• 한국세라믹학회지
• /
• 제37권7호
• /
• pp.721-725
• /
• 2000

In this study, the dispersion stability of nano-sized CeO2 particles, synthesized by hydrothermal method in aqueous was evaluated from observing the surface potential behavior of CeO2 particle synthesized by solid state reaction. The isoelectric point(IEP) of nano-sized CeO2 synthesized by hydrothermal synthesis was found to be pH 9 contrary to the isoelectric point of micro-sized CeO2 synthesized by solid state reaction at pH 6.7. IEP was shifted to pH 2.0 as the addition of D-3019 from 0.1 to 1.0 wt%. The surface potential of CeO2 particles synthesized by hydrothermal synthesis was reduced as the addition of B-1001 used as a binder without change of IEP because the absorption of B-1001 polymer on the CeO2 particles shifted the shear plane of CeO2 particles outward away from the surface. This surface potential behavior was well correlated with the dispersion stability of slurry.

• 한국분말재료학회지
• /
• 제14권2호
• /
• pp.123-126
• /
• 2007

In this work, the dispersion behavior of $Y_2O_3$ particles in binary aluminum (Al)-copper (Cu) cast alloy was investigated with respect to Cu contents of 20 (hypoeutertic), 33 (eutectic) and 40 (hypereutectic) wt.%. In cases of hypo and hypereutectic compositions, SEM images revealed that the primary Al and ${\theta}$ phases were grown up at the beginning, respectively, and thereafter the eutectic phase was solidified. In addition, it was found that some of $Y_2O_3$ particles can be dispersed into the primary Al phase, but none of them are is observed inside the primary 6 phase. This different dispersion behavior of $Y_2O_3$ particles is probably due to the difference in the val- ues of specific gravity between $Y_2O_3$ particles and primary phases. At eutectic composition, $Y_2O_3$ particles were well dispersed in the matrix since there is few primary phases acting as an impediment site for particle dispersion during solidification. Based on the experimental results, it is concluded that $Y_2O_3$ particles are mostly dispersed into the eutectic phase in binary Al-Cu alloy system.

• 비파괴검사학회지
• /
• 제34권3호
• /
• pp.233-240
• /
• 2014

나노/마이크로 소자의 개발이 활발해짐에 따라 나노/마이크로 박막의 기계적 물성의 정밀 측정에 대한 필요성이 점차 커지고 있다. 기존의 파괴적인 방법의 한계를 극복하기 위한 방법으로, 유도초음파를 이용한 비파괴적인 박막 물성 방법에 대한 관심이 늘어나고 있다. 유도초음파를 이용하여 박막의 물성을 측정하는 실험을 설계하거나, 물성 측정에 대한 실험 결과를 이해하는데 있어 박막의 분산선도를 이해하는 것은 필수적이라 할 수 있다. 본 연구에서는, 전달 행렬법을 이용하여 박막의 분산선도를 계산하는 방법을 제시하고, 이를 금속 박막에 적용하여 그 특성을 관찰하였다. 전달 행렬법을 이용하여 다층판에서의 주파수에 따라 유도초음파가 전파하는 속도를 계산하여 상용 프로그램과 비교하여 그 타당성을 확인하였다. 이러한 방법을 Si 기판 위에 증착된 Al 금속 박막에 적용하여 얻은 분산곡선의 분석을 통해, 박막의 두께 조건에 따른 모드와 분산 및 비분산 특성이 나타나는 구간을 관찰할 수 있었다.

• 한국수자원학회논문집
• /
• 제36권4호
• /
• pp.575-586
• /
• 2003

하천에 오염물질이 순간적으로 유입된 경우에는 연속적인 유입의 경우와 다르게 분산계수의 변화에 따라 오염물질의 거동 특성이 민감하게 변한다. 하천에 순간적으로 유입된 오염물질의 거동특성을 분석하기 위하여 한강하류부에서 수리인자 및 수질인자를 실측하였다. 분산계수 추정에 사용되는 경험식에 실측된 수리인자를 적용하여 갈수시 한강하류부의 분산계수의 규모를 분석하고, 적용 가능성이 큰 경험식을 제시하였다 또한, 실측된 수질인자를 RMA-4 모형의 계산치와 비교하여 만족할 만한 결과를 얻었다. 한강하류부에 순간적으로 유입된 오염물질의 분산계수, 하류단 수위 등의 변화에 따라 오염물질의 분산범위, 분산경로, 최초 및 최대농도 도달시간 등을 파악하였다.

• Earthquakes and Structures
• /
• 제23권2호
• /
• pp.115-128
• /
• 2022

One common method to select input ground motions to predict dynamic behavior of structures subjected to seismic excitation requires spectral acceleration (S_a) match target mean response spectrum. However, dispersion of ground motions, which explicitly affects the structural response, is rarely discussed in this method. Generally, selecting ground motions matching target mean and variance has been utilized as an appropriate method to predict reliable seismic response. The goal of this paper is to investigate the impact of target spectra variance of ground motions on structural seismic response. Two sets of ground motions with different target variances (zero variance and minimum variance larger than inherent variance of the target spectrum) are selected as input to two different structures. Structural responses at different heights are compared, in terms of peak, mean and dispersion. Results show that increase of target spectra variance tends to increase peak floor acceleration, peak deformation and dispersions of response of interest remarkably. To short-period structures, dispersion increase ratios of seismic response are close to that of S_a of input ground motions at the first period. To long-period structures, dispersions of floor acceleration and floor response spectra increase more significantly at the bottom, while dispersion increase ratios of IDR and deformation are close to that of S_a of input ground motions at the first period. This study could further provide useful information on selecting appropriate ground motion to predict seismic behavior of different types of structures.

