• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.415-420
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• 2016

To enhance electrochemical performances of anode materials, the surface of coal tar pitch (CTP) was modified by incorporating heteroatoms through chemical treatment with phosphoric acid ($H_3PO_4$). The prepared anode materials with modified CTP was analyzed by XRD, FE-SEM and XPS. The electrochemical performances of modified CTP were investigated by constant current charge/discharge test, rate performance, cyclic voltammetry and impedance tests using the electrolyte of $LiPF_6$ dissolved in the mixed organic solvents (ethylene carbonate : dimethyl carbonate = 1 : 1 vol% + vinylene carbonate 3 wt%). The coin cell using modified CTP ($H_3PO_4/CTP$ = 3 : 100 in weight) has better initial capacity and initial efficiency (489 mAh/g, 82%) than those of other composition coin cells. Also, it was found that the capacity retention was 86% after 30 cycles and the rate capability was 87% at 2 C/0.1 C.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.459-464
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• 2016

In this study, the electrochemical characteristics of porous silicon/carbon composite anode were investigated to improve the cycle stability and rate performance in lithium ion batteries. In this study, the effect of TEOS and $NH_3$ concentration, mixing speed and temperature on particle size of nano silica was investigated using $St{\ddot{o}}ber$ method. Nano porous Si/C composites were prepared by the fabrication processes including the synthesis of nano $SiO_2$, magnesiothermic reduction of nano $SiO_2$ to obtain nano porous Si by HCl etching, and carbonization of phenolic resin. Also the electrochemical performances of nano porous Si/C composites as the anode were performed by constant current charge/discharge test, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1vol%). It is found that the coin cell using nano porous Si/C composite has the capacity of 2,006 mAh/g and the capacity retention ratio was 55.4% after 40 cycle.

• Polymer(Korea)
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• v.35 no.6
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• pp.586-592
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• 2011

In this study, we synthesized vinylbenzyl chloride-co-styrene-co hydroxyethyl acrylate (VBC-co-St-co-HEA) copolymer that can be applied to redox the flow battery process. The anion exchange membrane was prepared by the amination and crosslinking of VBC-co-St-co-HEA copolymer. The chemical structure and thermal properties of VBC-co-St-co-HEA copolymer and aminated VBC-co-St-co-HEA(AVSH) membrane were characterized by FTIR, $^1H$ NMR, TGA, and GPC analysis. The membrane properties such as ion exchange capacity(IEC), electrical resistance, ion conductivity and efficiency of all-vanadium redox flow battery were measured. The IEC value, electrical resistance, and ion conductivity were 1.17 meq/g, $1.9{\Omega}{\cdot}cm^2$, 0.009 S/cm, respectively. The charge-discharge efficiency, voltage efficiency and energy efficiency from all-vanadium redox flow battery test were 99.5, 72.6 and 72.1%, respectively.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.16 no.2
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• pp.7-12
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• 2020

The battery of an electric vehicle is a key part of the energy supply to operate the vehicles. There are many factors affecting battery life such as charging method, discharge rate, and ambient temperature those are requires systematic monitoring and management. To solve the issues like environmental problems and fuel consumption reduction the battery needs more performance improvement. In this study, it was analyzed the thermal characteristics and securing battery stability for electric vehicle battery cooling system. The simulation test was operated using GT-suite software with several conditions like cooling capacity 1, 2 and 4 kW, cooling flow rate 5, 10, 20 and 30 LPM, and battery initial temperatures 40, 35, and 30℃ at the temperature of ambient 25℃. The results shown that the case of cooling flow rate at 20 LPM was most efficient among all above conditions.

• Aerospace Engineering and Technology
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• v.7 no.2
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• pp.110-116
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• 2008

This paper gives a brief summary of the TVC battery design description, specifications and test results. The TVC battery for KSLV-I upper stage contains 168 Sony l8650VT high power lithium-ion cells. It configured as 2 strings in parallel, with each string containing 84 series connected cells. This allows to meet nominal 270V voltage and capacity requirements specified for the mission of the Thrust Vector Control(TVC) system. The loads profile of the TVC system has short duration, high current pulse. To power such a system with minimal mass, the battery employed l8650VT Cells. This cell is specifically designed for high rate applications and is capable of a 10C continuous discharge.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 1998.10a
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• pp.376-381
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• 1998

The large scaled field test by prefabricated vertical drains was performed to evaluate the superiority of vertical discharge capacity for drain materials through compare and analyze the time-settlement behavior with drain spacing and the compression index and consolidation coefficient obtained by laboratory experiments and field monitoring system 1. The relation of measurement settlement( $S_{m}$) versus design settlement( $S_{t}$) and measurement consolidation ratio( $U_{m}$) versus design consolidation ratio( $U_{t}$) were shown $S_{m}$=(1.0~l.1) $S_{t}$, $U_{m}$=(1.13~l.17) $U_{t}$, at 1.0m drain spacing and $S_{m}$=(0.7~0.8) $S_{t}$, $U_{m}$=(0.92~0.99) $U_{t}$ at 1.5m drain spacing, respectively. 2. The relation of field compression index( $C_{cfield}$) and virgin compression index( $V_{cclab}$) was shown $C_{cfield}$=(1.0~1.2) $V_{cclab}$, But it was nearly same value when considered the error with determination method of virgin compression index and prediction method of total settlement. 3. field consolidation coefficient was larger than laboratory consolidation coefficient, and the consolidation coefficient ratio( $C_{h}$/ $C_{v}$) were $C_{h}$=(2.4 ~ 3.0) $C_{v}$. $C_{h}$=(3.5 ~ 4.3) $C_{v}$ at 1.0m and 1.5m drain spacing and increased with increasing of drain spacingngasing of drain spacingng spacingng

