• Elastomers and Composites
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• 제41권4호
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• pp.252-259
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• 2006

천연고무(NR) 라텍스의 원심분리 농축과정의 부산물인 고농도 단백질 함유 스킴 천연고무라텍스(SNRL)를 이용한 고무/점토 나노복합체의 새로운 제조방법을 제시하였다. SNRL과 26% 아크릴로니트릴 함량의 NBR 라텍스의 혼합물에 수분산 유기화 점토(OC)를 첨가하여 혼합하고, 건조 후에 밀혼합과 가황공정을 거쳐 NR/아크릴로니트릴 부타디엔 고무(NBR) 나노복합체를 제조하였다. X-선 회절(XRD) 연구를 통하여 제조된 NR/NBR 블렌드 나노복합체는 층간 삽입이 높은 삽입형과 일부 박리형을 나타내는 것으로 밝혀졌고, 특히 NBR 상이 많은 블렌드에서 그 효과는 더 크게 나타났다. 동적기계적 거동 분석결과 NBR 상이 높은 블렌드가 상용성이 더 높은 것으로 나타났다. NR/NBR 25/75 블렌드가 가장 우수한 기계적 강도를 나타내었다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1997년도 춘계학술발표회논문집(2)
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• pp.165-170
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• 1997

Samples of extruded dispersions of 24 vol.% spherical U-2wt%Mo and U-10wt.%Mo powders in an aluminum matrix were annealed for over 2,000 hours at 40$0^{\circ}C$. No significant dimensional changes occurred in the U-1025.%Mo/aluminum dispersions. The U-2wt.%Mo/aluminum dispersion, however, increased in volume by 26% after 2,000 hours at 40$0^{\circ}C$. This large volume change is mainly due to the formation of voids and cracks resulting from nearly complete interdiffusion of U-Mo and aluminum. Interdiffusion between U-10wt.%Mo and aluminum was found to be minimal. The different diffusion behavior is primarily due to the fact that U-2wt.%Mo decomposes from an as-atomized metastable r-phase(bcc) solid solution into the equilibrium r-U and U$_2$Mo two-phase structure during the experiment, whereas U-10wt.%Mo retains the metastable r-phase structure after the 2,000 hours anneal and thereby displays superior thermal compatibility with aluminum compared to U-2wt.%Mo. In addition, the molybdenium supersaturated in U-10wt.%Mo particles inhibits the diffusion of aluminum atoms along the grain boundary into the particle. Also, the dissolution of only a few Mo atoms in UAL$_3$ retards the formation of the intermediate phase, as Mo atoms need to migrate from new intermetallic compounds to unreacted islands.

• Elastomers and Composites
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• 제56권3호
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• pp.179-186
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• 2021

Carbon-based nanofillers, including nanodiamond (ND) and carbon nanotubes (CNTs), have been employed in epoxy matrixes for improving the toughness, using the tow prepreg method, of epoxy compounds for high pressure tanks. The reinforcing performance was compared with those of commercially available toughening fillers, including carboxyl-terminated butadiene acrylonitrile (CTBN) and block copolymers, such as poly(methyl methacrylate)-b-poly(butyl acrylate)-b-poly(methyl methacrylate) (BA-b-MMA). CTNB improved the mechanical performance at a relatively high filler loading of ~5 phr. Nanosized BA-b-MMA showed improved performance at a lower filler loading of ~2 phr. However, the mechanical properties deteriorated at a higher loading of ~5 phr because of the formation of larger aggregates. ND showed no significant improvement in mechanical properties because of aggregate formation. In contrast, surface-treated ND with epoxidized hydroxyl-terminated polybutadiene considerably improved the mechanical properties, notably the impact strength, because of more uniform dispersion of particles in the epoxy matrix. CNTs noticeably improved the flexural strength and impact strength at a filler loading of 0.5 phr. However, the improvements were lost with further addition of fillers because of CNT aggregation.

