• 제목/요약/키워드: Distillation technique

검색결과 46건 처리시간 0.024초

5[kW]급 풀-브릿지 고주파 공진형 인버터를 이용한 고효율 유도가열 히터 개발 (Development a High-Efficiency Induction Heating Heater using a 5[kW] Class Full-Bridge High Frequency Resonant Inverter)

  • 권혁민;신대철
    • 전력전자학회논문지
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    • 제10권5호
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    • pp.481-487
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    • 2005
  • 제안한 유도가열 시스템은 증류탑 장치에 사용되는 특수충진체에 의한 열교환기술과 IH(Induction-Heating)전자유도가열용의 특수한 고주파 전력회로 기술을 응용한 차세대 가열방식이다. 특히 일체의 연소과정이 없다는 점에서 작업환경의 개선이 가능하며 본 기술은 IGBT대응의 고주파 인버터를 사용하여 상용교류로부터 수[kHz]의 고주파 교류를 발생시킬 수 있다. 본 논문에서는 절연체 용기 내에 특수 스텐레스 발열체부하를 수납하여 용기 외부의 고주파 공진형 인버터 접속의 워킹코일로부터 비접촉 상태로 전자유도 와전류를 구조체에 흘림으로서 발열하게 되는 새로운 유체가열방식을 제안한다. 그리고 5[kW]급 풀-브릿지 공진형 인버터 시스템과 공진부하의 동작해석, 특성분석 및 본 시스템을 이용한 고효율 스팀 발생장치의 개발과 시스템의 응용에 대해 논하였다.

공진형 인버터를 이용한 2단 유도가열 시스템의 주파수제어에 관한 연구 (A Study on the Frequency Control on the Induction Heating System Using Two Step Resonant Inverter)

  • 유재훈;신대철
    • 조명전기설비학회논문지
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    • 제22권1호
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    • pp.95-103
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    • 2008
  • 제안한 유도가열 시스템은 증류탑 장치에 사용되는 특수충진체에 의한 열교환기술과 IH(Induction-Heating) 전자유도가열용의 특수한 고주파 전력회로 기술을 응용한 차세대 가열방식이다. 특히 일체의 연소과정이 없다는 점에서 작업환경의 개선이 가능하며 본 기술은 IGBT대응의 고주파 인버터를 사용하여 상용교류로부터 수[kHz]의 고주파교류(HFAC)를 발생시킬 수 있다. 본 논문에서는 1.5[kW]급 하프-브릿지 공진형 인버터 시스템과 공진부하의 동작해석, 특성분석 및 본 시스템을 이용한 2단 가열 과열증기 발생장치의 개발과 시스템의 응용에 대해 논하였다.

Determination of Methylmercury in Biological Samples Using Dithizone Extraction Method Followed by Purge & Trap GC-MS

  • Lee, Jung-Sub;Ryu, Yoon-Jung;Park, Jae-Sung;Jeon, Sung-Hwan;Kim, Sam-Cwan;Kim, Young-Hee
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2293-2298
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    • 2007
  • In this study, a dithizone extraction technique involving purge & trap GC-MS was developed for the determination of methylmercury in biological samples, especially blood and fish. After alkaline digestion, methylmercury in biological samples was extracted into dithizone and back-extracted into aqueous sulfide solution. The extracted methylmercury was converted to the volatile ethyl derivative, purged and trapped onto a solid-phase collection medium, and then introduced into the GC-MS system. The determined MDLs of the established method were 0.9 ng·g?1 for biological samples and its accuracy and precision were found to be 93% and 3.8%, respectively. The method was validated by analysis of CRMs such as SRM 966, BCR 463 and IAEA 407 and all analytical results were within certified ranges with average RSDs of less than 6%. The analytical results of field-sampled fish also showed that the method can be successfully used as an alternative for commonly used distillation method followed by GC-CVAFS detection.

ZIF-11을 이용한 수소 동위원소 분리 (Hydrogen Isotope Separation by using Zeolitic lmidazolate Frameworks (ZIF-11))

  • 이슬지;오현철
    • 한국재료학회지
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    • 제30권12호
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    • pp.655-659
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    • 2020
  • Hydrogen isotopes (i.e. deuterium and tritium) are supplied to the tokamak in the International Thermonuclear Experimental Reactor (ITER) fuel cycle. One important part of the ITER fuel cycle is the recycling of unused fuel back to the tokamak, as almost 99 % of fuel is unburned during fusion reaction. For this, cryogenic distillation has been used in the isotope separation system (ISS) of ITER, but this technique tends to be energy-intensive and to have low selectivity (typically below 1.5 at 24 K). Recently, efficient isotope separation by porous materials has been reported in the so-called quantum sieving process. Hence, in this study, hydrogen isotope adsorption behavior is studied using chemically stable ZIF-11. At low temperature (40 K ~ 70 K), the adsorption increases and the sorption hysteresis becomes stronger as the temperature increases to 70K. Molar ratio of deuterium to hydrogen based on the isotherms shows the highest (max. 14) ratio at 50 K, confirming the possibility of use as a potential isotope separation material.

