• Title/Summary/Keyword: Distribution of particles

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Physical, Morphological, and Chemical Analysis of Fly Ash Generated from the Coal Fired Power Plant (석탄 화력발전소에서 발생되는 석탄회 특성과 형성 분석에 관한 연구)

  • 이정언;이재근
    • Journal of Energy Engineering
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    • v.7 no.1
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    • pp.146-156
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    • 1998
  • Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A physical, morphological, and chemical characteristic of fly ash has been analyzed. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, ash recycling and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution and gravimeter. Morphological characteristic of fly ash is performed using a scanning electron micrograph and an optical microscope. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry (ICP). The distribution of fly ash size was ranged from 15 to 25 $\mu$m in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, relative opacity, coloration, cenosphere and plerosphere. The spherical fly ash might be generated at the condition of complete combustion. The size of fly ash was found to be increased the with particle-particle interaction of agglomeration and coagulation. Fly ash consisted of $SiO_2\;Al_2O_3\;and\;Fe_2O_3$ with 85% and carbon with 3~10% of total mass.

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Synthesis of Resole-type Phenolic Beads via Suspension Polymerization Technique (현탁중합을 이용한 레졸형 구형 페놀입자의 합성)

  • Hahn, Dongseok;Kim, Daejung;Kim, Hongkyeong
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.279-284
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    • 2013
  • The phenolic beads in macrosize range were obtained by suspension polymerization at $98^{\circ}C$ from phenol and formaldehyde in the presence of basic catalyst with a phenol to formaldehyde (P/F) range of 1:1~1:4, and they were carbonized to spherical carbon beads under nitrogen at $700^{\circ}C$. Thermal analysis on spherical phenolic beads obtained by suspension polymerization showed that the postcuring process is essential. In order to optimize the suspension polymerization, the effects of the P/F molar ratio, the pH of catalyst, and the molecular weight of stabilizer on the size distribution and yield of spherical phenol beads were examined separatively. The particle size was increased whereas the yield was decreased with P/F molar ratio. The increasing basicity of catalyst made the particle size to increase, while the molecular weight of stabilizer had more effect on the yield rather than on the particle size distribution. The thermal stability of the spherical phenolic beads obtained through postcure was also examined by TGA. The phenol beads of high P/F ratio still showed the weight loss at $220^{\circ}C$ even after postcure due to the high possibility of dibenzyl ether, while those of low P/F ratio showed the steady decrease in weight during $220^{\circ}C$ to $400^{\circ}C$, which showed that the optimal P/F ratio was 1:2.

The Dispersion Capacity of Some Chemical Dispersing Agents in Korean Soils (우리나라 토양(土壤)에 있어서 수종(數種) 분산제(分散劑)의 분산능(分散能)에 관(關)하여)

  • Im, Jeong-Nan;Cho, In-Sang;Cho, Seong-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.13 no.2
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    • pp.65-70
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    • 1980
  • This experiment was aimed at selecting the most suitable dispersing agent to the Korean soils. The particle size distribution of 18 soil samples representing the great soil groups in Korea was analysed with 5 different dispersing agents by pipette-method. Passing percent of 0.05, 0.02 and 0.002mm in diameter was used for the comparision of the dispersion capacity of chemical agents. The results obtained are as follows; 1. The influence of chemical agents on dispersion seemed to be greater to finer soil particles. The passing percents of 0.002mm showed a great differences according to the chemical agents used, while little differences was observed in those of 0.05mm. 2. It was showed that sodium pyrophosphate had the highest dispersion capacity for the most of Korean soils, the dispersion capacity of sodium hexametaphosphate was also high enough except for volcanic ash soils. 3. It was recommendable that sodium hexametaphosphate could widely be used as a dispersing agent in the routine analysis of soil particle size distribution except for the Volcanic ash soils. 4. The dispersion of Volcanic ash soils was rather poor when chemical agents used. Therefore, special care should be taken for the dispersion of allophane soils.

