• Bulletin of the Korean Chemical Society
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• 제14권2호
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• pp.188-191
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• 1993

The reaction between methyl 2,3-di-O-benzyl-4,6-di-O-mesyl-${\alpha}$-D-glucopyranoside (1b) and potassium superoxide resulted in hydrolysis, and gave methyl 2,3-di-O-benzyl-${\alpha}$-D-glucopyranoside (1) as a sole product. When the reaction was performed with a vicinal dimesylate, methyl 4,6-O-benzylidene-2,3-di-O-mesyl-${\alpha}$-D-altropyranoside (4b), again the hydrolysis product, methyl 4,6-O-benzylidene-${\alpha}$-D-altropyranoside (4) was obtained. However, the reaction of potassium superoxide with another vicinal dimesylate, methyl 4,6-O-benzylidene-2,3-di-O-mesyl-${\alpha}$-D-glucopyranoside (3b), nucleophilic displacement took place to afford methyl 4,6-O-benzylidene-${\alpha}$-D-altropyranoside (4). Apparently different results from two trans vicinal dimesylates, 3b and 4b are explained by the transient formation of epoxides, methyl 2,3-anhydro-4,6-O-benzylidene-${\alpha}$-D-allopyranoside (8) and methyl 2,3-anhydro-4,6-O-benzylidene-${\alpha}$-D-mannopyranoside (9) by $KO_2$. The reaction between the allo epoxide 8 and $KO_2$ gave altro 4. The manno epoxide 9 also afforded altro 4 as the major product. Facile epoxide formation by the reaction of a vicinal dimesylate and superoxide was also observed with 3-O-benzyl-1,2-O-isopropylidene-5,6-di-O-mesyl-${\alpha}$-D-glucofuranose: 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-${\beta}$-L-idofuranose was obtained.

• 대한치과교정학회지
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• 제18권2호
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• pp.367-385
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• 1988

In case of skeletal Class III malocclusion with underdeveloped maxilla, the extraoral orthopedic force for the stimulation of maxillary growth or anterior reposition of the maxilla has been used clinically for the improvement of facial skeletal relationship. The purpose of this investigation was to examine the initial reaction of maxillofacial complex to the maxillary protraction by using extraoral orthopedic force. The dried human skull was used and this investigation was done by means of double exposure holographic interferometry. The protraction forces placed on the canine or the first molar were parallel, $10^{\circ}$ downward, $20^{\circ}$ downward to the occlusal plane. Fringe pattern of each protraction condition was compared and analized. The results were as follows: 1. Each maxillofacial bone displaced saparately. 2. More displacement was shown at the area of the teeth and the alveolar bone. 3. A counterclockwise rotation of the maxilla wa decreased by downward protraction and especially 20 degree downward protraction from the canine showed least rotation. 4. On the zygomatic arch, outward bend was observed and this effect was decreased by downward protraction. 5. On the zygomatic bone, the counter clockwise rotation was increased by the downward protraction. 6. When maxillary expansion was applied at the same time, outward and upward displacement with counterclockwise rotation was observed on the maxilla. 7. The lateral pterygoid plate of sphenoid bone was affected by maxillary protraction.

• 한국소음진동공학회논문집
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• 제12권10호
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• pp.749-757
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• 2002

Excessive vibration in flexible structures is a problem encountered in many different fields, causing fatigue of structural components. Passive techniques, though sometimes limited in their capabilities, have been used in the past to attenuate vibrations. Recently active techniques have been developed to enhance vibration control performance beyond that provided by their passive counterparts. Most often, the focus of active control methods has been to suppress structure displacements. In cases where vibration results in structure failures, displacement suppression may not be the best choice of control approaches (it can, in fact, increase dynamic loads which would be even more harmful to supports) . This paper presents two optimal control methods for attenuating steady state vibrations in flexible structures. One method minimizes shaft displacements while another minimizes dynamic reaction forces. The two methods are applied to a model of a typical flexible structure system and their results are compared. It is found that displacement minimization can increase loads, while load minimization decreases loads.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2001년도 추계학술대회논문집 II
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• pp.1126-1131
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• 2001

Excessive vibration in rotating machinery is a problem encountered in many different fields, causing such difficulties as fatigue of machinery components and failure of supporting bearings. Passive techniques, though sometimes limited in their capabilities, have been used in the past to attenuated vibrations. Recently active techniques have been developed to provide vibration control perform beyond that provided by their passive counters. Most often, the focus of active control methods has been to suppress rotating machinery displacements. In cases where vibration results in bearing failures, displacement suppression may not be the best choice of control approaches (it can, in fact, increase dynamic bearing loads which would be even more harmful to bearings). This paper presents two optimal control methods for attenuating steady state vibrations in rotating machinery. One method minimizes shaft displacements while the other minimizes dynamic bearing reaction forces. The two methods are applied to a model of a typical rotating machinery system and their results are compared. It is found that displacement minimization can increase bearing loads, while bearing load minimization, on the other hand, decreases bearing loads.

