• Title/Summary/Keyword: Direct decomposition

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Formation of copper films from copper formate by laser-induced pyrolytic decomposition (Copper formate의 레이저 유도 열 분해에 의한 Cu 박막의 제조)

  • Kim, Jae-Kwon;Park, Se-Ki;Lee, Cheon
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1444-1446
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    • 1998
  • Direct writing of copper lines has been achieved by pyrolytic decomposition of copper formate films using a focused argon ion laser beam($\lambda$ =514.5nm) on a glass. The thickness and linewidth of the deposited copper films were considered as a function of laser power and scan speed. As the result from AES, there are no other elements except for copper after decomposition in the atmospheric ambient.

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Estimation of displacement responses of a suspension bridge by using mode decomposition technique (모드분해기법을 이용한 현수교의 변위응답추정)

  • Chang, Sung-Jin;Kim, Nam-Sik;Kim, Ho-Kyung
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2009.04a
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    • pp.320-325
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    • 2009
  • In this study, a method to estimate the suspension bridge deflection is developed using mode decomposition technique. In order to examine the suspension bridge stability against these dynamic loadings, the prediction of displacement response is very important to evaluate bridge stability. However, it is recognized that any measurement of movement for suspension bridges may be difficult for the absence of proper methods to measure the displacement response on site. This study aims at suggesting a method to estimate the displacement response from the measured strain signals in an indirect way to predict the displacement response, not a direct way to measure the displacement response. Additionally, by applying the FBG sensors with multi-point measurements not influenced by electric noise, it can be expected that the technique would be applicable to infrastructures.

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Singular Value Decomposition Approach to Observability Analysis of GPS/INS

  • Hong, Sin-Pyo;Chun, Ho-Hwan
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.1
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    • pp.133-138
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    • 2006
  • Singular value decomposition (SDV) approach is applied to the observability analysis of GPS/INS in this paper. A measure of observability for a subspace is introduced. It indicates the minimum size of perturbation in the information matrix that makes the subspace unobservable. It is shown that the measure has direct connections with observability of systems, error covariance, and singular structure of the information matrix. The observability measure given in this paper is applicable to the multi-input/multi-output time-varying systems. An example on the observability analysis of GPS/INS is given. The measure of observability is confirmed to be less sensitive to system model perturbation. It is also shown that the estimation error for the vertical component of gyro bias can be considered unobservable for small initial error covariance for a constant velocity horizontal motion.

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Determination of Trace Anions in Concentrated Hydrogen Peroxide by Direct Injection Ion Chromatography with Conductivity Detection after Pt-Catalyzed On-Line Decomposition

  • 김도희;이보경;이동수
    • Bulletin of the Korean Chemical Society
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    • v.20 no.6
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    • pp.696-700
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    • 1999
  • A method has been developed for the determination of trace anion impurities in concentrated hydrogen peroxide. The method involves on-line decomposition of hydrogen peroxide, ion chromatographic separation and subsequent suppressed-type conductivity detection. H2O2 is decomposed in Pt-catalyst filled Gore-Tex membrane tubing and the resulting aqueous solution containing analytes is introduced to the injection valve of an ion chromatograph for periodic determinations. The oxygen gas evolving within the membrane tubing escapes freely through the membrane wall causing no problem in ion chromatographic analysis. Decomposition efficiency is above 99.99% at a flow rate of 0.4mL/min for a 30% hydrogen peroxide concentration. Analytes are quantitatively retained. The analysis results for several brands of commercial hydrogen peroxides are reported.

Development of Methane Decomposition Reactor for Hydrogen Production Using Solar Thermal Energy (수소생산을 위한 태양열 이용 메탄 분해 반응기 개발)

  • Kim, Haneol;Kim, Jongkyu
    • New & Renewable Energy
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    • v.17 no.2
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    • pp.40-49
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    • 2021
  • This paper explains the development process of methane decomposition to hydrogen and carbon black using solar thermal energy. It also demonstrates the advantages and disadvantages of five different reactors for each development stage, including the reactor's experimental results. Starting with the initial direct heating type reactor, the indirect heating type reactor was developed through five modifications. The 40-kWth solar furnace installed at the Korea Institute of Energy Research was used for the experiment. In the experiment using the developed indirect heating reactor, an 89.0% methane to hydrogen conversion rate was achieved at a methane flow rate of 40 L/min, obtained at about twice the flow rate compared to previous advanced studies.

Modal parameter identification with compressed samples by sparse decomposition using the free vibration function as dictionary

  • Kang, Jie;Duan, Zhongdong
    • Smart Structures and Systems
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    • v.25 no.2
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    • pp.123-133
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    • 2020
  • Compressive sensing (CS) is a newly developed data acquisition and processing technique that takes advantage of the sparse structure in signals. Normally signals in their primitive space or format are reconstructed from their compressed measurements for further treatments, such as modal analysis for vibration data. This approach causes problems such as leakage, loss of fidelity, etc., and the computation of reconstruction itself is costly as well. Therefore, it is appealing to directly work on the compressed data without prior reconstruction of the original data. In this paper, a direct approach for modal analysis of damped systems is proposed by decomposing the compressed measurements with an appropriate dictionary. The damped free vibration function is adopted to form atoms in the dictionary for the following sparse decomposition. Compared with the normally used Fourier bases, the damped free vibration function spans a space with both the frequency and damping as the control variables. In order to efficiently search the enormous two-dimension dictionary with frequency and damping as variables, a two-step strategy is implemented combined with the Orthogonal Matching Pursuit (OMP) to determine the optimal atom in the dictionary, which greatly reduces the computation of the sparse decomposition. The performance of the proposed method is demonstrated by a numerical and an experimental example, and advantages of the method are revealed by comparison with another such kind method using POD technique.

