• Title/Summary/Keyword: Dispersion Curves

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Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.

Analysis of solute transport in rivers using a stochastic storage model (확률론적 저장대모형을 이용한 하천에서의 물질혼합거동 해석)

  • Kim, Byunguk;Seo, Il Won;Kwon, Siyoon;Jung, Sung Hyun;Yun, Se Hun
    • Journal of Korea Water Resources Association
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    • v.54 no.5
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    • pp.335-345
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    • 2021
  • The one-dimensional solute transport models have been developed for recent decades to predict behavior and fate of solutes in rivers. Transient storage model (TSM) is the most popular model because of its simple conceptualization to consider the complexity of natural rivers. However, the TSM is highly dependent on its parameters which cannot be directly measured. In addition, the TSM interprets the late-time behavior of concentration curves in the shape of an exponential function, which has been evaluated as not suitable for actual solute behavior in natural rivers. In this study, we suggested a stochastic approach to the solute transport analysis. We delineated the model development and model application to a natural river, and compared the results of the proposed model to those of the TSM. To validate the proposed model, a tracer test was carried out in the 4.85 km reach of Gam Creek, one of the first-order tributaries of Nakdong River, South Korea. As a result of comparing the power-law slope of the tail of breakthrough curves, the simulation results from the stochastic storage model yielded the average error rate of 0.24, which is more accurate than the 14.03 and 1.87 from advection-dispersion model and TSM, respectively. This study demonstrated the appropriateness of the power-law residence time distribution to the hyporheic zone of the Gam Creek.

Genetic Parameters for Litter Size in Pigs Using a Random Regression Model

  • Lukovic, Z.;Uremovic, M.;Konjacic, M.;Uremovic, Z.;Vincek, D.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.2
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    • pp.160-165
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    • 2007
  • Dispersion parameters for the number of piglets born alive were estimated using a repeatability and random regression model. Six sow breeds/lines were included in the analysis: Swedish Landrace, Large White and both crossbred lines between them, German Landrace and their cross with Large White. Fixed part of the model included sow genotype, mating season as month-year interaction, parity and weaning to conception interval as class effects. The age at farrowing was modelled as a quadratic regression nested within parity. The previous lactation length was fitted as a linear regression. Random regressions for parity on Legendre polynomials were included for direct additive genetic, permanent environmental, and common litter environmental effects. Orthogonal Legendre polynomials from the linear to the cubic power were fitted. In the repeatability model estimate of heritability was 0.07, permanent environmental effect as ratio was 0.04, and common litter environmental effect as ratio was 0.01. Estimates of genetic parameters with the random regression model were generally higher than in the repeatability model, except for the common litter environmental effect. Estimates of heritability ranged from 0.06 to 0.10. Permanent environmental effect as a ratio increased along a trajectory from 0.03 to 0.11. Magnitudes of common litter effect were small (around 0.01). The eigenvalues of covariance functions showed that between 7 and 8 % of genetic variability was explained by individual genetic curves of sows. This proportion was mainly covered by linear and quadratic coefficients. Results suggest that the random regression model could be used for genetic analysis of litter size.

A Word Dictionary Structure for the Postprocessing of Hangul Recognition (한글인식 후처리용 단어사전의 기억구조)

  • ;Yoshinao Aoki
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.9
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    • pp.1702-1709
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    • 1994
  • In the postprocessing of Hangul recognition system, the storage structure of contextual information is an important matter for the recognition rate and speed of the entire system. Trie in general is used to represent the context as word dictionary, but the memory space efficiency of the structure is low. Therefore we propose a new structure for word dictionary that has better space efficiency and the equivalent merits of trie. Because Hangul is a compound language, the language can be represented by phonemes or by characters. In the representation by phonemes(P-mode) the retrieval is fast, but the space efficiency is low. In the representation by characters(C-mode) the space efficiency is high, but the retrieval is slow. In this paper the two representation methods are combined to form a hybrid representation(H-mode). At first an optimal level for the combination is selected by two characteristic curves of node utilization and dispersion. Then the input words are represented with trie structure by P-mode from the first to the optimal level, and the rest are represented with sequentially linked list structure by C-mode. The experimental results for the six kinds of word set show that the proposed structure is more efficient. This result is based on the fact that the retrieval for H-mode is as fast as P-mode and the space efficiency is as good as C-mode.

