• 제목/요약/키워드: Disperse

검색결과 648건 처리시간 0.033초

Synthesis of Red Disperse Dyes with Various Diazo Components and Coloration of Unmodified Pure Polypropylene Fibers

  • Kim, Tae-Kyeong;Jang, Kyung-Jin;Jeon, Seon-Hee
    • 한국염색가공학회지
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    • 제22권1호
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    • pp.1-7
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    • 2010
  • The five new red disperse dyes for unmodified pure polypropylene fibers were synthesized. As a coupling component, a di-n-hexyl substituent was used in common, while various substituents were used for the diazo component. The dye having electron donating group at diazo component showed hypsochromic shift compared to the unsubstituted dye, while the dyes having electron withdrawing groups showed bathochromic shift. Owing to their extreme hydrophobicity caused by the di-n-hexyl substituent, all dyes exhibited very high affinity toward pure polypropylene fibers. Fastness to washing was very good for all dyes and fastness to light was good except two purplish red dyes.

Phthalimide계 신규 Azo dye의 Polyurethane계 섬유 염색 특성 (Dyeing Properties of Polyurethane Fiber by Novel Phthalimidyl Azo Disperse Dyes)

  • 최종윤;최재홍
    • 한국염색가공학회지
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    • 제21권6호
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    • pp.46-55
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    • 2009
  • Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di($\beta$-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at $120^{\circ}C$ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

Coloration of Poly(lactic acid) with Disperse Dyes. 1. Comparison to Poly(ethylene terephthalate) of Dyeability, Shade and Fastness

  • Choi Jae-Hong;Seo Woon-Young
    • Fibers and Polymers
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    • 제7권3호
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    • pp.270-275
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    • 2006
  • The dyeability of poly(lactic acid) [PLA] with a range of commercial disperse dye was examined and compared to that of poly(ethylene terephthalate) [PET] in addition to the colour and fastness of the resultant dyeings. A screening exercise in which twenty dyes of differing energy types and chemical classes were applied to PLA revealed a substantial variation between the dyes in terms of dye uptake (12-88 % at 4 % o.w.f.). Nine dyes exhausted above 70 % and were selected for further study, which involved comparison of shade and fastness of PLA dyeings with those of the corresponding PET dyeings. Differences in shade depended on hue while wet fastness of each of the PLA dyeings was either the same or 0.5-1.0 point lower than its PET counterpart. In all but one case, dye photostability in PLA was found to be very similar to that in PET. Dye build-up profiles on PLA were also investigated and from these results mixtures of compatible dyes identified.

Synthesis of Temporarily Solubilized Reactive Disperse Dyes and Their Application to the Polyester/Cotton Blend Fabric

  • Lee, Jung-Jin;Han, Nam-Keun;Lee, Won-Jae;Park, Jae-Hong;Kim, Jae-Pil
    • Fibers and Polymers
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    • 제3권3호
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    • pp.85-90
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    • 2002
  • Five temporarily solubilized reactive disperse dyes were synthesized and characterized. They were applied to polyester/cotton blend fabric using one-bath dyeing method without dispersing agent. The dye that has azonaphthalene chro-mophore seemed to not only be exhausted on polyester but also react with cotton. But other dyes were selectively dyed on polyester and showed limited uptake on cotton. Good levelling as well as moderate to good colour fastness was obtained with the dyes on P/C blend fabric.

Disperse diazo black D(DBD) photopolymer의 박막 제작과 이의 물리적 특성에 관한 연구 (A manufacture of disperse diaso black D(DBD) photopolymer thin films and its Physical Properties)

  • 정용환;이호식;변대현;김태완
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1333-1335
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    • 1997
  • We have made disperse diazo black D(DBD) thin films using Langmuir-Blodgett(LB) and vacuum-evaporation technique. Physical and optical properties of the films were investigated. Solution was made with a concentration of $10^{-3}mol/{\ell}$ using chloroform. Moving wall apparatus, (NL-LB140S-MWC) was employed to make the LB films. X,Y and Z-type LB films were manufactured and studied UV/visible absorbance spectra and morphology of surface using atomic force microscopy(AFM). Vacuum-evaporated DB D thin films were made at a pressure of $10^{-5}$ torr. The absorption peaks were observed at 200 and 400 nm in the LB films and vacuum-deposited films. We have also studied photoluminescence spectrum of the DBD films.

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MSPD 방법에 의한 돈육중 Carbadox와 Olaquindox 분석법 연구 (A study on determination of carbadox and olaquindox in swine tissues by matrix solid Phase disperse method")

  • 황래홍;김영수;김기근
    • 한국동물위생학회지
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    • 제19권2호
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    • pp.163-171
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    • 1996
  • This study was carried out to determination of carbadox and olaquindox residues in swine tissues by MSPD(matrix solid phase disperse)method. The results obtained were as follows ; 1. Optimal wavelengths of UV for carbadox and olaquindox were 310 and 370nm, respectively 2. Ethyl acetate-Acetonitrile(8:2) was found to be adequate as extractant in this method. 3. The average overall recovery of carbadox at the 0.01, 0.05, and 1.0PPM spike levels was 89. 2% and that of olaquindox was 89.9%, and the detection limits were 0.5ng for carbadox and olaquindox.

