• Title/Summary/Keyword: Disperse dyes

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Elimination of COD and Color of Dye by UV/H2O2, UV/TiO2 System (UV/H2O2, UV/TiO2 시스템에서 염료의 색도 및 COD 제거)

  • Kim, Kei-Woul;Park, Joung Mi;Sim, Su-Jin;Yee, Hi-Joung;Rhee, Dong Seok
    • Journal of Industrial Technology
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    • v.20 no.A
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    • pp.51-56
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    • 2000
  • The Photocatalytic decolorization and degradation of commercial dyes were studied using a batch reactor. Degussa P25 titanium dioxide and $H_2O_2$ were used as the photocatalyst and proved to be effective for dyes degradation when they were irradiated with UV light. The light source was a 20W low pressure mercury lamp. Three different kinds of dyes, such as direct dye(congo red), acid dye (acid black) and disperse dye(disperse blue) were tested. Extending the UV only treatment up to 120min, direct dye was decolorized to 60% and degraded to 30% as COD. On the other side, acid and disperse dyes were eliminated less than 10% as color and COD. But, color and COD were eliminated about 90% for all of the three dyes by $UV/H_2O_2$ system. And then the most effective decolorization was done for direct dye with 96% removal efficiency by $UV/TiO_2$ system at 120min with 500mg/L of $TiO_2$.

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A Study on Dyeing Properties of Self Moisture Control Knitted Fabric (수분 반응형 자기조절 섬유의 복합조직 편물에 대한 염색성 고찰)

  • Kim, Eun-Mi;Noh, Yong-Hwan;Yang, Gwang-Ung;Choi, Jae-Hong
    • Textile Coloration and Finishing
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    • v.26 no.2
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    • pp.79-87
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    • 2014
  • Dyeing fabric weaved with two or more kinds of fiber in different section has various dyeing interactions caused by different material properties of them. Newly developed knit fabric was used in this study. It composited by two different blocks, each block is included PET fiber and CDP fiber separately. Build-up properties with cation dyes and disperse dyes were good having average 83% of dyeing exhaustion yield on 5% o.w.f. dye concentration. As depending on dyeing methods, there were not showed direct interaction between cation dyes and disperse dyes. This result could be considered their different dyeing mechanism. Compatibility was best in S-type disperse dyes investigated their critical absorption range as $120^{\circ}C{\sim}130^{\circ}C$. Wash fastness was generally good in most dye.

A Study on Dyes Solubility of Dry cleaning Solvents (드리아 클리닝 용제에 대한 염료의 용해성)

  • Cha, Ok-Sun;Shin, Jung-Sook
    • Textile Coloration and Finishing
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    • v.2 no.3
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    • pp.43-50
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    • 1990
  • The purpose of this paper is to investigate the dyes solubility of dry cleaning solvents among the current domestic products. The dyes were experimented in following way; 1) The flow rate of dyes by paper chromatography method. 2) The color difference & the absorbance of solvents between the dyed fabrics before and after dry cleaning. From the experiment, following results were obtained. 1. In paper chromatography methods, the flow rate of dyes in the disperse dyes was bigger while flow was not shown in the direct dyes & acid dyes. 2. The more the number of times on dry cleaning in dyed fabrics was, the higher the absorbance of solvents was shown. The results were showed following order, PerchloroethyleneHydrocarbon> Fluorocabon. 3. The color difference between before & after dry cleaning on dyed fabrics showed bigger in disperse dyes.

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Dyeing Properties of Blanket Fabric of Dyeable Polypropylene

  • Kim, Hyun-Jin;Lee, Jin-Ah;Chang, Young-Min;Park, Jong-Ho;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.36-43
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    • 2007
  • Dyeing and fastness properties of a dyeable PP fiber were examined with four different types of disperse dyes. It was found that the dyed PP fiber could be cleared by soaping without using sodium hydrosulphite, and that the heat setting above $140^{\circ}C$ resulted in the melting of the PP fiber. The rates of dyeing and the extents of exhaustion of three primary E type dyes were different with each other, the apparent color strength did not increase with increasing dye concentration, and color fastness to washing was not satisfactory. In the cases of both high wash fastness and high light fastness dyes, the rates of dyeing were slow and the extents of exhaustion were very low. On the other hand, the dyeing rates of three primary S type dyes were similar and the build-up properties were good with good color fastnesses. It might be concluded that the best disperse dyes for the dyeable PP fiber were S type dyes.

The Application of Disperse Dyes to the Ultra Low Liquor Ratio Dyeing System (초저욕비 염색을 위한 분산염료의 적용연구)

  • Kim, Tae-Gyeong;Kim, Jin-Su;Park, Hui-Mun;Nam, Chang-U
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.192-194
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    • 2008
  • The study has focused on the dyeing properties of 4 kinds of high temperature type mono azo disperse dyes, widely used in the dyeing factory, under the ultra low liqour ratio (1:4) dyeing condition. Among those, C.I. Disperse Red 343 and C.I. Disperse Blue 79 showed un-levelled dyeing results from the ultra low liquor ratio dyeing bath as well as poor dispersion stability under the high temperature. We recommended some leveling agents to improve the leveling behavior of these dyes mentioned above. The milling technology should be further developed to achieve the dispersion stability.