• 대한조선학회논문집
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• 제58권1호
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• pp.40-48
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• 2021

Through a series of bollard pull tests of a propeller in partially submerged condition, thrust, torque, and shaft excitation force of a conventional propeller model were measured using a six-component load cell. By variation of the Weber number and Reynolds number, a consistent towing tank model test condition was derived. The effects of propeller immersion depth on the ventilation behavior and change of force and moment acting onto the propeller shaft were investigated. The decrease in thrust owing to the inception of ventilation was confirmed, and a large degree of dispersion of the thrust and torque coefficients were also observed in the transition region where the blade tip was under the water surface. The shaft excitation force was derived from the force and moment onto the propeller shaft.

• 한국분말재료학회지
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• 제26권1호
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• pp.1-5
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• 2019

In this study, porous Mo-5 wt% Cu with unidirectionally aligned pores is prepared by freeze drying of camphene slurry with $MoO_3-CuO$ powders. Unidirectional freezing of camphene slurry with dispersion stability is conducted at $-25^{\circ}C$, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The green bodies are hydrogen-reduced at $750^{\circ}C$ and sintered at $1000^{\circ}C$ for 1 h. X-ray diffraction analysis reveals that $MoO_3-CuO$ composite powders are completely converted to a Mo-and-Cu phase without any reaction phases by hydrogen reduction. The sintered bodies with the Mo-Cu phase show large and aligned parallel pores to the camphene growth direction as well as small pores in the internal walls of large pores. The pore size and porosity decrease with increasing composite powder content from 5 to 10 vol%. The change of pore characteristics is explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

• Korean Chemical Engineering Research
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• 제56권6호
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• pp.811-818
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• 2018

A fire and explosion accident caused by a liquefied petroleum gas (LPG) welding and cutting torch gas leak occurred 10 m underground at the site of reinforcement work for bridge columns, killing four people and seriously injuring ten. We conducted a comprehensive investigation into the accident to identify the fundamental causes of the explosion by analyzing the structure of the construction site and the properties of propane, which was the main component of LPG welding and cutting work used at the site. The range between the lower and upper explosion limits of leaking LPG for welding and cutting work was examined using Le Chatelier's formula; the behavior of LPG concentration change, which included dispersion and concentration change, was analyzed using the fire dynamic simulator (FDS). We concluded that the primary cause of the accident was combustible LPG that leaked from a welding and cutting torch and formed a explosion range between the lower and upper limits. When the LPG contacted the flame of the welding and cutting torch, LPG explosion occurred. The LPG explosion power calculation was verified by the blast effect computation program developed by the Department of Defense Explosive Safety Board (DDESB). According to the fire simulation results, we concluded that the welding and cutting torch LPG leak caused the gas explosion. This study is useful for safety management to prevent accidents caused by LPG welding and cutting work at construction sites.

• 한국재료학회지
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• 제31권12호
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• pp.657-664
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• 2021

To build a highly active photocatalytic system with high efficiency and low cast of TiO₂, we report a facile hydrothermal technique to synthesize Ag₂Se-nanoparticle-modified TiO₂ composites. The physical characteristics of these samples are analyzed by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray analysis, transmission electron microscopy and BET analysis. The XRD and TEM results show us that TiO₂ is coupled with small sized Ag₂Se nanoplate, which has an average grain size of about 30 nm in diameter. The agglomeration of Ag₂Se nanoparticles is improved by the hydrothermal process, with dispersion improvement of the Ag₂Se@TiO₂ nanocomposite. Texbrite BA-L is selected as a simulated dye to study the photodegradation behavior of as-prepared samples under visible light radiation. A significant enhancement of about two times the photodegradation rate is observed for the Ag₂Se@TiO₂ nanocomposite compared with the control sample P25 and as-prepared TiO₂. Long-term stability of Ag₂Se@TiO₂ is observed via ten iterations of recycling experiments under visible light irradiation.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2000년도 하계종합학술대회 논문집(2)
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• pp.16-19
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• 2000

