to be applicable to dryness syndrom and constipation of insufficiency type, have something to do with kidney(the most), lung, spleen and large intestine. The most principal cause of disease is yin-fluid, the rest deficiency of qi, insufficiency of yang, stagnation of qi and retention of fever etc. There are enriching the blood and moistening dryness in principal therapy, the rest are invigorating qi and loosing the bowel, warming and invigorating the spleen and kidney, regulating the flow of qi and promoting the stagnancy of qi and expelling the pathogenic heat etc. In prescriptions there are Yunjangtang, Jengaektang, Hwanggitang, Jechunjeon, Yukmatang and Majainhwan as the causes of disease, meanwhile are Yungjang-tang, Jechunjeon and Majainhwan in the vulgaris prescriptions. And in medical herbs there are nourishing yin medicines as Rhizoma rehmanniac, Radix ophiopogonis and Radix scrophulariae etc., invigorating qi medicines as Radix astragali, Radix codonopsitis and Radix polygoni multiflori etc, invigorating yang medicines as Caulis cistanchis and Semen psoraleae etc., promoting qi circulating medicines as Radix saussurea, Lignum aquilariae and Radix linderae etc., and reducing fever and therapeutic method to keep the adverse qi flowing downward medicines as Semen cannabis, Rhizoma rhei, Fructus immaturus ponciri, and Cortex magnoliae etc.. Meantime Rhizoma rehmanniae, Radix ophiopogonis, Caulis cistanchis, Radix angelicae gigantis, Semen cannabis, Semen biotae, Semen pruni japonicae and Semen persicae in principal herb-medicines. In clinical reports the process of disease was between 10 to 20 years, the evacuation cycle between 4 to 7 days, generally possessed chronic diseases as hypertension, diabetes, arteriosclerosis and cerebro- vascular disorders etc. and the efficiency rate was more than 90%. The senile constipation is occured in succession or promoted by chronic diseases as obesity, hypertension, diabetes, arteriosclerosis. hrperlipemia, cerebro- vascular disorders etc., so diet-regulating, adequate exercise, proper evacuation-habit and psychologic rest etc. are important more than medicine-treatments.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.29 no.4 s.235
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• pp.563-569
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• 2005

This paper develops a finite element model of a cabover type large truck. The finite element model is for evaluating torsional stiffness of the frame of the large truck. The torsional test of the frame is conducted in order to validate the developed finite element model. A load cell is used to measure the load applied to the frame. An angle sensor is used to measure the torsional angle. An actuator is used to apply a load to the frame. A vertical upward load and a vertical downward load are applied to the frame in the torsional test. The frame's torsional stiffness is computed with the measured load and torsional angle in the torsional test. The finite element model of the large truck includes cab, deck and payload, suspension, and tire. Cab, deck, and suspension are modeled not to affect the frame's torsional stiffness. The simulation is performed with the developed finite element model for evaluating the frame's torsional stiffness. The simulation results show a very good correlation with the torsional test results in the tendency of changing of the frame's torsional stiffness not only with the direction of the applying load but also with the amount of the applying load. In addition, the simulation results predict the measured torsional stiffness of the frame with about $5{\%}$ error.

• Journal of the korean society of oceanography
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• v.35 no.1
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• pp.16-33
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• 2000

In order to measure the vertical fluxes of particles and reactive radionuclides such as thorium and polonium isotopes, Dunbar-type sediment traps were freely deployed at the Ulleung Basin and in warm and cold water masses around the polar front of the East Sea. We estimated the ratios of the catched (F) to the predicted $^234$Th fluxes (P) using natural tracers pair $^234$Th-$^238$U. The F/P ratios are decreased with increasing water depth. Whereas the concentrations of suspended particles are homogeneous in water column, the mass fluxes are also decreased with increasing water depth like the F/P ratios. These facts indicate that organic matters of settling particles are destructed within the euphotic layer due to decomposition. Whereas regenerations of sinking particles are negligible in the cold water mass, about 80% of them are regenerated in the warm water mass during falling of large particles. These downward mass fluxes are closely correlated with their primary productions in euphotic zone. The activities of $^234$Th, $^228$Th and $^210$Po in the sinking material were increased with water depth. Because $^234$Th steadily produced in the water column are cumulatively adsorbed on the surface of sinking particles, vertical $^234$Th fluxes were observed to increase with water depth. Therefore, these sinking particles play important roles in transporting the particle reactive elements like thorium from surface to the deep sea. The scavenging processes including adsorption and settling reactions generate radio-disequilibrium between daughter and parent nuclides in water column. The activity ratios of $^234$Th/$^238$U and $^228$Th/$^228$Ra were observed to be < 1.0 in the surface water and approached to be equilibrium below the thermocline. The extent of the deficiency of daughter nuclides compared to the parents nuclide was highly correlated with the vertical particle flux. Because most of the $^210$Po in the surface water are scavenged on a labile phase and are recycled at sub-surface depths (< 200 m), the $^210$Po are always observed to be excess activities compared to $^226$Ra in surface water.