• 대한화학회지
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• 제32권6호
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• pp.593-602
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• 1988

크라운 에테르를 반복 사용 기능의 상이동 촉매(phase transfer catalyst ; PTC)로 유도하기 위해 고분자 물질로 지지된 크라운 에테르(polymer-supported crown ether ; Ps-CE)류를 합성하고, 이들 Ps-CE(solid phase)를 이용하여 액-고-액 3상 불균일계에서의 1-bromooctane(유기층)의 iodide(수용층) 친핵 치환 반응속도를 측정하고 그 상이동 촉매능을 연구검토하였다. Ps-CE류는 hydroxymethyl기를 지니는 크라운 에테르류를 합성한 후 이를 1∼2% cross-linked chloromethylated polystyrene 에그라프트시켜 제조하였다. 3상 불균일계치환반응은 반응기질의 농도에 의존하는 유사 일차반응이었고 반응속도상수$(k_{obsd})$는 사용한 촉매량에 비례하였으며, 가교밀도, 온도, 용매 등에 영향을 받음을 알 수 있었다. Ps-CE의 촉매능을 구조적으로 유사한 가용성 크라운 에테르의 촉매능과 비교하였으며, 반응 후 단순히 여과분리하고 이를 PTC로서 반복사용하였을때 촉매능의 감소없이 재사용이 가능함을 알 수 있었다. 반응의 활성화 엔탈피 및 엔트로피는 각각 10∼20kcal $mol^{-1}, 20~55eu.이었고 활성화 자유 에너지는 ∼30kcal mol^{-1}$,/TEX>이었다.

• Composites Research
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• 제28권4호
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• pp.191-196
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• 2015

본 연구에서는 접착제로 체결된 구조물의 접착 조인트에서의 파괴인성을 조사하기 위하여 알루미늄 폼으로 제작한 Mode III 형 DCB 시험편들에 대하여 정적 해석 및 실험을 수행하였다. 정적 해석에서의 경우, 각 시험편 모델들은 강제 변위가 약 5 mm 진행되었을 때 최대 반력을 보였으며, 이 때 각 시험편 모델들의 최대 반력은 두께가 35 mm인 모델이 약 0.25 kN, 두께가 45 mm인 모델이 약 0.28 kN, 두께가 55 mm인 모델이 약 0.5 kN으로 나타났다. 이 해석 결과들을 입증하기 위하여 정적 실험의 경우에서 두 개의 시험편들을 택하였다. 정적 실험에서의 경우, 각 시험편들은 강제 변위가 약 5~6 mm 진행되었을 때 최대 반력을 보였으며, 각 시험편들의 최대 반력은 두께가 35 mm인 시험편이 약 0.22 kN, 두께가 45 mm인 시험편이 약 0.3 kN으로 나타났다. 도출된 결과값들을 비교하였을 때 해석과 실험의 데이터들 간에 큰 차이가 없음을 알 수 있었고, 따라서 별도의 실험과정 없이 해석을 통해서도 그 연구 데이터들을 확보할 수 있을 것으로 판단되며, Mode III 형 DCB 접합구조물에서의 기계적 특성들을 체계적으로 분석할 수 있을 것으로 사료된다.

• 한국지반공학회논문집
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• 제15권2호
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• pp.3-16
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• 1999

현재 국내에서는 부유식 구조물을 이용하여 소각로 및 담수화 공장을 해상에 축조하는 BMP(Barge Mounted Plant) 시스템에 관한 연구를 수행중에 있다(한국기계연구원 1997). 본 논문에서는 이러한 BMP의 계류 돌핀(mooring dolphin) 구조물하부의 말뚝기초의 거동을 모델하는 기법에 관하여 다루었다. 지반-말뚝계의 축하중 및 횡하중에 대한 거동은 지반을 비선형 스프링으로 모델하고 말뚝을 일축부재 및 보로 모델하여 유한차분적으로 해를 구하는 비선형 지반반력해석을 수행한다. 이러한 말뚝두부에서의 하중-변위관계로부터 지반-말뚝계의 등가강성을 산정할 수 있다. 따라서 본 연구에서는 거제도 주변 해역을 대상으로 지반조사를 수행하였고 이를 토대로 지반의 깊이에 따른 축방향 및 횡방향 하중전이 관계를 도출하였다. 그리고 돌핀하부의 말뚝에 대하여 축하중 및 횡하중에 대한 지반반력해석을 수행하였다. 이러한 해석과정을 통하여 대상지역에 적합한 말뚝의 관입깊이 및 단면을 합리적으로 산정할 수 있었다. 결국 말뚝두부에서의 하중-변위관계로부터 지반-말뚝계의 강성을 모델함으로써, 지반조건을 고려하여 돌핀구조물의 동적해석을 합리적으로 수행할 수 있었다. 해석결과 지반-말뚝계의 강성을 고려할 경우에는 강체로 고려한 경우에 비하여 변위 진폭이 상당히 크게 나타났다. 그리고 돌핀의 케이싱 상부의 모멘트가 더 크게 나타나고 해저지표 말뚝두부에 전달되는 모멘트는 더 작게 나타남을 알 수 있었다.