DC and low frequency noise characteristics of InGaP/InGaAs pseudomorphic HEMTs (p-HEMTs) grown by compound source MBE are investigated for temperature range of 150K to 370K. Equivalent input noise spectra( $S_{iv}$ ) were measured as a function of frequency and temperature. $S_{iv}$ was measured to be 3.4 $\times$ 10$^{-12}$ $V^2$/ Hz at 1kHz for 1.3 X 50${\mu}{\textrm}{m}$$^2$InGaP/InGaAs p-HEMT at room temperature. Measurements of the low-frequency noise spectra of the p-HEMT as a function of temperature show that the trap with an activation energy level around 0.589 eV is a dominant trap that accounts for the low-frequency noise behavior of the device. The normalized extrinsic gm frequency dispersion of the p-HEMT. was as low as 2.5％ at room temperature, indicating that the device has well-behaved low-frequency noise characteristics. Sub-micron (0.25 $\times$ 50${\mu}{\textrm}{m}$$^2$) gate p-HEMT showed $f_{T}$ and $f_{max}$ of 40GHz and 108GHz, respectively.y.y.

• 한국건축시공학회지
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• 제23권4호
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• pp.381-392
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• 2023

본 연구에서는 산화 그래핀 나노플레이트릿(Oxidized graphene nanoplatelet, GO)와 유공유리분말(Hollow glass powder, HGP)를 활용한 초고강도 콘크리트의 역학특성을 검토하였으며 이를 위해 작업성, 강도(압축, 인장), 수밀성, 내부조직을 검토하였다. 그 결과 HGP 소량 투입으로 작업성능을 획기적으로 회복시킬 수 있었고 강도특성 및 수밀성도 증가하는 것으로 나타났다. cGO(C사의 GO) 와 HGP는 응집현상 없이 분산이 잘 되어 있는 것으로 확인되었고 공극량은 20% 이상 감소하는 것으로 나타났다. cGO와 HGP가 실리카 흄(Silica fume, SF)을 대체할 수 있는지에 대해서도 검토하였다. cGO와 HGP의 사용으로 SF 없이도 쉽게 작업성을 확보할 수 있었고 역학특성도 향상되는 것으로 나타났으며 신재료의 사용으로 콘크리트 제조방법의 변화가 가능함을 확인할 수 있었다.

• 공업화학
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• 제8권5호
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• pp.816-821
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• 1997

기체분산기로 단일노즐을 사용한 내부순환 공기리프트 반응기에서 수력학과 액체의 흐름특성을 해석하였다. 실험은 공기-물계에서 기체속도와 반응기의 높이를 변화시키면서 국부지역의 기체체류량과 추적자의 충격-응답곡선을 측정하였다. 실험결과, 약 8 cm/s이상의 기체속도에서 상승관은 기포가 강한 합체를 일으키는 난류흐름을 나타내었고 하강관에서는 균일한 크기의 큰 기포들이 분산된 지역까지의 축방향 높이가 기체속도의 증가에 따라 감소하였다. 그리고 국부지역과 반응기 전체의 평균 기체체류량은 기체속도가 증가할수록 증가하였고 반응기 상부지역의 높이가 증가할수록 감소하였다. 또한 혼합시간은 기체속도보다 반응기 상부지역의 높이에 크게 영향을 받으며 이들이 증가할수록 감소하였다. 상승관과 하강관에서 액체의 흐름은 플러그흐름에 근접하였고 환전혼합흐름으로 볼 수 있는 반응기 상부지역의 크기에 따라 반응기 전체의 액체흐름특성이 크게 변화하였다. 이때 액체의 순환속도는 기체속도가 증가할수록 증가하였고 다른 기체분산기에서 보다 상당히 큰 값을 나타내었다.