• 한국전기전자재료학회논문지
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• 제30권3호
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• pp.185-191
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• 2017

Cadmium compounds with one dimension (1D) nanostructures have attracted attention for their excellent electrical and optical properties. In this study, vertically aligned CdTe-Si nanostructures with high density were synthesized by several simple chemical reactions. First, l D Te nanostructures were synthesized by silver assisted chemical Si wafer etching followed by a galvanic displacement reaction of the etched Si nanowires. Nanowire length was controlled from 1 to $25{\mu}m$ by adjusting etching time. The Si nanowire galvanic displacement reaction in $HTeO_2{^+}$ electrolyte created hybrid 1D Te-branched Si nanostructures. The sequential topochemical reaction resulted in $Ag_2Te-Si$ nanostructures, and the cation exchange reaction with the hybrid 1D Te-branched Si nanostructures resulted in CdTe-Si nanostructures. Wet chemical processes including metal assisted etching, galvanic displacement, topochemical and cation exchange reactions are proposed as simple routes to fabricate large scale, vertically aligned CdTe-Si hybrid nanostructures with high density.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3227-3231
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• 2014

Bamboo-like Te nanotubes were synthesized via the galvanic displacement reaction of NiFe nanowires with Ni-rich and Fe-rich segments. The thick and thin components of the synthesized Te nanotubes were converted from the Ni-rich and Fe-rich segments in the NiFe nanowires respectively. The dimensions of the Te nanotubes were controlled by employing sacrificial NiFe nanowires with tailored dimensions as the template for the galvanic displacement reaction. The segment lengths of the Te nanotubes were found to be dependent on those of the sacrificial NiFe nanowires. The galvanic displacement reaction was characterized by analyzing the open circuit potential and the corrosion resistance.

• 한국재난정보학회 논문집
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• 제13권3호
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• pp.286-295
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• 2017

본 연구는 경사계에 의한 지중수평변위 계측값을 중심으로 수치해석에 적용하기 위한 지반 반력계수를 다양한 이론 및 경험식으로 산출하여 비교하였다. 산정된 지반반력계수의 변화에 따라 벽체 최상단에서는 벽체변위의 최소값과 최대값의 차이가 6.80배로 크게 났으나, 최대 변위점에서는 차이는 거의 없는 1.06배로 나타나 지반반력계수의 증분에 비해 변위의 차이는 작으며 전체적으로 비슷한 값을 나타내었다. 또한 최대변위 발생점에서의 변위를 수치해석한 결과와 계측치로 비교한 결과 변위형상은 비슷하게 나타났다.

• 동력기계공학회지
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• 제21권2호
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• pp.83-88
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• 2017

We have examined the effect of values of subgrade reaction coefficient on the dynamic responses(displacement and strain responses) of the buried concrete pipeline of which the end boundary condition is the fixed ends. We have carried out the dynamic analysis of mode superposition method with representative values of coefficient of subgrade reaction applicable to the classified rock masses. We have found that the effect of subgrade reaction coefficient on the dynamic responses of the pipeline appears noticeable for the seismic waves having relatively high frequency and low apparent propagation velocity.

• Structural Engineering and Mechanics
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• 제54권4호
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• pp.793-807
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• 2015

Constructing the influence lines of forces of statically indeterminate structures is a traditional issue in structural engineering and mechanics. However, the existing kinematic method for establishing these force influence lines is an indirect or mixed approach by combining the force method with the theorem of reciprocal displacements, which is yet inconsistent with the kinematic method for statically determinate structure. This paper proposes the direct kinematic method in conjunction with the load-displacement differential relation for exactly constructing influence lines of reaction and internal forces of indeterminate structures. Firstly, through applying the principle of virtual displacement, the formula for influence lines of reaction and internal forces of indeterminate structure via direct kinematic method is derived based on the released structure. Then, a computational approach with a clear concept and unified procedure as well as wide applicability based on the load-displacement differential relation of beam is suggested to achieve conveniently the closed-form expression of force influence lines, and exactly draw them. Finally, three representative examples for constructing force influence lines of statically indeterminate beams and frame illustrate the superiority of the proposed method.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2529-2534
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• 2012