• 한국운동역학회지
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• 제23권4호
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• pp.357-367
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• 2013

The purposes of this study were investigated physical compensation for gait on induced knee stiffness in normal subjects. Ten subjects were participated in the experiment(age: $26.0{\pm}6.3$ yrs, height: $175.5{\pm}5.3$ cm, weight: $69.1{\pm}6.1$ kg). The study method adopted 3D analysis with five cameras and ground reaction force with two force-plate. Induced knee stiffness level were classified as gait pattern on ROM of knee(free level, $30^{\circ}$ restriction level, fix level). The results were as follows; In angular displacement of hip joint, left hip joint was the more extended in mid-stance on induced right knee stiffness. In angular displacement of knee joint, there was no physical compensation on induced right knee stiffness, but free knee level gait was more flexed in swing phase of right knee joint. In angular displacement of ankle joint, right ankle joint was the more dorsiflexed on induced right knee stiffness, and $30^{\circ}$ restriction level and fix level gait were less plantarflexed in TO2. In trunk tilt, free and $30^{\circ}$ restriction level gait was more backward tilt on induced right knee stiffness. In ROM of each joint, right knee joint was more larger and trunk tilt was more lower on induced right knee stiffness. In GRF, Fx was more bigger lateral force in free and $30^{\circ}$ restriction level gait, and was more bigger medial force in fix level gait. Fy was more bigger propulsion force in free level gait, and was was more bigger braking force in $30^{\circ}$ restriction level gait. Left braking force in $30^{\circ}$ restriction level gait was more bigger. Fz was no significant.

• 한국운동역학회지
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• 제15권4호
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• pp.143-151
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• 2005

This study was conducted to investigate the technical factors of Cuervo forward straight vaults with single twist, single and half twists, and double twists actually performed by three execellent male gymnasts participated in artistic gymnastics competition of 2003 summer Universiade in Daegu and the 85th National Sports Festival in Cheongju. To accomplish the research goals the Cuervo vaults of three gymnasts were filmed by using three digital camcorders set by 60 Hz, and data were collected through the DLT method of three dimensional cinematography. The kinematic and kinetic variables as each phasic time, CM displacement velocity, release angle inclination angle hip joint angle landing angle, average horse reaction force average moment arm average torque, whoe body's total remote local angular momentum were analyzed, so the following conclusions were reached. Generally to perform the better Cuervo vault, a gymnast should touch down on the board with the great horizontal velocity of the whole body through the fast run-up, and touch down on the horse by decreasing the horizontal displacement of the whole body during the preflight, so raise CM height gradually within a short horse contact time. He should increase the horse reaction force through checking the horizontal velocity of the whole body effectively and the inclination angular displacement of the handstand, if so he can have the large vertical velocity of the whole body. By using the acquired the velocity and the angular momentum of the whole body, he can vault himself higher and twist sufficiently, then he can get better if the body could be tilted by swinging both arms and perform the cat twist with a little flexions at hip joints. According to the above outcomes we can judge that the best athletes is LuBin, the better is YTY, and the next is JSM.

• 대한치과교정학회지
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• 제24권2호
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• pp.447-476
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• 1994

This study was performed to evaluate the initial reaction of maxillofacial complex to the Class II intermaxillary and the anterior vertical elastic forces on the six types of archwires including multiloop edgewise arch wires(MEAW). A human dry skull was used for this purpose and this investigation was done by holographic interferometry. Based on such investigation, the fringe pattern and the number of fringes of each condition were compared and analyzed. The findings of this study were as follows: 1. As the orthodontic forces increased, the amount of displacement increased. 2. As the orthodontic forces were applied, the fringes were shown not only in the teeth and the maxilla but also in the adjacent bones, i.e., temporal bone, zygomatic bone, nasal bone, frontal bone and sphenoid bone. And the direction of fringe pattern and the number of fringes were different from each other by the sutures. 3. As the long Class II elastic forces were applied, the backward-downward displacements of the anterior teeth and the maxilla were shown, and backward displacement of the former were grater than those of the latter. And backward displacements were greater by the long Class II elastic forces than by the short Class II elastic forces. 4. As the anterior vertical elastic forces were applied, downward displacements of the anterior teeth and the maxilla were shown, and the downward displacements of the former were greater than those of the latter relatively. 5. The downward displacements of the anterior area to the anterior vertical elastic forces of the MEAW were greater than those of other archwires. In addition, the more tip-back bend was applied, the more displacement was seen. 6. As the Class II intermaxillary forces and the enough anterior vertical elastic forces were applied on the MEAW with tip-back bend, there was an intrusive effect of the posterior teeth.