• Journal of Electrochemical Science and Technology
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• v.5 no.4
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• pp.95-104
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• 2014

Electrochemical performance of Li-ion cells with $LiMn_2O_4$ cathodes and graphite anodes with carbonates electrolytes containing quaternary ammonium-based room temperature ionic liquids (ILs) is investigated. Eight different ILs based on tetraalkylammonium, pyrrolidinium or piperidinium cations paired with bis(trifluoromethylsulfonyl)imide or tris(pentafluoroethyl)trifluorophosphate anions are examined in combination with dimethyl carbonate as a main solvent and fluoroethylene carbonate as a solid electrolyte interface forming agent. It is shown that cycling properties of the cells are strongly affected by the content of ILs in the electrolyte mixtures and its increase corresponds to lower discharge capacity retention. Since viscosity and conductivity of ILs are of a great importance for the electrolytes formulation, some kind of combined parameter should be used for the assessment of IL applicability and calculated values of Walden products for neat ILs represent one of the possible options. Besides, positive effect of ILs on reduction of flammability and enhancement of thermal stability of electrolytes in contact with charged electrodes have been demonstrated by means of self-extinguishing time test and differential scanning calorimetry respectively.

• The Journal of Korean Physical Therapy
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• v.16 no.3
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• pp.142-151
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• 2004

The purpose of this study was to determine the validity and the reliability of the WISCI II to ascertain its value in the walking function evaluation of spinal cord injury patient. The WISCI II consists of 20 variables with a total valus ranging from 6 to 20 score. A group of 23 spinal cord injury patient were included in this study. To determine the validity, kappa statistics between the WISCI II and SCIM II were measured. The result of this study are as follows: 1) In the validity study, the kappa statistics between the WISCI II and SCIM II were 0.79 and 0.84 for an initial total score and a discharge total score respectively, indicating a reasonable agreement between the two test. 2) In the reliability study, the Cronbach's alpha coefficient was 0.83 and 0.95 for total score indicating a good internal consistency. The finding suggest that the WISCI II demonstrated an acceptable validity and reliabilit for the evaluation of walking function capacity of spinal cord injury patient in clinical practice.

• Proceedings of the Korean Geotechical Society Conference
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• 2001.10a
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• pp.147-158
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• 2001

In general, two methods have been used to predict settlement of soft ground. One method is Terzaghi's one dimensional consolidation theory which gives time-settlement relationship using the standard consolidation test results. The other is forecasting method of ground settlement to be occured in the future using in-situ monitoring data. The above both methods have some defects in application manner or in itself especially in very deep and soft clayey ground. In view of the lessons and experiences of soft ground improvement projects, several techniques were proposed for more accurate theorectical calculation of consolidation settlement as follows ; ① Subdivision of soft ground, ② Consideration of secondary compression, ③ Using the modified compression index, etc. And also, revised hyperbolic fitting method was suggested to minimize the error of predicted future settlement. In addition, revised De-Beer equation of immediate settlement of loose sandy soil was proposed to overcome the tendency to show too small settlement calculation results by original De-Deer equation. And also, considering the various effects of settlement delay in the improved ground by vertical drains, time-settlement caculation equation(Onoue method) was revised to match the tendency of settlement delay by using the characteristics of discharge capacity decreases of vertical drain with time elapse by the pattern of hyperbolic equation.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.5
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• pp.558-566
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• 2007

The performance characteristics of water-chilling heat pump using $CO_2$ with respect to variation of refrigerant charge amount was investigated experimentally. An experimental apparatus is consisted of a compressor, a gas cooler, an expansion valve, an evaporator and a liquid receiver. All heat exchangers used in the test rig are counter-flow-type heat exchangers with concentric dual tubes, which are made of copper. The gas cooler and the evaporator consist of 6 and 4 straight sections respectively arranged in parallel, each has 2400 mm length. The experimental results summarize as the followings : As the refrigerant charge ratio of $CO_2$ heat pump system increases, the discharge pressure and compressor ratio increases, but mass flow rate of refrigerant decreases. Also the compressor work increases with the increase of refrigerant charge ratio. However, the heating and cooling capacity of $CO_2$ heat pump decreases as the refrigerant charge ratio increases. The maximum heating COP of $CO_2$ heat pump system presented at 0.25 refrigerant charge ratio. It is possible to confirm the optimum charge ratio of $CO_2$ heat pump system by the viewpoint of heating COP.