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Disperse diazo black D(DB-D) photopolymer의 초박막 제작과 이의 물성 및 전기적 특성 연구 (A manufacture of disperse diazo black D(DB-D) photopolymer ultrathin films and its physical and electrical properties[1])

  • 정용환;김태완;변대현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.493-496
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    • 1997
  • We have made disperse diazo black D(DB-D) ultrathin films using Langmur-Blodgett(LB) and vacuum-evaporation technique. Physical and electrical properties of the films were investigated. Solution was made with a concentration of 10$^{-3}$ mol/$\ell$ using chloroform. Moving wall apparatus (NL-LB140 S-MWC) was employed to make the LB films. X,Y and Z-type LB films were manufactured and studied by UV/visible absorbance spectra and morphology of surface using atomic force microscopy. Vacuum-evaporated DB-D think films were made at a pressure of 10$^{-5}$ torrr. The absorption peaks appear at 200 and 40nm in the LB films and vacuum-deposited films. And we have studied photoluminescence spectrum of the DB-D films. Also TGA and DSC properties of the DB-D have been observed and current -voltage characteristics of the DB-D LB films have been measured along the perpendicular direction.

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환원세정방법에 따른 스웨드 직물의 세탁견뢰도 (Washing Fastness of Polyester Artificial Suede Fabric According to Reduction Clearing Method)

  • 강연희;백진주;서말용;김삼수;허만우;이난형
    • 한국염색가공학회지
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    • 제13권4호
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    • pp.234-240
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    • 2001
  • In order to improve the washing fastness of dyed polyester artificial suede fabric, it was dyed by using auto and anthraguinone type disperse dyes and treated with 3 different reduction clearing methods. The reduction clearing methods used in this study were normal alkaline reduction clearing, $N_2$ gas replacement method, and ultrasonic treatment during normal reduction clearing. The results were as followings ; The washing fastness property of dyed polyester artificial suede fabric was slightly improved by reduction clearing with $N_2$ gas replacement or with ultrasonic treatment comparing with normal alkaline reduction clearing. It was found that the use of $N_2$ gas replacement or ultrasonic treatment during reduction clearing eave effective removal of unfixed dyes on the fiber surface. We also obtained that the azo type disperse dye on polyester artificial fabric suede fabric showed higher wash fastness than anthraquinone type disperse dye.

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Development of a Disperse Dye Immunoassay Technique for Detection of Antibodies against Neospora caninum in Cattle

  • Selahi, Fatemeh;Namavari, Mehdi;Hosseini, Mohammad Hossein;Mansourian, Maryam;Tahamtan, Yahya
    • Parasites, Hosts and Diseases
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    • 제51권1호
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    • pp.129-132
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    • 2013
  • In this study a disperse dye immunoassay method was standardized and evaluated for detection of antibodies against Neospora caninum in cattle. Sera from 150 cattle with a recent history of abortion were collected and tested by commercial ELISA kit and a standardized in-house dye immunoassay system. The positivity rate for the sera used in this study was 34.6% for the disperse dye immunoassay (DDIA) compared to 32% obtained by ELISA kit. This study showed no significant difference between DDIA and ELISA. The results indicated that the DDIA provide an economic, simple, rapid and robust test for detection of N. caninum infection in cattle.

분산염료에 의한 Poly(trimethylene terephthalate) 섬유의 염색거동의 해석 (The Interpretation of Dyeing Behavior of Poly(trimethylene terephthalate) Fiber with a Disperse Dye)

  • 윤석한;김태경;임용진;조규민
    • 한국염색가공학회지
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    • 제13권4호
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    • pp.249-255
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    • 2001
  • To interpret the dyeing behavior of PTT fiber with C. I. Disperse Violet 1, the thermodynamic Parameters of dyeing, such as standard affinity, heat of dyeing(enthalpy change), entropy change, diffusion coefficient, and activation energy of diffusion, were obtained from isotherms and dyeing rates at various temperatures and compared with those of PET fiber. The heat of dyeing(enthalpy change) and the entropy change of PTT fiber showed smaller negative values than those of PET fiber. This means that the dye molecules in the PTT fiber are combined more loosely than in the PET fiber and that is due to the flexibility of polymer chains of PTT fiber. The diffusion coefficients of C. I. Disperse Violet 1 into the PTT fiber were larger than those for PET fiber, and the activation energy of diffusion on PTT fiber was smaller than that on PET fiber.

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