• Title/Summary/Keyword: Dispersion evaluation

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Evaluation of Gelation Characteristics with The Variation of Additive Contents in The Alumina Slurry for Gel Casting Process (겔 캐스팅 공정을 위한 알루미나 슬러리에서의 첨가제 함량 변화에 따른 겔화특성 평가)

  • Chung, J.K.;Oh, C.Y.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.31 no.5
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    • pp.290-295
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    • 2022
  • Recently, the use of high-tech ceramic parts in functional electronic parts, automobile parts and semiconductor equipment parts is increasing. These ceramics materials are required to have high reproducibility, reliability, large size and complex shapes. The researchers initiated the work to develop a new shaping method called gel casting, which allows high performance ceramic materials with a complex shape to be produced. The manufacturing process parameters of gel casting include uniform mixing of the initiator, bubble removal, and slip injection. In this study, we analyzed the dispersion and gelation characteristics according to the change in the additive content of the alumina slurry in the gel casting process. The alumina slurry for gel casting was prepared by mixing a solvent, a monomer and a dispersant through a ball mill. Alumina powder and a gelation initiator were added to the mixed solution, and ball milling was performed for 24 hours. A viscosity of 6,435 cps and a stable zeta potential value were obtained under the conditions of alumina powder content of 55 vol% and dispersant 2.0 wt%. After curing for 12 hours by adding aps 0.1wt%, TEMED 0.2wt%, and Monomer 3, 5wt%, it was possible to separate from the molding cup, confirming that the gelation was completed.

Elastic buckling performance of FG porous plates embedded between CNTRC piezoelectric patches based on a novel quasi 3D-HSDT in hygrothermal environment

  • Yujie Zhang;Zhihang Guo;Yimin Gong;Jianzhong Shi;Mohamed Hechmi El Ouni;Farhan Alhosny
    • Advances in nano research
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    • v.15 no.2
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    • pp.175-189
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    • 2023
  • The under-evaluation structure includes a functionally graded porous (FGP) core which is confined by two piezoelectric carbon nanotubes reinforced composite (CNTRC) layers. The whole structure rests on the Pasternak foundation. Using quasi-3D hyperbolic shear deformation theory, governing equations of a sandwich plate are driven. Moreover, face sheets are subjected to the electric field and the whole model is under thermal loading. The properties of all layers alter continuously along with thickness direction due to the CNTs and pores distributions. By conducting the current study, the results emerged in detail to assess the effects of different parameters on buckling of structure. As instance, it is revealed that highest and lowest critical buckling load and consequently stiffness, is due to the V-A and A-V CNTs dispersion type, respectively. Furthermore, it is revealed that by porosity coefficient enhancement, critical buckling load and consequently, stiffness reduces dramatically. Current paper results can be used in various high-tech industries as aerospace factories.

Electrochemical Catalysts Test for Nano Pt Particles on Carbon Support Synthesized by a Polyol Process Parameter Control (폴리올 공정 제어에 의한 탄소기반 나노 Pt 촉매 담지 특성 평가)

  • Chae Lin Moon;Jin Woo Bae;Soon Mok Choi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.164-169
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    • 2023
  • Nano Pt particles were dispersed on carbon-based supports by a polyol process for a catalyst application in a polymer electrolyte fuel cell. We tried to optimize the effect of pH on the electrostatic forces between the support and the Pt colloids. We investigated the relationship among the surface charges on the carbon support, the solution pH, and the concentration of a glycolate, and the Pt particle size. The produced catalyst with nano Pt particles on the support was evaluated by the long-term cyclic voltammetry (CV) performance test and compared with the results from a commercial catalyst. Our experimental results reveal that the pH-control can modify the particle size distribution and the dispersion of the nano Pt particles. This resulted in a cost-effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells better than a commercial catalyst system.

Propagating and evanescent waves in a functionally graded nanoplate based on nonlocal theory

  • Cancan Liu;Jiangong Yu;Bo Zhang;Xiaoming Zhang;Xianhui Wang
    • Advances in nano research
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    • v.14 no.5
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    • pp.463-474
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    • 2023
  • The purpose of this paper is to present the analysis of propagating and evanescent waves in functionally graded (FG) nanoplates with the consideration of nonlocal effect. The analytical integration nonlocal stress expansion Legendre polynomial method is proposed to obtain complete dispersion curves in the complex domain. Unlike the traditional Legendre polynomial method that expanded the displacement, the presented polynomial method avoids employing the relationship between local stress and nonlocal stress to construct boundary conditions. In addition, the analytical expressions of numerical integrations are presented to improve the computational efficiency. The nonlocal effect, inhomogeneity of medium and their interactions on wave propagation are studied. It is found that the nonlocal effect and inhomogeneity of medium reduce the frequency bandwidth of complex evanescent Lamb waves, and make complex evanescent Lamb waves have a higher phase velocity at low attenuation. The occurrence of intersections of propagating Lamb wave in the nonlocal homogeneous plate needs to satisfy a smaller Poisson's ratio condition than that in the classical elastic theory. In addition, the inhomogeneity of medium enhances the nonlocal effect. The conclusions obtained can be applied to the design and dynamic response evaluation of composite nanostructures.