• Macromolecular Research
• /
• 제17권7호
• /
• pp.469-475
• /
• 2009

We investigated the feasibility of dispersion polymerization without any stabilizer, which has been considered essential for ensuring colloidal stability. By employing small amounts of a lyophilic comonomer, 4-vinyl pyridine, styrene was successfully polymerized by dispersion polymerization in aqueous alcohol without stabilizer to afford stable poly(styrene-co-4-vinyl pyridine) copolymer microspheres. The stable microspheres were produced in the 4-vinyl pyridine range of 2-15 wt% to styrene. Without 4-vinyl pyridine, severely coagulated particles were obtained, implying that the poly(4-vinyl pyridine) moiety endowed colloidal stability. The polymerization kinetics, behavior, and properties of the ultimate particles showed general features of dispersion polymerization. The study results suggest that stabilizer- tree dispersion polymerization is possible, thereby facilitating the synthesis of impurity(stabilizer)-tree polymer particles.

• 대한기계학회논문집A
• /
• 제41권11호
• /
• pp.1065-1075
• /
• 2017

본 연구는 고속충돌에 따른 파괴로 인하여 발생한 파편들의 분산거동을 예측하기 위해 고속충돌 실험과 함께 재료거동 모델링 및 수치해석을 수행하였다. 알루미늄 합금과 강철로 각각 구성된 2종류의 위협체 및 표적판에 대해 충돌실험을 수행하였으며 위협체는 약 1 km/s의 속력으로 표적판과 충돌하고, 이 충돌로 인하여 발생한 파편은 알루미늄 합금 관측판에 손상을 유발시키게 하였다. 사용된 소재의 차이에 의해 파편의 분산거동이 상이하였으며 이에 따라 관측판에 형성된 파편의 분산 반경 또한 다름을 확인하였다. 수치해석은 실험과 동일한 조건하에서 수행되었으며 파편으로 인한 파괴 및 손상을 모사하기 위하여 입자완화 유체동역학(smoothed particle hydrodynamics, SPH)기법과 유한요소(finite element, FE) 연계 기법을 적용하였다. 실험 측정된 결과와 해석값을 비교분석한 바, 표적판의 관통부 지름과 관측판상의 파편 분산반경은 5 % 이내의 오차로 잘 일치하였다. 아울러 강철 위협체와 강철 표적판이 충돌한 경우 가장 큰 분산반경을 보임에 따라 타 경우에 비해 가장 위협적임을 알 수 있었다.

• Carbon letters
• /
• 제26권
• /
• pp.25-30
• /
• 2018

The dielectric medium used in electrophoretic displays (EPDs) is required to be an environmentally friendly solvent with high density, low viscosity, and a large electric constant. Hydrofluoroether, a highly fluorinated solvent with eco-friendly characteristics, is regarded as a viable alternative medium for EPDs, owing to the similarity of its physical properties to those of the conventional EPD medium. Surface modification of particles is required, however, in order for it to disperse in the charged solvent. Also, positive/negative charges should be present on the particle surface to enable electrophoretic behavior. In this study, carbon black particles wrapped with positively charged nitrogen (N-CBs) were fabricated by a simple hydrothermal process using a poly(diallyldimethylammonium chloride) solution as a black coloring agent for the EPD. The dispersion behavior of N-CBs was investigated in various solvents.

• 한국환경과학회지
• /
• 제11권12호
• /
• pp.1321-1326
• /
• 2002

A numerical model is investigated to predict a behavior of the gaseous volatile organic compounds and a subsurface contamination caused by them in the unsaturated zone. Two dimensional advective-dispersion equation caused by a density difference and two dimensional diffusion equation are computed by a finite difference method in the numerical model. A laboratory experiment is also carried out to compare the results of the numerical model. The dimensions of the experimental plume are 1.2m in length, 0.5m in height, and 0.05m in thickness. In comparing the result of 2 methods used in the numerical model with the one of the experiment respectively, the one of the advective-dispersion equation shows better than the one the diffusion equation.

• 한국방재학회:학술대회논문집
• /
• 한국방재학회 2008년도 정기총회 및 학술발표대회
• /
• pp.199-202
• /
• 2008

It is well-known fact that tidal difference between the ebb and flow in Yellow Sea is about 9 m so that it has largest value in the world. This wide range of tide level enables Yellow Sea water to intrude into main stream of Han River. However, the study of the tidal reach of Han River has not been carried out thoroughly since North and South Koreas share this region so that topography data and physical measurement are lacking. In this study, to examine the reverse flow and dispersion behavior by tidal effect at the tidal reach of Han River, 2-D river analysis models were applied. RMA-2 was applied to calculate the horizontal velocities and water surface elevation. With the results of velocities and water depth, RAM4, which is 2-D advection-dispersion model based on FEM was simulated to analyze the horizontal transport behavior of BOD.