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Health and Environmental Risk Assessment of Pollutants in Pohang (포항지역 오염물질 보건.환경 위해성 평가 -미세먼지의 발생특성 및 농도분포를 중심으로-)

  • Jung, Jong-Hyeon;Choi, Won-Joon;Leem, Heon-Ho;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.7
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    • pp.2719-2726
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    • 2010
  • The purpose of this study was to investigate the scientific basic grounds for the assessment of health and environmental diseases resulting from air pollutants in Pohang. For this study, we investigated pollutants, weather characteristics and concentration distribution of fine particles ($PM_10$) yearly and each season, using data from Air Quality Monitoring Stations. The properties of concentration distribution and seasonal fluctuation of $PM_10$ were studied qualitatively and quantitatively using CALPUFF, air dispersion model. The average concentration of $PM_10$ for each season was spring($75.7{\mu}g/m^3$)>summer($56.8{\mu}g/m^3$)>winter($53.6{\mu}g/m^3$)>fall( $52.7{\mu}g/m^3$). In the case of spring, high concentrations appear due to the Asian dust frequently occurring. The contributions of $PM_10$ classified by the types of pollution source in Pohang were point source 62%>mobile source 33%>area source 5%. An important point is that 97% of emissions were produced from the iron manufacture in steel industry. Therefore, it is necessary to control the emission sources of pollutants and to construct an observation system at Pohang steel industrial complex from now on. It’s time to control the risk factors for health and environmental disease to protect the health of resident in Pohang and its neighboring areas.

Printability of coating layer with nano silica sol for inkjet printing high-end photo paper (나노 실리카 졸을 이용한 잉크젯 프린팅용 고품질 인쇄용지 도공층의 인쇄적성)

  • Kim, Hye-Jin;Nahm, Sahn;Han, Kyu-Sung;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.352-358
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    • 2019
  • In recent years, printing paper with a function of information delivery and aesthetic value has attracted a great attention with increasing market demand for coated paper that is capable of high quality printing. The coated paper for inkjet printing with high-quality of photorealistic grades requires the coating layer with a good wettability and porous surface structure in order to improve the printability of ink. In this study, the coated paper was prepared using polyvinyl alcohol (PVA) and surface treated nano silica sol with silane coupling agent. It was confirmed that the coating layer with surface treated nano silica sol showed a uniform pore distribution and flat surface roughness. Glossiness of the prepared printing paper was similar to that of commercial high quality photo paper. Especially, the coated paper with surface treated nano silica sol showed improved printability with excellent roundness of the printed dot of ink. These results indicates that the coating layer with excellent wettability and uniform pore distribution can be formed by using the nano-silica particles with improved dispersibility through the surface treatment of the silane coupling agent.

Simulation of Plume Length Induced by Orimulsion Combustion (오리멀젼 연소시 발생하는 백연의 연기거리 전산모사)

  • Kwak, Byoung-Kyu;Kim, Jong-Ho;Joo, Ji-Bong;Lee, Jeong-Jin;Kim, Jin-Soo;Kim, Young-Hun;Yi, Jong-Heop
    • Clean Technology
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    • v.14 no.2
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    • pp.136-143
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    • 2008
  • The objective of this study is to investigate the visibility of plume at the Y power plant stack, which fires the orimulsion as a fuel. The plume contains numerous primary particles under $1\;{\mu}m$ size and inorganic ions possibly inferred by the chemicals of secondary aerosol formation. We evaluated the visibility of the plume using the modified PLUVUE-II model. The monitoring data on the particle size distribution (PSD) and secondary aerosols of sulfate were applied to estimate and evaluate the main factors of plume opacity. The chemical reactions were applied to the model for the secondary aerosol formation of $(NH_4)_2SO_4(s)$. The maximum plume length was estimated by an optic method using threshold contrast. The results showed that the plume length was strongly dependent upon the PSD and $(NH_4)_2SO_4(s)$ concentration of the plume emitted from the stack.

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Argo Project: On the Distribution Prediction of Drifting Argo Floats (Argo프로젝트: Argo플로트 분포 예측)

  • Yang Chan-Su;Ishida Akio
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.1
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    • pp.22-29
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    • 2004
  • An international project, known as Argo, for collecting data on temperature, salinity and velocity of currents in the world's oceans, has been started in the year 2000 and the full Argo array of approximately 3000 floats will be deployed by 2006. 18 countries deployed 1,023 floats, which are operating in the ocean of the world as of December 2003. In the present study, we tried to predict float distribution and a rate of drifting ashore of the floats after their termination based upon a product of the ocean general circulation model of JAMSTEC (Japan Marine Science and Technology Center). We first evaluated reliability of the model prodilct quantitatively by comparing trajectories of surface buoys of WOCE Surface Velocity Program (SVP) and those predicted by the model surface current field. It is found that the model is acceptable for practical application to deploy floats and to estimate those trajectories. 653 particles at 3-degree spacing are used to investigate the ratio of floats drifted ashore, given that during the first 4 years floats cycle between the surface and 2000m for 10 days and then floats are on just the surface for 100 years. The simulation indicates that about 29% of deployed floats will be drifted ashore within 100-year.

