• Title/Summary/Keyword: Dissolution condition

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Analysis of Electrocoagulation Process using Faraday's Law (Faraday's Law에 의한 전기응집공정의 분석)

  • Kim, Hye-Sook;Yun, Young-Im;Cho, Eun-Jeong;Choi, Yun-Hee;Oh, Mi-Young;Kim, Yeong-Kwan
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.351-355
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    • 2001
  • This research was carried out to find out the possibility of using Faraday's law in analyzing the electrocoagulation system. Bench-scale reactor equipped with aluminum electrode plates was operated using synthetic wastewater which received sodium chloride for conductivity adjustment. Phosphate was added to the wastewater to induce the precipitation with Al. The amount of aluminum dissolved from the electrodes could be predicted by Faraday's law with a difference less than 5%. This difference was greater at a higher electric current, probably due to the increased solution temperature. However, effect of pH on the dissolution of the aluminum was negligible. The result of this study suggested that the operating condition of electrocoagulation system could be developed using the Faraday's law when the pollutant concentration is given.

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The Influence of Electrolytic Condition on Tunnel Etching and Capacitance Gain of High purity Aluminium Foil on capacitor (전해조건이 고순도 알루미늄 박 콘덴서의 터널에칭과 정전용량에 미치는 영향)

  • 이재운;이병우;김용현;이광학;김흥식
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.44-56
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    • 1997
  • Influence of electrochemical etching conditions on capacitance gain of aluminium electrolytic on capacitor foil has been investigated by etching cubic textured high purity aluminum foil in dilute hydrochloric acid. Uniformly distributed etch pit tunnels on aluminum surface have been obtained by pretreatment aluminium foil in 10% NaOH solution for 5 minutes followed by electrochemical etching. Electrostatic capacitance of etched aluminium foil anodized to high voltage increased with the increase of current density, total charge, temperature and concentration of electrolyte up to maximum CV-value and then deceased. Election optical observation of the etched foil revealed that the density of etch of etch pits increased with the increase of current density and concentration of electrolyte. this increase of etch pit density enlarged of the increase of capacitance. However, abnormal high current density and high electrolyte concentration induced the local dissolution of the foil surface which resulted the decrease of foil capacitance.

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Synthesis and Photosensitive Characterization Comparison by Gray Scale of Photoresist for Printing Plate;Study of the Photoresist for Printing Plate[II] (인쇄 제판용 Photoresist의 합성과 G.S법에 의한 감광특성 비교;인쇄 제판용 Photoresist의 연구[II])

  • Lee, Ki-Chang
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.27-34
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    • 1997
  • Naphthoquinone-1,2-diazide-5-sulfonyl [NDS]derivatives members of Quinone diazide compound that are utilizable as photoresist for printing plate were synthesized, and photoresist were prepared by mixing these derivatives with a matrix resin(PF, CF) at various weight ratios. Photosensitive characteristics of photoresist were studied by Gray scale method, and SEM to analyze if they can be used as photosensitive material in a printing plate. Experimental results showed using IR, UV, NDS derivatives were photoconverted and developer-soluble photoresist were produced. Photoresist in the mixing ratio of 1:4 of NDS[II] and CF resin gave rise to the highest dissolution rate. In addition, photoresist obtained at this condition resulted in the most superior sensitivity.

퇴적물 내 비소의 지구미생물학적 거동 연구

  • Lee Jong-Un;Lee Sang-U;Park Ji-Min;Kim Gyeong-Ung;Jeon Hyo-Taek;Jeong Myeong-Chae
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.111-114
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    • 2006
  • The effects of indigenous bacteria on geochemical behavior of As in As-contaminated sediments (Hwachon mine and Myoungbong mine) after biostimulation with a variety of carbon sources were investigated under anaerobic condition. In Hwachon sediment, As was dramatically extracted from nonsterile sediment with time, reaching the highest concentration of $500{\mu}g/L$. The As leaching was likely caused by microbial dissolution of Fe oxides/oxyhydroxides with which As had been coprecipitated. However, in the case of Myoungbong sediment supplied with glucose, dissolved As decreased with time likely due to production of As sulfide(s) and subsequent precipitation, which resulted from bacterial reduction of $SO_4^{2-}$. The results implied that bacterial in-situ stabilization of As In subsurface has a potential to be practically applied.

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The Effect of Molecular Weight on the Gelation Behavior of Regenerated Silk Solutions

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.23 no.1
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    • pp.183-186
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    • 2011
  • The various molecular weight (MW) regenerated silk fibroins were prepared with different dissolution condition and the effect of MW on the gelation behavior of regenerated aqueous silk fibroin (SF) solution was investigated. The result of gelation time measurement indicated that the gelation of SF aqueous solution was accelerated by the increase of MW and SF concentration. When formic acid was added in SF aqueous solution, the gelation time of SFL and SFC30 aqueous solution showed a significant decreaseat 0.03% formic acid addition. In case of the lowest MW sample, SFC180, SF molecules became aggregated and precipitated without gelation after 28 days storage time. These findings indicate that MW control of SF can be utilized to control the gelation time of SF aqueous solution.