얼굴 영상 기반의 심박수 추정을 위한 딥러닝 모델의 경량화 기법 (Lightweight Deep Learning Model for Heart Rate Estimation from Facial Videos)

  • 황규태;박명근;이상준
    • 대한임베디드공학회논문지
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    • 제18권2호
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    • pp.51-58
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    • 2023
  • This paper proposes a deep learning method for estimating the heart rate from facial videos. Our proposed method estimates remote photoplethysmography (rPPG) signals to predict the heart rate. Although there have been proposed several methods for estimating rPPG signals, most previous methods can not be utilized in low-power single board computers due to their computational complexity. To address this problem, we construct a lightweight student model and employ a knowledge distillation technique to reduce the performance degradation of a deeper network model. The teacher model consists of 795k parameters, whereas the student model only contains 24k parameters, and therefore, the inference time was reduced with the factor of 10. By distilling the knowledge of the intermediate feature maps of the teacher model, we improved the accuracy of the student model for estimating the heart rate. Experiments were conducted on the UBFC-rPPG dataset to demonstrate the effectiveness of the proposed method. Moreover, we collected our own dataset to verify the accuracy and processing time of the proposed method on a real-world dataset. Experimental results on a NVIDIA Jetson Nano board demonstrate that our proposed method can infer the heart rate in real time with the mean absolute error of 2.5183 bpm.

Mie 산란광법 및 Shadowgraph법을 이용한 다성분 혼합연료의 증발특성연구 (A Study on Evaporative Characteristics of Multi-component Mixed Fuels Using Mie Scattered Light and Shadowgraph Images)

  • 윤준규;명광재;차경옥
    • 대한기계학회논문집B
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    • 제30권7호
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    • pp.682-691
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    • 2006
  • This study was conducted to assess the effect of mixed fuel composition and mass fraction on spray inner structure in evaporating transient spray under the various ambient conditions. Spray structure and spatial distribution of liquid phase concentration are investigated using a thin laser sheet illumination technique on the multi-component mixed fuels. A pulsed Ar+ laser was used as a light source. The experiments were conducted in a constant volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector. Used fuel contain $i-octane(C_8H_{18}),\;n-dodecane(C_{12}H_{26})$ and $n-hexadecane(C_{16}H_{34})$ that are selected as low-, middle- and high-boiling point fuel, respectively. Experimental conditions are 25Mpa, 42MPa, 72MPa and 112MPa in injection pressure, $5kg/m^3,\;15kg/m^3\;and\;20kg/m^3$ in ambient gas density, 400K, 500K, 600K and 700K in ambient gas temperature, 300K and 368K in fuel temperature, and different fuel mass fraction. Experimental results indicate that the more high-boiling point component, the longer the liquid phase it were closely related to fuel physical properties, but injection pressure had no effect on. And there was a high correlation between the liquid phase length and boiling temperature at 75% distillation point.

Solid Phase Microextraction을 이용한 계피의 향기성분 분석 (Analysis of Aroma Compounds of Cinnamon by Solid Phase Microextraction)

  • 이창국;이재곤;장희진;곽재진
    • 한국식품영양학회지
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    • 제16권4호
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    • pp.372-378
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    • 2003
  • SDE 및 SPME를 이용하여 계피로부터 추출한 휘발성 향기성분을 GC/MSD 분석한 결과 terpenes 20종, alcohol 3종, carbonyl 5종, esters 2종으로 총 30개의 휘발성 성분을 확인하였다. 이들 중 trans-cinnamaldehyde (86.4%), cis-cinnamaldehyde(0.9%), hydrocinnamaldehyde (0.1%) 등의 carbonyl 화합물이 peak area% 기준으로 약 88.2%로 계피 중 대부분을 차지하는 것으로 나타났다. 또한 식물체의 향기성분 분석에 많이 이용되는 SPME fiber 4종류를 비교 분석한 결과 terpen류 화합물들은 PDMS fiber에서 추출효율이 가장 좋았으며, cinnamyl alcohol과 같은 다소 극성인 화합물의 경우 DVB/CAR/PDMS fiber와 PA fiber에서 추출 효율이 가장 좋은 것으로 나타났다. SPME법에서 최적 조건을 설정하기 위해 추출온도와 추출시간을 달리하면서 비교 분석한 결과 copaene, murolene, cadinene, cis-cinnamaldehyde 등의 area% 값은 온도와 시간이 커질수록 증가한 반면에 trans-cinnamaldehyde의 area% 값은 감소하였다.