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Tensile Properties and Thermal Stability of Cellulose Nanofibril/Clay Nanocomposites

  • Park, Byung-Dae;Singh, Adya P.;Um, In Chul
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.1
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    • pp.18-24
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    • 2013
  • This work attempted to fabricate organic/inorganic nanocomposite by combining organic cellulose nanofibrils (CNFs), isolated by 2,2,6,6-tetramethylpiperidine-1-oxy radical (TEMPO)-mediated oxidation of native cellulose with inorganic nanoclay. The morphology and dimension of CNFs, and tensile properties and thermal stability of CNF/clay nanocomposites were characterized by transmission electron microscope (TEM), tensile test, and thermogravimetry (TG), respectively. TEM observation showed that CNFs were fibrillated structure with a diameter of about $4.86{\pm}1.341nm$. Tensile strength and modulus of the hybrid nanocomposite decreased as the clay content of the nanocomposite increased, indicating a poor dispersion of CNFs or inefficient stress transfer between the CNFs and clay. The elongation at break increased at 1% clay level and then continuously decreased as the clay content increased, suggesting increased brittleness. Analysis of TG and derivative thermogravimetry (DTG) curves of the nanocomposites identified two thermal degradation peak temperatures ($T_{p1}$ and $T_{p2}$), which suggested thermal decomposition of the nanocomposites to be a two steps-process. We think that $T_{p1}$ values from $219.6^{\circ}C$ to $235^{\circ}C$ resulted from the sodium carboxylate groups in the CNFs, and that $T_{p2}$ values from $267^{\circ}C$ to $273.5^{\circ}C$ were mainly responsible for the thermal decomposition of crystalline cellulose in the nanocomposite. An increase in the clay level of the CNF/clay nanocomposite predominately affected $T_{p2}$ values, which continuously increased as the clay content increased. These results indicate that the addition of clay improved thermal stability of the CNF/clay nanocomposite but at the expense of nanocomposite's tensile properties.

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Fabrication and Sensing Capability of Cholesterol Sensors Based on ZnO Nanofibers (산화아연 나노섬유 기반 콜레스테롤 센서의 제작과 성능)

  • Jo, So Yeon;Kim, Ji Yeong;Kim, Sang Sub
    • Korean Journal of Materials Research
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    • v.23 no.5
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    • pp.281-285
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    • 2013
  • In the present work, ZnO nanofibers were applied to electrode materials for the detection of cholesterol. ZnO nanofibers were synthesized using the electrospinning technique with zinc acetate as a precursor. Electrospinning-synthesized ZnO nanofibers were uniformly distributed by properly controlling the electrospinning parameters. After the calcination treatment, nanofibers of pure ZnO phase were synthesized. Then, these fibers were successfully placed on Au-coated glass substrates by dispersion of ZnO nanofibers in ethanol, dropping, and drying, in sequence. Cholesterol oxidase was then immobilized onto the surface of the ZnO nanofibers. To enhance the immobilization, Nafion was additionally applied. The sensing performances of the fabricated ZnO nanofibers-based sensors were analyzed by cyclic voltammetry in terms of cholesterol concentration ranging from 100 to 400 mg/dl. In the I-V curves, measured by cyclic voltammetry, the ZnO nanofiber-based sensor showed a proportional current behavior with cholesterol concentrations in phosphate buffered saline solution. The sensitivity was measured and found to be $30.7nA/mM{\cdot}cm^2$, which is comparable to the values reported in the literature. After not only optimizing the shape of the ZnO nanofibers but also improving the adhesion nature between the ZnO nanofibers and the Au conducting layer, these fibers can be a good candidate for electrode materials in devices used to detect low concentrations of cholesterol in blood.