Editing Depression Features in Static CAD Models Using Selective Volume Decomposition (선택적 볼륨분해를 이용한 정적 CAD 모델의 함몰특징형상 수정)

  • Woo, Yoon-Hwan;Kang, Sang-Wook
    • Korean Journal of Computational Design and Engineering
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    • v.16 no.3
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    • pp.178-186
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    • 2011
  • Static CAD models are the CAD models that do not have feature information and modeling history. These static models are generated by translating CAD models in a specific CAD system into neutral formats such as STEP and IGES. When a CAD model is translated into a neutral format, its precious feature information such as feature parameters and modeling history is lost. Once the feature information is lost, the advantage of feature based modeling is not valid any longer, and modification for the model is purely dependent on geometric and topological manipulations. However, the capabilities of the existing methods to modify static CAD models are limited, Direct modification methods such as tweaking can only handle the modifications that do not involve topological changes. There was also an approach to modify static CAD model by using volume decomposition. However, this approach was also limited to modifications of protrusion features. To address this problem, we extend the volume decomposition approach to handle not only protrusion features but also depression features in a static CAD model. This method first generates the model that contains the volume of depression feature using the bounding box of a static CAD model. The difference between the model and the bounding box is selectively decomposed into so called the feature volume and the base volume. A modification of depression feature is achieved by manipulating the feature volume of the static CAD model.

Hydorgen Production by Catalytic Decomposition of Propane Over Cabon-Based Catalyst (탄소계 촉매를 이용한 프로판 분해 반응에 의한 수소 생산)

  • Yoon, Suk Hoon;Han, Gi Bo;Lee, Jong Dae;Park, No-Kuk;Ryu, Si Ok;Lee, Tae Jin;Yoon, Ki June;Han, Gui Young
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.668-674
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    • 2005
  • It is reported that a method for the hydrogen production from the propane decomposition using carbon black as a catalyst is more effective than from the methane decomposition. Since the by-products like CO and $CO_2$ are not produced by the direct decomposition of propane, it is considered as an environmentally sustainable process. In this study, hydrogen was produced by the direct decomposition of propane using either commercial activated carbon or carbon black at atmospheric pressure in the temperature range of $500-1,000^{\circ}C$. Resulting products in our experiment were not only hydrogen but also several by-products such as methane, ethylene, ethane, and propylene. Hydrogen yield increased as temperature increased because the amount of those by-products produced in the experiment was inversely proportional to temperature. The achieved hydrogen yield at $750^{\circ}C$ with commercial DCC N330 catalyst was 22.47% in this study.

High Performance Hybrid Direct-Iterative Solution Method for Large Scale Structural Analysis Problems

  • Kim, Min-Ki;Kim, Seung-Jo
    • International Journal of Aeronautical and Space Sciences
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    • v.9 no.2
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    • pp.79-86
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    • 2008
  • High performance direct-iterative hybrid linear solver for large scale finite element problem is developed. Direct solution method is robust but difficult to parallelize, whereas iterative solution method is opposite for direct method. Therefore, combining two solution methods is desired to get both high performance parallel efficiency and numerical robustness for large scale structural analysis problems. Hybrid method mentioned in this paper is based on FETI-DP (Finite Element Tearing and Interconnecting-Dual Primal method) which has good parallel scalability and efficiency. It is suitable for fourth and second order finite element elliptic problems including structural analysis problems. We are using the hybrid concept of theses two solution method categories, combining the multifrontal solver into FETI-DP based iterative solver. Hybrid solver is implemented for our general structural analysis code, IPSAP.

The Analysis of Airborne Trimethylamine Using a Headspace (HS)-SPME Method (헤드스페이스-SPME 방법을 이용한 트리메틸아민의 분석방법 연구)

  • Ahn, Ji-Won;Kim, Ki-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.3
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    • pp.357-366
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    • 2008
  • In this study, the analytical performance of trimethylamine (TMA) were investigated with respect to headspace-solid phase microextraction (HS-SPME) method. In order to induce the elution of aqueous TMA to headspace, NaOH was added as a decomposition reagent to aqueous TMA standard. By controlling the combination of three major variables for TMA extraction, the extent of extraction was compared between the two contrasting conditions for each variable (i.e., reaction time (long (L) vs short (S)), exposure temperature (30 vs $50^{\circ}C$), and exposure time (10 vs 30 min)). The results of this comparative analysis showed that the extraction efficiency for all eight types of HS-SPME combinations decreased on the order: L-30-30>L-50-10>L-30-10>L-50-30>S-30-30>S-50-30>S-50-10>S-30-10. The effect of reaction time appeared to exert significant influences on the relative recovery rate of HS-SPME at 90% confidence level. However, the effects of exposure temperature or exposure time were not so significant as reaction time. When the recovery rate of HS-SPME is compared against the direct injection of liquid standard into GC injector, it recorded as 2%. According to this comparative study, the reaction conditions for HS-SPME application can exert significant influences on the analysis of TMA.