Volatile Flavor Compounds in the Leaves of Fifteen Taxa of Korean Native Chrysanthemum Species

  • Kim, Su Jeong;Ha, Tae Joung;Kim, Jongyun;Nam, Jung Hwan;Yoo, Dong Lim;Suh, Jong Taek;Kim, Ki Sun
    • 원예과학기술지
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    • 제32권4호
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    • pp.558-570
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    • 2014
  • This study was conducted to compare the volatile flavor compounds found in the leaves of 15 taxa of Korean native Chrysanthemum species. The volatile flavor compounds from the taxa were collected using a simultaneous steam distillation and extraction technique and were analyzed using gas chromatography/mass selective detector (GC/MSD). A total of 45 volatile flavor compounds were identified with six functional groups: 14 alcohols, 4 ketones, 19 hydrocarbons, 5 esters, 2 acids, and 1 aldehyde. The main functional group in 15 taxa of Chrysanthemum species was alcohols, accounting for 28.7% of volatile flavor compounds, followed by ketones (21.2%) and hydrocarbons (13.2%). Camphor, which is known for its antimicrobial properties, was the most abundant volatile compound (30%) in C. zawadskii ssp. latilobum and var. leiophyllum. In particular, C. indicum subspecies and C. boreale contained ${\alpha}$-thujone, which has outstanding anti-bacterial, anti-cancer, anti-inflammatory, anti-ulcer, and anti-diabetic efficacies. C. indicum var. albescens could be used in perfumes, since it showed 21 times more camphene than C. indicum. In addition, C. indicum var. acuta contained a fairly high content of 1,8-cineole, which has an inhibitory effect on mutagenesis. C. lineare contained only pentadecanoic acid compounds, whereas other taxa hexadecanoic acids. Overall, the Korean native Chrysanthemum species had considerable variation in volatile flavor compounds in their leaves. This study provides a good indication of specific potential use for various applications.

영양진단을 위한 신속한 엽분석 방법으로서 근적외분광분석기의 이용 (Application of Near Infrared Reflectance Spectroscopy as a Rapid Leaf Analysis Method to Evaluate Nutritional Diagnosis in Apple (Malus Domestica Borkh, Fuji) and grape(Vitis Labrusca, Campbell Early))

  • 서영진;박만;김창배;;윤재탁;조래광
    • 한국토양비료학회지
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    • 제33권4호
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    • pp.242-246
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    • 2000
  • 근적외 분광분석기를 이용하여 과수의 영양진단을 위한 신속한 엽분석 수단으로 활용하고자 본 시험을 수행하였다. 사과 '후지'품종 잎 177점, 포도 '캠벨얼리' 품종 잎130점의 시료를 이용하여 1,100~2.500nm까지 근적외영역의 흡수스펙트럼을 측정하였다. 총질소 분석은 살리실산-황산으로 분해후 켈달 증류하여 측정하였다. 근적외 스펙트럼과 총 질소함량과의 상관분석을 이용, 검량식을 개발하였고 화학분석한 결과에 대한 예측식을 구하였다. 사과는 중회귀계수 0.965, 검량식의 표준오차 0.086, 포도는 중회귀계수 0.926, 검량식의 표준오차 0.152이었다. 개발된 검량식을 이용하여 예측식을 작성한 결과는 사과의 경우 0.360, 포도 0.210의 결과를 얻었다. 지역간, 년차간 발생되는 변이가 보정된다면 신속한 엽분석 수단이 될 것으로 판단된다.

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HORIZON EXPANSION OF THERMAL-HYDRAULIC ACTIVITIES INTO HTGR SAFETY ANALYSIS INCLUDING GAS-TURBINE CYCLE AND HYDROGEN PLANT

  • No, Hee-Cheon;Yoon, Ho-Joon;Kim, Seung-Jun;Lee, Byeng-Jin;Kim, Ji-Hwang;Kim, Hyeun-Min;Lim, Hong-Sik
    • Nuclear Engineering and Technology
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    • 제41권7호
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    • pp.875-884
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    • 2009
  • We present three nuclear/hydrogen-related R&D activities being performed at KAIST: air-ingressed LOCA analysis code development, gas turbine analysis tool development, and hydrogen-production system analysis model development. The ICE numerical technique widely used for the safety analysis of water-reactors is successfully implemented into GAMMA, with which we solve the basic equations for continuity, momentum conservation, energy conservation of the gas mixture, and mass conservation of 6 species (He, N2, O2, CO, CO2, and H2O). GAMMA has been extensively validated using data from 14 test facilities. We developed a tool to predict the characteristics of HTGR helium turbines based on the throughflow calculation with a Newton-Raphson method that overcomes the weakness of the conventional method based on the successive iteration scheme. It is found that the current method reaches stable and quick convergence even under the off-normal condition with the same degree of accuracy. The dynamic equations for the distillation column of HI process are described with 4 material components involved in the HI process: H2O, HI, I2, H2. For the HI process we improved the Neumann model based on the NRTL (Non-Random Two-Liquid) model. The improved Neumann model predicted a total pressure with 8.6% maximum relative deviation from the data and 2.5% mean relative deviation, and liquid-liquid-separation with 9.52% maximum relative deviation from the data.