• Title/Summary/Keyword: Direct Synthesis

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Direct Synthesis of Dimethyl Ether from Synthesis Gas (합성가스로부터 디메틸에테르 직접 합성)

  • Hahm, Hyun-Sik;Kim, Song-Hyoung;Kang, Young-Gu;Shin, Ki-Seok;Ahn, Sung-Hwan
    • Journal of the Korean Institute of Gas
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    • v.13 no.4
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    • pp.8-14
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    • 2009
  • Dimethyl ether(DME) was synthesized from synthesis gas by a one-step process in which a hybrid catalyst was used. The hybrid catalyst consisted of Cu-ZnO-$Al_2O_3$ for the methanol synthesis reaction and aluminum phosphate or $H_3PO_4$-modified $\gamma$-alumina for the methanol dehydration reaction. The prepared catalysts were characterized by XRD, BET, SEM, FT-IR and $NH_3$-TPD. From the XRD analysis, it was verified that the aluminum phosphate was successfully synthesized. The specific surface areas of the synthesized aluminum phosphates were varied with the ratio of P/Al. The hybrid catalyst in which P/Al ratio of the aluminum phosphate was 1.2 showed the highest CO conversion of 55% and DME selectivity of 70%. There was no remarkable decrease in catalytic activity with the phosphoric acid treatment of $\gamma$-alumina. However, when treated with concentrated phosphoric acid(85%), the catalytic activity and DME selectivity decreased.

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Enviroment-Friendly Synthesis of Nanocrystalline Nickel Oxide and Its Antibacterial Properties (폐과일껍질을 이용한 친환경 NiO 나노분말 합성 및 향균특성 연구)

  • Yuvakkumar, R.;Song, Jae Sook;Hong, Sun Ig
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.24-31
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    • 2018
  • This study reports an environment-friendly synthetic strategy to process nickel oxide nanocrystals. A mesoporous nickel oxide nanostructure was synthesized using an environmentally benign biomimetic method. We used a natural rambutan peel waste resource as a raw material to ligate nickel ions to form nickel-ellagate complexes. The direct decomposition of the obtained complexes at $700^{\circ}C$, $900^{\circ}C$ and $1100^{\circ}C$ in a static air atmosphere resulted in mesoporous nickel oxide nanostructures. The formation of columnar mesoporous NiO with a concentric stacked doughnuts architecture was purely dependent on the suitable direct decomposition temperature at $1100^{\circ}C$ when the synthesis was carried out. The prepared NiO nanocrystals were coated on cotton fabric and their antibacterial activity was also analyzed. The NiO nanoparticle-treated cotton fabric exhibited good antibacterial and wash durability performance.

Cyber Character Implementation with Recognition and Synthesis of Speech/lmage (음성/영상의 인식 및 합성 기능을 갖는 가상캐릭터 구현)

  • Choe, Gwang-Pyo;Lee, Du-Seong;Hong, Gwang-Seok
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.37 no.5
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    • pp.54-63
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    • 2000
  • In this paper, we implemented cyber character that can do speech recognition, speech synthesis, Motion tracking and 3D animation. For speech recognition, we used Discrete-HMM algorithm with K-means 128 level vector quantization and MFCC feature vector. For speech synthesis, we used demi-syllables TD-PSOLA algorithm. For PC based Motion tracking, we present Fast Optical Flow like Method. And for animating 3D model, we used vertex interpolation with DirectSD retained mode. Finally, we implemented cyber character integrated above systems, which game calculating by the multiplication table with user and the cyber character always look at user using of Motion tracking system.

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Synthesis of direct-patternable ZnO film incorporating Pt Nanoparticles

  • Choi, Yong-June;Park, Hyeong-Ho;Reddy, A.Sivasankar;Park, Hyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.369-369
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    • 2007
  • ZnO film has been investigated during several decades because it has excellent optical property like a transmittance among the range of visible light for using transparent conducting oxide (TCO) films. But ZnO film has not enough conductivity for applying to TCO devices. Therefore we synthesized platinum nanoparticles and they incorporated into ZnO due to improve the electrical property of ZnO film by sol-gel synthesis method. Also, we fabricated photosensitive ZnO thin film containing Pt nanoparticles by sol-gel process and spin-coating for using photochemical solution deposition. Photosensitive ZnO film could carry out the direct-pattern which allow the etching process to be convenient. The optical and electrical properties of ZnO film with or without various atomic percent of Pt nanoparticles annealed at various temperatures were investigated by using UV-Vis spectroscopy and 4-point probe method, respectively. We characterized the ZnO thin film containing Pt nanoparticles using X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy.

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Direct synthesis of Neu5Ac from GlcNAc using NALasc and GlcNAc 2-epimerase

  • Lee, Jeong-Gyu;Lee, Jeong-O;Lee, Seon-Gu;Kim, Byeong-Gi
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.210-214
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    • 2001
  • GlcNAc 2-epimerase gene from human was cloned. However GIcNAc 2-epimerase was expressed in E. coli as inclusion body formation. Several approaches were tried such as expression in low temperature and low concentration of IPTG. With these treatments production of active form of human GIcNAc 2-epimerase ι ,vas enhanced. For the direct synthesis of NeuAc from GlcNAc and pyruvate, NALase and GlcNAc 2-epimerase were characterized in terms of temperature effect on activity. equilibrium and stability, inhibition by pyruvate etc. For cheap and ease preparation of both the NALase and GlcNAc 2-epimerase, pEN24ma vector was made. which express both the NALasc and GIcNAc 2-epimerase simultaneously. In addition, E. coli BL21(DE3) harboring two plasmids was also made. Of the two systems, the latter was better for the expression of both enzymes.

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