Poly(3,4-ethylenedioxythiophene) coated Manganese Dioxide (PEDOT/$MnO_2$) composite electrode was fabricated by simply immersing the $MnO_2$ electrode in an acidic aqueous solution containing 3,4-ethylenedioxythiophene (EDOT) monomers. Analysis of open-circuit potential of the $MnO_2$ electrode in the solution indicates the reduction of outer surface of $MnO_2$ to dissolved $Mn^{2+}$ ions and simultaneously oxidation of EDOT monomer to PEDOT on the $MnO_2$ surface to form a PEDOT shell via a galvanic displacement reaction. Analysis of cyclic voltammograms and specific capacitance of the PEDOT/$MnO_2$, conductive carbon added $MnO_2$ and conductive carbon added PEDOT/$MnO_2$ electrodes suggests that the conductive carbon acted mainly to provide a continuous conducting path in the electrode to improve the rate capability and the PEDOT layer on $MnO_2$ acts to increase the active reaction site of $MnO_2$.

• Structural Engineering and Mechanics
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• 제64권6권
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• pp.793-802
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• 2017

The damage of concrete due to the expansion of alkali-aggregate reaction (AAR) and thermal-chemical reactions affecting the strength of concrete is studied. The empirical equations for the variations of expansion of AAR, compressive strength and degradation of the modulus of elasticity with time, and compressive strength with degradation of the modulus of elasticity are proposed by analysing numerous experimental data. It is revealed that the expansion of AAR and compressive strength increase with time. The proposed combination of the time variations of chemical and mechanical parameters provides a satisfactory prediction of the concrete strength. Seismic analysis of the aged Koyna dam is conceded for two different long-term experimental data of concrete incorporating the proposed AAR based properties. The responses of aged Koyna dam reveal that the crest displacement of the Koyna dam significantly increases with time while the contour plots show that major principal stress at neck level reduces with time. As the modulus of elasticity decreases with ages the stress generated in the concrete structure get reduces. On the other hand with lesser value of modulus of elasticity the structure becomes more flexible and the crest displacement becomes very high that cause the seismic safety of the dam reduce.

• 한국지반공학회논문집
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• 제20권2호
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• pp.5-13
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• 2004

기존의 흙을 사용하여 건설된 철도 노반은 반복적인 교통하중의 증가, 열차속도의 향상, 노반상으로의 지하수의 유입, 노반의 배수능력 저하 등의 이유로 인해 시간경과에 따라 쉽게 그 기능을 상실할 수 있다. 본 연구에서는 실대형시험과 수치해석을 수행함으로씨 철도노반으로서의 쇄석강화노반의 성능을 평가하였다. 쇄석강화노반의 탄$.$소성 연직변위는 모사열차하중의 재하횟수에 관계없이 일반 흙노반에 비해 작은 응답특성을 보였으며, 동일한 노반 부설두께에서는 노반반력계수의 증가에 따라 감소하며, 동일한 강성인 경우 노반 부설두께 증가에 따라 감소하는 경향을 보였다. 하지만, 쇄석강화노반의 부설두께에 비해 노반의 강성이 궤도에 발생하는 전체 소성 연직변위에 더욱 큰 영향을 미치는 것으로 평가되었다.

• 한국응용과학기술학회지
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• 제26권3호
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• pp.279-287
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• 2009

Fisher-Tropsch synthesis for the production of hydrocarbon from syngas was investigated on 20% cobalt-based catalysts (20% Co/HSA, 20% Co/Si-MMS), which were prepared by home-made supports with high surface areas such as high surface alumina (HSA) and silica mesopores molecular sieve (Si-MMS). In the gas phase reaction by syngas only, 20% Co/Si-MMS catalyst was shown in higher CO conversion and lower carbon dioxide formation than 20% Co/HSA, whereas the olefin selectivity was higher in 20% Co/HSA than in 20% Co/Si-MMS. In the effect of n-hexane added in syngas, the selectivities of $C_{5+}$ and olefin were increased by comparing the supercritical phase reaction with the gas phase reaction in addition to reduce unexpected methane and carbon dioxide.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.3.1-3.1
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• 2011

Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.