• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.6
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• pp.747-757
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• 1997

A numerical investigation of the fuel concentration field in a fluidized bed has been carried out for the scale-up of a fluidized bed combustor (FBC). A two-dimensional transient model is developed using the two-phase fluidization, a simple chemical reaction, and lateral solid mixing theories. The uniformity of fuel concentration distributions is controlled by the location and the number of fuel feeders, fluidizing velocities and the bed-heights. While larger bubbles owing to greater fluidizing velocities enhance the fuel-dispersion in the bed, they have adverse effects on fuel combustion and thus result in the increase of fuel concentration, since a greater bubble means a larger bypass which reduces gas-exchange rates between bubble and emulsion phases. Average or maximum values of the bed fuel concentration are utilized as criteria for the scale-up from a pilot/lab-scale to a commercial-size bed.

• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.3
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• pp.263-270
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• 2015

Using Diesel-Water Emulsion fuel in commercial diesel engine can reduce NOx and soot when it is injected through the injector. Because water in Diesel-Water Emulsion fuel is vaporized ahead of diesel particle and it cause decrease of combustion temperature. Furthermore, research about the possibility of applicating Diesel-Water Emulsion fuels to commercial diesel engine is demanded in order to prove that Diesel-Water Emulsion fuel is able to apply commercial diesel engine without any replacement of equipments. This research analyzed applicable possibility of Diesel-Water Emulsion fuels to commercial diesel engine's fuel injection system refering injection and spray characteristics. In this research, there are 3 experiments, that is injection quantity, spray visualization, and injection rate. Diesel-Water Emulsion fuel has less injection quantities compared to diesel fuel, and spray penetration length is more longer than diesel. Furthermore, emulsion fuels have less dispersed than diesel fuel. In conclusion, comparing with diesel fuel with only spray characteristics, Diesel-Water Emulsion fuel has bad effects about dispersion and vaporization.

• Journal of the Korean Professional Engineers Association
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• v.45 no.6
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• pp.20-27
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• 2012

World has become interested in the development of new dean energy because of oil prices rise and global warming due to carbon dioxide emissions. This study evaluated the safety of the refueling infrastructure for hydrogen, CNG and HCNG(hydrogen blended natural gas) which recently take center stage as a clean fuel. The risk of fuel was evaluated by 3D computational fluid dynamics program for gas dispersion and explosion. Hydrogen is higher than the CNG explosion overpressure and shows rapid spread. On the other hand, CNG and 30% HCNG showed quite similar characteristics. HCNG slightly rises in risk than the CNG, but HCNG is safe compared to hydrogen.

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1577-1582
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• 2010

A 20 wt % Pt/C is fabricated and characterized for use as the cathode catalyst in a polymer electrolyte membrane fuel cell (PEMFC). By using the polyol method, the fabrication process is optimized by modifying the carbon addition sequence and precursor mixing conditions. The crystallographic structure, particle size, dispersion, and activity toward oxygen reduction of the as-prepared catalysts are compared with those of commercial Pt/C catalysts. The most effective catalyst is obtained by ultrasonic treatment of ethylene glycol-carbon mixture and immediate mixing of this mixture with a Pt precursor at the beginning of the synthesis. The catalyst exhibits very uniform particle size distribution without agglomeration. The mass activities of the as-prepared catalyst are 13.4 mA/$mg_{Pt}$ and 51.0 mA/$mg_{Pt}$ at 0.9 V and 0.85 V, respectively, which are about 1.7 times higher than those of commercial catalysts.

• Journal of the Korean Society of Safety
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• v.37 no.2
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• pp.1-9
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• 2022

Most factories deal with toxic or flammable chemicals in their industrial processes. These hazardous substances pose a risk of leakage due to accidents, such as fire and explosion. In the event of chemical release, massive casualties and property damage can result; hence, quantitative risk prediction and assessment are necessary. Several methods are available for evaluating chemical dispersion in the atmosphere, and most analyses are considered neutral in dispersion models and under far-field wind condition. The foregoing assumption renders a model valid only after a considerable time has elapsed from the moment chemicals are released or dispersed from a source. Hence, an initial dispersion model is required to assess risk quantitatively and predict the extent of damage because the most dangerous locations are those near a leak source. In this study, the dispersion model for initial consequence analysis was developed with three-dimensional unsteady advective diffusion equation. In this expression, instantaneous leakage is assumed as a puff, and wind velocity is considered as a coordinate transform in the solution. To minimize the buoyant force, ethane is used as leaked fuel, and two different diffusion coefficients are introduced. The calculated concentration field with a molecular diffusion coefficient shows a moving circular iso-line in the horizontal plane. The maximum concentration decreases as time progresses and distance increases. In the case of using a coefficient for turbulent diffusion, the dispersion along the wind velocity direction is enhanced, and an elliptic iso-contour line is found. The result yielded by a widely used commercial program, ALOHA, was compared with the end point of the lower explosion limit. In the future, we plan to build a more accurate and general initial risk assessment model by considering the turbulence diffusion and buoyancy effect on dispersion.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.11
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• pp.1552-1560
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• 2001

This paper presents the experimental results of a study undertaken to develop an electrostatic spray system for a combustion application. The characteristics of the liquid atomization and the droplet dispersion in the electrostatic spray of twin fluids were investigated by the optical measurement techniques. The processes associated with the break-up of charged jets were also observed using the laser sheet visualization. The diameter and velocity of droplets were simultaneously measured using the phase Doppler measurement technique. The electrostatic atomization of the liquid fuel depended primarily on the charging voltage and the flow rate, but the dispersion of droplets depended significantly on the aerodynamic flow. Aerodynamic influences on the liquid atomization decreased with an increase of the charging voltage. Consequently, the liquid atomization and the droplet dispersion could be independently controlled using the electrostatic and aerodynamic mechanisms.

• Journal of computational fluids engineering
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• v.5 no.3
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• pp.1-7
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• 2000

In high-pressure diesel engine, the injected fuel spray impinges on the piston cavity surface due to the short distance between the injection nozzle and the cavity wall. The behavior of the impinging spray has the great influence on the dispersion of fuel, the evaporation, and the mixture formation process. In this study, the numerical simulation using the GTT code was performed to study the gas flows, the spray behaviors, and the fuel vapor distributions in the combustion of a D.I engine for variation of spray angle and swirl ratio.

• Journal of the Korean Electrochemical Society
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• v.11 no.4
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• pp.262-267
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• 2008

Effective dispersion of noble metal Pt-Ru catalysts was conducted for the application of direct formic acid fuel cell(DFAFC) electrodes by electrospray method. The amount of catalysts deposited on the electrodes increased with increasing deposition time. However, the performance of cell test decreased with the deposition time after 80 min. because of agglomeration of catalysts. With the conventional hand-spray method, the density of the anode catalysts deposited was $3.0\;mg/cm^2$ and the maximum power density of the MEA was $74\;mW/cm^2$. On the other hand, the MEA prepared by the electrospray method, showed a similar power density of $72\;mW/cm^2$. However, the density of the anode catalysts deposited was much lower than the case of the hand-spray and the density the anode catalysts in this case was $1.85\;mg/cm^2$.

• Nuclear Engineering and Technology
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• v.45 no.7
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• pp.827-838
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• 2013

Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to $200^{\circ}C$, and for Mo content in the range of 6 - 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea's KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

• Proceedings of the Korean Nuclear Society Conference
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• 2004.10a
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• pp.891-892
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• 2004