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Dyeing Properties of Polyester Ultrarmicrofiber (초극세 폴리에스테르 섬유의 염색성)

  • 정동석;김호정;이문철
    • Textile Coloration and Finishing
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    • v.11 no.3
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    • pp.1-8
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    • 1999
  • Polyester ultrarmcrofiber(UMF, fiber fineness : 0.05d) and the other three kinds of polyester fibers(0.52, 1.04 and 2.08d) were dyed with two disperse dyes, C.1. Disperse Red 60 and Blue 56. Dyeing rates and absorption isotherms of these dyes have been measured at 100, 115 and $130^\circ{C}$ in water system. The dye bath was maintained at pH 5.0 with acetic acid(0.1mo1/1) /sodium acetate(0.1mo1/1) buffers and a liquor ratio of 1000:1. The absorption isotherms from two disperse dyes are nearly linear up to the saturation values, which increase with the temperature of dyeing. Dye uptake decreased with the fiber fineness in lower temperature $100^\circ{C})$, whereas increased in higher temperature$(130^\circ{C})$. A comparatively greater quantity of dye is necessary to dye ultrarmcrofiber fabrics than conventional fabrics. Disperse Blue 56 having a good build-up property is agreed to Fothergill's equation, which is inversely varied with the fiber fineness by the quantity of dye necessary to obtain a given shade.

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Dyeing Properties of Polyurethane Fiber by Novel Phthalimidyl Azo Disperse Dyes (Phthalimide계 신규 Azo dye의 Polyurethane계 섬유 염색 특성)

  • Choi, Jong-Yun;Choi, Jae-Hong
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.46-55
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    • 2009
  • Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di($\beta$-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at $120^{\circ}C$ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

Dyeing of Cotton and Polyester/Cotton Blend with Disperse Dyes Using Sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate

  • Kim, Mi-Kyung;Yoon, Seok-Han;Kim, Tae-Kyeong;Bae, Jin-Seok;Yoon, Nam-Sik
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.352-357
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    • 2006
  • The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino) benzenesulfonate (DBDCBS) at alkaline condition ofroom temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow 9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel hetero-bifunctional bridge compound, DBDCBS, has two reactive groups such as dichloro-striazinyl group and ${\alpha},\;{\beta}$-dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared. The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton blend by one kind of disperse dye was achieved.

On Bath Dyeing of silk/synthetic Fibre Blends(III) ―Adsorption Behavior of Acid Dyes/Disperse Dyes on Silk/PET― (견/합성섬유 혼방품의 일욕염색(III) ―산성염료/분산염료 염욕에서의 견/PET의 염착거동―)

  • Gwag, In Jun;Yoon, Kyung Sup;Kim, Ae Soon;Kim, Gong Ju
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.67-78
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    • 1993
  • In one bath dyeing system of silk/PET fiber blend fabric with acid/disperse dyes, adsorption behavior of disperse dyes and acid dyes on silk and PET fabrics were examined. In the dyeing of PET with C.I.Disperse Red 19(Red 19) and C.I.Disperse Red 60(Red 60) at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake with Red 60 was higher than that with Red 19. When the silk/PET dyed with Red 19 and Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake on PET was influenced by affinity of the dye to the silk fabric dyed together. When the silk/PET dyed with Blue 80/Red 19 and Blue 80/Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$ for 60 minutes, color of PET dyed with Red 19 and Red 60 was little influenced by Blue 80 but silk dyed with Blue 80 was influenced. Interrelation of K/S value and Munsell value was scarcely any but showed the change tendency of K/S value.

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The Disperse Dyeing of Polyester/Cotton Blend Using a Hetero-bifunctional Bridge Compound(II) (이반응형 브릿지 화합물을 이용한 폴리에스테르/면 복합소재의 단일분산염료 일욕염색(II))

  • Kim, Mi-Kyung;Yoon, Seok-Han;Kim, Tae-Kyeong;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.19 no.1 s.92
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    • pp.1-11
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    • 2007
  • Dyeing of polyester/cotton blends is usually carried out through the two-bath or one-bath two-step dyeing method using proper disperse dyes and reactive dyes for each fiber. However, the dyeing requires relatively long and complicated procedure as well as there are some problems such as lower dyeability. In the present study, new one-bath one-step dyeing process was investigated using disperse dyes having amino groups and hetero-bifunctional bridge compound(DBDCBS) including dichloro-s-triazinyl groups and ${\alpha},{\beta}$-dibromopropionylamido groups to improve the dyeability of cotton component in polyester/cotton blends. And the one-bath dyeing properties of polyester/cotton blends was evaluated by various dyeing conditions such as pH, temperature and dye concentration, The optimum dyeing condition was pH 4 and $110-120^{\circ}C$. Color fastness were relatively good because of the colvalent bond formation between DBDCBS-reacted cotton fiber and disperse dye.