A Study on Quality Improvement by Evaluation and Application of GUM-based Measurement Uncertainty (GUM 기반 측정불확도의 평가 및 적용에 의한 품질개선)

  • Insoo Choi;Sun Hur
    • Journal of Korean Society for Quality Management
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    • v.51 no.3
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    • pp.419-434
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    • 2023
  • Purpose: Measurement results obtained under non-ideal measurement environment conditions may contain uncertain factors. As a result, the reliability of measurement results may be deteriorated. In this study, we tried to find ways to improve quality by evaluating and applying measurement uncertainty based on GUM. Methods: In the flatness measurement of semiconductor parts, uncertainty factors that could occur under actual environmental conditions of workers were derived, and measurement uncertainties were calculated, and methods for minimizing the main factors affecting the measurement results were analyzed. Results: Depending on the part and the coordinate measuring machine, it was shown that the effect of dispersion caused by repeated measurements as type A uncertainty and the effect of the calibration results of equipment as type B uncertainty have the main influence. Conclusion: Depending on the uncertainty factors of type A and type B and the influence of the total expanded uncertainty, the central value and confidence interval of the initial measurement results showed fluctuations. It is considered that analysis and measures for the main uncertainty factors are needed as quality improvement in the industrial field.

Fabrication and Comparative Evaluation of Soybean Hull Nanofibrillated Cellulose (대두피 나노 섬유화 셀룰로오스 제작 및 비교 평가)

  • Jin-Hoon Kim;Hui-Yun Hwang
    • Composites Research
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    • v.37 no.3
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    • pp.150-154
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    • 2024
  • In this study, nanofibrillated cellulose was extracted from soybean hulls - a by-product of soybeans - and compared with soybean hull nanofibrillated cellulose obtained by using other nanofibrillated methods. Dry soybean hulls were ground into prepare micrometer-sized powders, from which microcellulose was isolated using NaOH and HCl. The nanometer-sized cellulose was successfully extracted through ultrasonic dispersion and ball milling. The soybean hull nanofibrillated cellulose exhibited a diameter of 60-100 nm and a length of 0.3-1.0 ㎛, which matches the diameter of soybean nanofibrillated cellulose made by other nanofibrillated methods but is significantly shorter in length.

Single Carbon Fiber/Acid-Treated CNT-Epoxy Composites by Electro-Micromechanical Technique and Wettability Test for Dispersion and Self-Sensing (젖음성 시험과 전기-미세역학 시험법과 통한 단 카본섬유/산처리된 CNT-에폭시 나노복합재료의 분산과 자체-감지능)

  • Jang, Jung-Hoon;Wang, Zuo-Jia;GnidaKouong, Joel;Gu, Ga-Young;Park, Joung-Man;Lee, Woo-Il;Park, Jong-Kyoo
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.90-97
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    • 2009
  • Dispersion and self-sensing evaluation for single-carbon fiber reinforced in three different acid-treated CNT-epoxy nanocomposites were investigated by electro-micromechanical techniques and wettability tests. Self-sensing based on contact resistivity exhibited more noise for single carbon fiber/acid-treated CNT-epoxy composites than it did for untreated CNT. However, the apparent modulus was higher the acid treated case than the untreated case which is attributed to better stress transfer. The interfacial shear strength (IFSS) between carbon fibers and the CNT-epoxy was lower than that between carbon fiber and neat epoxy due to the increased viscosity associated with the addition of the CNT. The CNT-epoxy nanocomposite exhibited more hydrophobicity than did neat epoxy. Change in the thermodynamic work of adhesion was consistent with changes in the IFSS but disproportional to that of the apparent modulus. The optimum condition of acid treatment on the need can be obtained instead of the maximum condition.

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Evaluation of phase velocity in model rock mass using wavelet transform of surface wave (표면파에 대한 웨이블렛 변환을 이용한 모형 암반의 위상속도 예측)

  • Lee, Jong-Sub;Ohm, Hyon-Sohk;Kim, Dong-Hyun;Lee, In-Mo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.10 no.1
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    • pp.69-79
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    • 2008
  • Prediction of ground condition ahead of tunnel face might be the most important factor to prevent collapse during tunnel excavation. In this study, a non-destructive method to evaluate the phase velocity in model rock mass using wavelet transform of surface wave was proposed aiming at ground condition assessment ahead of tunnel face. Model tests using gypsum as a rocklike material composed of two layers were performed. A Piezoelectric actuator with frequencies ranging from 150 Hz to 5 kHz was selected as a harmonic source. The acceleration history was measured with two accelerometers. Wavelet transform analysis was used to obtain the dispersion curves from the measured data. The experimental results showed that the near-field effects can be neglected if the distance between two receivers is chosen to be three times the wavelength. A simple inversion method using weighted factor based on the normal distribution was proposed. The inversion results showed that the predicted phase velocity agreed reasonably well with the measured one when the wavelength influence factor was 0.2. The depth of propagation of surface wave was from 0.42 to 0.63 times the wavelength. The range of wavelength varying with phase velocity in dispersion curve matched well with that estimated by inversion technique.