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A Study on the Distribution of Underground Plant Biomass and its Effect on the Stream Bank Stability (농촌 소 하천 제방 상의 식물 근계 분포 현황에 따른 제방 지지 역할에 관한 연구 - 경남 진주시 농촌 소하천 유역의 대나무와 잔디를 대상으로 -)

  • Lee, Chun-Seok;Kim, Jung-Uk
    • Journal of Korean Society of Rural Planning
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    • v.5 no.1 s.9
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    • pp.95-103
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    • 1999
  • The purpose of this study is to find out the distribution of underground biomass and its soil stabilizing effects. Bamboo and grass were examined and compared. 1. Thirty 'soil & root' samples were collected to the depth of 30cm with Impact-corer, and then divided into three sections(0-10cm, 10-20cm, 20-30cm). Each piece had a volume of $950cm^3$ and the underground biomass was separated from the soil particles by washing with flowing water. The average underground biomass rates of bamboo and grass were 10.8% and 4% of each sample, respectively. The rate of grass root biomass declined with depth, but the bamboo root biomass was at peak at around 20cm depth. 2. The shear strength was measured with con-penetration tester at each sample collecting site. Three measurements were made at each depth(0-10cm, 10-20cm, 20-30cm) and were compared with the impact counts needed to insert the corer to the depth of 30cm. The shear strength has clear correlations with underground biomass. The more underground biomass, the higher shear strength. The shear strength of bamboo was about three times larger than the grass.

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Fine Structural Characterization and Localization of Lectin Receptors in the Cultured Fibroblast (배양 섬유 세포에 있어서 세포 표면의 미세구조적 특성과 당단백 (lectin WGA 수용체)의 분포)

  • Kim, Soo-Jin;Hahm, So-Young
    • Applied Microscopy
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    • v.31 no.1
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    • pp.49-57
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    • 2001
  • In this study, the distribution of lectin receptors in culutured fibroblast was explored using colloidal gold label complexed with lectin WGA purified from wheat germ (Triticum vulgare). The lectin WGA gold complex, shown to recognize GlcNAc (N-acetylgalactosamine) and NeuNAc (N-acetylneuraminic acid) regions, was applied to detect binding sites in Lowicryl HM 20 sections viewed under electron microscope Labeled sections of the culutured fibroblast revealed gold particles specifically distributed on the cytoplasm and cell surface of the fibroblast. Labeling of 24 hours culutured fibroblast was then quantified and compared to that of 72 hours culutured fibroblast. 24 hours culutured fibroblast sections resulted in specific gold particle distribution on the cytoplasmic vesicle of the culutured fibroblast. These results indicate that lectin WGA receptors are located in the cytoplasmic vesicle and cell surface of the 24 hours culutured fibroblast, and on the cell surface of the 72 hours culutured fibroblast. Therefore, the GlcNAc and NeuNAc regions on the cell surface appear to be functionally associated with cell-recognition and protection from other cell of the tissue, and linked with secretion and exocytosis of the fibroblast cytoplasm.

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Distribution of the Quantum Dot Nano-particles that Penetrate Skin and Distinction of Combined Osmium Tetroxide in Electron Microscopic Analysis (피부로 침투된 양자점 나노입자의 분포와 전자현미경 분석 시 발견되는 오스뮴산 결합물과의 구분)

  • Choi, Ki-Ju;Park, Sang-Yong;Lee, Jeong-Min;Shin, Heon-Sub;Yang, Jung-Eun;Lee, Don-Gil;Mavonov, Garfurjon T.;Yi, Tae-Hoo
    • Applied Microscopy
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    • v.42 no.1
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    • pp.1-7
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    • 2012
  • The possibility of nanoparticles (NPs) in biotechnology had been discussed by biomedical investigators. Here we report to suggest a solution and problems when using electron microscopy to determine the distribution of quantum dots (QDs) nanoparticles that penetrate skin. The results of this study showed that NPs were able to penetrate stratum corneum (SC) and sebocyte via hair follicle. However, we have found artifacts such as nanoparticles that are produced from combination of free fatty acid and osmium tetroxide during specimen preparation. It is usually difficult to identify NPs. Therefore, we tried to resolve these problems by comparing the cross-correlation image pattern that are derived from the images of sample that had been processed differently. This method can contribute to more accurate interpretation and minimal errors during the analysis using quantum dot as tracer.