A study on the bending strength characteristics of steel bar and GFRP rebar in salt water surroundings (해수 환경에서의 철근과 GFRP 리바의 굽힘 강도 특성에 관한 연구)

  • Han, Gil-Young;Lee, Dong-Gi;Kwak, Sang-Muk;Bae, Si-Yon;Kim, Ki-Sung
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.10a
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    • pp.354-358
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    • 2002
  • This paper describes the need for a ductile Fiber Reinforced Plastics (FRP) reinforcement for concrete structures. To promte the degradation of the adhesive condition at the fiber/matrix micro interface without matrix dissolution loss were carried out in salt water surrounding. The absorption properties and the bending strength were compared about GFRP rebar and steel bar.

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Electrochemical Studies on the Mechanism of the Fabrication of Ceramic Films by Hydrothermal-Electrochemical Technique

  • Zhibin Wu;Masahiro Yoshimura
    • Bulletin of the Korean Chemical Society
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    • v.20 no.8
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    • pp.869-874
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    • 1999
  • In this paper, electrochemical techniques are used to investigate hydrothermal-electrochemically formation of barium titanate (BT) ceramic films. For comparison, the electrochemical behaviors of anodic titanium oxide films formed in alkaline solution were also investigated both at room temperature and in hydrothermal condition at 150.0 ℃. Film structure and morphology were identified by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Titanium oxide films produced at different potentials exhibit different film morphology. The breakdown of titanium oxide films anodic growth on Ti electrode plays an important roles in the formation of BT films. BT films can grow on anodic oxide/metal substrate interface by short-circuit path, and the dissolution-precipitation processes on the ceramic film/solution interface control the film structure and morphology. Based upon the current experimental results and our previous work, extensively schematic proce-dures are proposed to model the mechanism of ceramic film formation by hydrothermal-electrochemical method.

Characteristics of ethylcellulose microcapsules of sulfisoxazole

  • Oh, Doo-Man;Lee, Min-Hwa
    • Archives of Pharmacal Research
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    • v.5 no.2
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    • pp.61-70
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    • 1982
  • Sulfisoxazole, a chemotherapeutic agent, was microencapsulated with ethylcellulose by means of phase separation form cyclohexane by temperatture change. The size distribution was determined by use of standard sieves and the effect of core to wall ratio was noted. To examine their shapes and usrface characteristics, the microcapsules were observed with a scanning electron microscope. Release of the drug from microcapsules into pH 7.5 buffer medium was studied. The release pattern was found to have similar properties to the release of a drug from an insoluble porous matrix reported. The apparent diffusion coefficient of sulfisoxazole was measured for the transport of the drug from the core of microcapsules into the surronding sink condition. The apparent diffusion coefficient increased with increasing capsule size.

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Preliminary Study on the Regeneration of Spent Electro-decontamination Solution Using Phosphoric Acid and Oxalic Acid

  • Naznin, Marufa;Septian, Ardie;Shin, Won Sik
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2015.10a
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    • pp.465-466
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    • 2015
  • In this study, different amount of (fe(0)) were dissolve into different strength of phosphoric ($H_3PO_4$) acid and the optimum solubility was observed at 0.89M Fe(0) into 4M of $H_3PO_4$ acid. Different concentration of oxalic acid was added to determine the optimum precipitated condition. The dissolution kinetics of Fe(0) into $H_3PO_4$ acid was investigated at $40-50^{\circ}C$. The optimum Fe-oxalate precipitate was dried and thermal decomposition using DSC-TG was conducted. Approximately 52 wt(%) of oxalic acid was removed at $300^{\circ}C$. Iron oxides such as magnetite and hematite that may be formed on the surface of nuclear waste were also dissolved into the $H_3PO_4$ acid and the optimum solubility for magnetite is 0.005M while that for hematite is 0.02M in 8M $H_3PO_4$ acid, respectively.

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Study on the Fatigue Resistance of Gray Cast Iron in CO2 Laser Surface Hardening (CO2레이저 표면경화(表面硬化) 처리된 회주철(灰鑄鐵)의 피로특성(疲勞特性)에 관한 연구(硏究))

  • Park, K.W.;Han, Y.H.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.3
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    • pp.169-181
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    • 1995
  • This study has been performed to investigate some effects of the power density and traverse speed of laser beam on the optical microstructure, hardness and fatigue resistance of gray cast iron treated by laser surface hardening technique. Optical micrograph has shown that the dissolution of graphite flakes and the coarsening of lath martensite tend to increase with a small amount of retained austenite as the power density increases under the condition of a given traverse speed. Hardness measurements have revealed that as the power density increases, hardness values of outermost surface layer increases from Hv=620 to Hv=647 in case of traverse speed of 2.0m/min at gray cast iron. Fatigue test has exhibited that the fatigue strength of laser surface hardened specimen is superier compared to that of untreated specimen, showing that values for the fatigue strength at $N_f=10^7$ of gray cast iron laser-surface-hardened at a low power density of $4076w/cm^2$ and a high power density of $8153w/cm^2$ under the condition of a given traverse speed of 2.0m/min are $15kg_f/mm^2$ and $20kg_f/mm^2$, respectively, whereas the fatigue strength of untreated specimen is $11kg_f/mm^2$. Under high stress-low cycle condition a noraml brittleness fracture appears, whereas a ductile fracture with beach mark is observed in the specimen tested under low stress-high cycle condition.

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