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Estimation of Genetic Parameters for Calving Ease by Heifers and Cows Using Multi-trait Threshold Animal Models with Bayesian Approach

  • Lee, D.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.8
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    • pp.1085-1090
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    • 2002
  • Genetic parameters for birth weights (BWT), calving ease scores observed from calves born by heifers (CEH), and calving ease scores observed from calves born by cows (CEC) were estimated using Bayesian methodology with Gibbs sampling in different threshold animal models. Data consisted of 77,458 records for calving ease scores and birth weights in Gelbvieh cattle. Gibbs samplers were used to obtain the parameters of interest for the categorical traits in two univariate threshold animal models, a bivariate threshold animal model, and a three-trait linear-threshold animal model. Samples of heritabilities and genetic correlations were calculated from the posterior means of dispersion parameters. In a univariate threshold animal model with CEH (model 1), the posterior means of heritabilities for calving ease was 0.35 for direct genetic effects and 0.18 for maternal genetic effects. In the other univariate threshold model with CEC (model 2), the posterior means of heritabilities of CEC was 0.28 for direct genetic effects and 0.18 for maternal genetic effects. In a bivariate threshold model with CEH and CEC (model 3), heritability estimates were similar to those in unvariate threshold models. In this model, genetic correlation between heifer calving ease and cow calving ease was 0.89 and 0.87 for direct genetic effect and maternal genetic effects, respectively. In a three-trait animal model, which contained two categorical traits (CEH and CEC) and one continuous trait (BWT) (model 4), heritability estimates of CEH and CEC for direct (maternal) genetic effects were 0.40 (0.23) and 0.23 (0.13), respectively. In this model, genetic correlation estimates between CEH and CEC were 0.89 and 0.66 for direct genetic effects and maternal effects, respectively. These estimates were greater than estimates between BWT and CEH (0.82 and 0.34) or BWT and CEC (0.85 and 0.26). This result indicates that CEH and CEC should be high correlated rather than estimates between calving ease and birth weight. Genetic correlation estimates between direct genetic effects and maternal effects were -0.29, -0.31 and 0.15 for BWT, CEH and CEC, respectively. Correlation for permanent environmental effects between BWT and CEC was -0.83 in model 4. This study can provide genetic evaluation for calving ease with other continuous traits jointly with assuming that calving ease from first calving was a same trait to calving ease from later parities calving. Further researches for reliability of dispersion parameters would be needed even if the more correlated traits would be concerned in the model, the higher reliability could be obtained, especially on threshold model with property that categorical traits have little information.

A High-resolution Numerical Simulation and Evaluation of Oak Pollen Dispersion Using the CMAQ-pollen Model (CMAQ-pollen 모델을 이용한 참나무 꽃가루 확산 고해상도 수치모의 및 검증)

  • Oh, Inbo;Kim, Kyu Rang;Bang, Jin-Hee;Lim, Yun-Kyu;Cho, Changbum;Oh, Jae-Won;Kim, Yangho;Hwang, Mi-Kyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.1
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    • pp.31-44
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    • 2017
  • The aim of this study is to evaluate the accuracy and variability of the oak pollen concentrations over the Seoul metropolitan region (SMR) simulated by the Community Multiscale Air Quality (CMAQ)-based pollen dispersion model, which is the CMAQ-pollen model integrated with the improved oak pollen emission model(PEM-oak). The PEM-oak model developed is based on hourly emission flux parameterization that includes the effects of plant-specific release, meteorological adjustment, and diurnal variations of oak pollen concentrations. A 33 day-run for oak pollen simulation was conducted by the CMAQ-pollen model with a 3 km spatial resolution for the SMR during the 2014 spring pollen season. Modeled concentrations were evaluated against the hourly measurements at three Burkard sampling sites. Temporal variations of oak concentrations were largely well represented by the model, but the quantitative difference between simulations and measurements was found to be significant in some periods. The model results also showed that large variations in oak pollen concentrations existed in time and space and high concentrations in the SMR were closely associated with the regional transport under strong wind condition. This study showed the effective application of the CMAQ-pollen modeling system to simulate oak pollen concentration in the SMR. Our results could be helpful in providing information on allergenic pollen exposure. Further efforts are needed to further understand the oak pollen release characteristics such as interannual variation of the oak pollen productivity and its spatio-temporal flowering timing.