Suppression of Harmonic Passband of Bandpass Filters(BPFs) Using Parallel-Coupled Mushroom Structure (평행 결합 Mushroom 구조를 이용한 대역 통과 여파기의 고조파 성분 억제)

  • Lee, Jae-Gon;Lee, Jeong-Hae
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.2 s.117
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    • pp.118-125
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    • 2007
  • Harmonic band of bandpass filter(BPF) is suppressed using coupled mushroom structure. Between double positive (DPS) transmission line such as microstrip and double negative(DNG) transmission line such as one dimensional mushroom structure, strong coupling broadly arises in the cross range of dispersion curves of isolated microstrip and mushroom structure because of complex propagation constant in the cross range. Strong coupling inhibits wave propagation, so that this kind of structure can be utilized as bandstop filter(BSF). This BSF utilizes coupled transmission line instead of coupled resonator, resulting in broad bandwidth(>30 %), shan-rejection, and high rejection level. The strong coupling between DPS and DNG transmissionline makes it possible shorten coupling length, resulting in compact size. In this paper, parallel coupled BSF having center frequency of 4 GHz and 3 dB fractional bandwidth of 40 % is designed and utilized to suppressed spurious mode of two bandpass filters.

A Study on the Estimation of Average Service Life for New Technology Products-in Case of Solor-cell (신기술 제품의 ASL 추정-솔라셀 사례 중심으로)

  • Cho, Jin-Hyung;Lee, S.J.;Oh, H.S.;Baek, S.S.;Kim, O.J.;Kim, B.K.;Jeong, K.S.;Park, S.H.;Kwon, D.C.;Ko, J.H.;Ryu, J.H.;Shim, S.C.
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.37 no.4
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    • pp.106-115
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    • 2014
  • Until now, because a new product (or facility) launched in market has been retired from one year of age, we can have had ASL by stub-curve method by Iowa curve. Recently, many innovative products with important role in market like display and solar-cell etc. are more durable and, what are better, they have the constant variance in ASL because of their good quality. Of course, there are some ones like smart mobile phone with relatively big dispersion in ASL. Estimating ASL of products like display and solar-cell etc., the new approach is needed. In this paper a new method applied traditional Iowa curve with accelerated reliability test (indoor/outdoor) etc. is proposed.

Identification of Guided-Wave Modes in Pipings of Power Plants by using Air-coupled Transducer (Air-coupled 트런스듀서를 이용한 발전설비 배관에서의 유도초음파 모드 규명)

  • Park, Ik-Keun;Kim, Hyun-Mook;Kim, Yong-Kwon;Song, Won-Joon;Cho, Yong-Sang;Jhang, Kyung-Young;Cho, Youn-Ho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.4
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    • pp.341-347
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    • 2004
  • In order to inspect the piping effectively, one of the important components in the facility of power plants, the ultrasonic guided wave was generated by a tomb transducer and was received in a non-contact fashion by using an air-coupled transducer. The guided wave modes that ran be generated by the comb transducer in piping are predicted from the theoretical dispersion curves and the element spacing of a comb transducer. Moreover, to receive the specific modes, the receiving angle of the air-coupled transducer is calculated from Snell's law between the phase velocities of guided waves and the sound velocity of air. The guided wave modes obtained in experiments are identified from the result of time-frequency analysis such as wavelet transform and two-dimensional fast Fourier transform.

Evaluation of Composite Laminates for Aircraft Primary-Structure Applications Using Non-Linear Parameter of Ultrasonic Guided Wave (유도초음파의 비선형 파라미터를 이용한 항공기 구조체의 복합재료 적층판 열화 평가)

  • Cho, Youn-Ho;Kim, Do-Youn;Choi, Heung-Soap;Lee, Joon-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.126-131
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    • 2010
  • The purpose of this study is to assess the condition of composites used in aircraft under varying temperature environment with ultrasound guided wave technique. Investigation of crucial influential factor on the composite health monitoring related to aircraft operational environments such as the number of thermal cycles and temperature deviation between ground level and flight altitude has been of a great concern for aircraft safety issue. In this study, ultrasonic guided wave health monitoring scheme is proposed to evaluate composite specimens damaged with the thermal fatigue simulating aircraft operational condition. Guided wave dispersion curves are used to select right modes which show a promising sensitivity to each different thermal fatigue damage level. The present approach can be also implemented as one of on-lines health monitoring tools for aircraft.