• Journal of the Korean Geotechnical Society
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• v.20 no.8
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• pp.135-145
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• 2004

In this study, the behavior of unpropped diaphragm walls on decomposed granite soil was investigated through centrifugal and numerical modelling. Centrifuge model tests were performed by changing the interval distance of surcharge. Excavation was simulated during the centrifuge tests by operating a solenoid valve that allowed the zinc chloride solution to drain from the excavation. In these tests, ground deformation, wall displacement and bending moment induced by excavation were measured. FLAC program which can be able to apply far most geotechnical problems was used in the numerical analysis. In numerical simulation, Mohr-Coulomb model fur the ground model, an elastic model for diaphragm wall were used for two dimensional plane strain condition. From the results of model tests, failure surface was straight line type, the ground of retained side inside failure line had downward displacement to the direction of the wall, and finally the failure was made by the rotation of the wall. The angle of failure line was about 67 ∼ 74$^{\circ}$, greater than calculated value. The locations of the maximum ground settlement obtained from model tests and analysis results are in good agreements. The displacement of wall and the change of the embedment depth is likely to have linear relationship.

• Asian-Australasian Journal of Animal Sciences
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• v.14 no.10
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• pp.1367-1373
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• 2001

This study used fowl sperm from three White Leghom rooster reared at our laboratory. Semen samples were exposed to the magnetic field strengths of from 650 to 5700 Gauss for one. two, or three days to investigate the influence of magnetic field on the orientation of fowl spermatozoa. Fowl spermatozoa were found to orient with their long axis of heads perpendicular to the magnetic field direction. The fowl spermatozoa were initially influenced when magnetic field intensities were from 650 to 5700 Gauss and the highest values (70.67, 72.49 and 71.79%) were found in the 5700 Gauss treatment at one, two, and three days exposure, respectively. Although percentages of the perpendicular oriented fowl spermatozoa increased along with the enhancement of the magnetic field intensity, the degree of orientation was only significantly higher in the treatments having the magnetic field strength from 1500 to 5700 Gauss than that in the control treatment at all exposure time. In addition, the experimental results also showed that the percentages of all orientational types of fowl spermatozoa (perpendicular category including upward perpendicular and downward perpendicular and parallel type consisting of leftward parallel and rightward parallel) in all treatments tended to be stable during exposure time. From the results of this study. it is suggested that (1) the diamagnetic anisotropy of the inside structural components of fowl spermatozoa induce them to orient perpendicular to the magnetic field direction, (2) the degree of orientation increased according to the enhancement of magnetic field strengths, (3) fowl spermatozoa had not an high sensitivity to the magnetic field, and the level of perpendicular orientation of fowl spermatozoa in this study is nearly similar to that of cattle sperm in the study of Suga et al. (2000).

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
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• v.40 no.5
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• pp.225-232
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• 2014

Objectives: The purpose of this retrospective study is to find the differentiating characteristics of cystic and cystic-appearing lesions that involve the impacted mandibular third molar by analyzing panoramic radiographs and computed tomography images, and to aid the preoperative diagnosis. Materials and Methods: Eighty-one patients who had a mandibular cystic or cystic-appearing lesion that involved impacted mandibular third molar and underwent cyst enucleation were included in the study. The preoperative panoramic radiograph and computed tomography findings were analyzed in accordance to the histopathologic type. Results: Most of the cystic lesions containing the mandibular third molar were diagnosed as a dentigerous cyst (77.8%). The occurrence of mesio-distal displacement of the third molar was more frequent in the odontogenic keratocyst (71.4%) and in the ameloblastoma (85.7%) than in the dentigerous cyst (19.1%). Downward displacement was primarily observed in each group. Odontogenic keratocyst and ameloblastoma showed more aggressive growth pattern with higher rate of bony discontinuity and cortical bone expansion than in dentigerous cyst. Conclusion: When evaluating mandibular cystic lesions involving the impacted mandibular third molar, dentigerous cyst should first be suspected. However, when the third molar displacement and cortical bone absorption are observed, then odontogenic keratocyst or ameloblastoma should be considered.