• 제목/요약/키워드: Dipolar

검색결과 183건 처리시간 0.012초

1,3-Dipolar cycloaddition 반응을 통해 기능화된 carbon nanotube 표면 위에 균일계 촉매 담지 및 에틸렌 중합 (Immobilization of Homogeneous Catalyst on Functionalized Carbon Nanotube via 1,3-Dipolar Cycloaddition Reaction and its Ethylene Polymerization)

  • 이정숙;이세영;이진우;고영수
    • Korean Chemical Engineering Research
    • /
    • 제54권4호
    • /
    • pp.574-581
    • /
    • 2016
  • 본 연구에서는 탄소나노튜브에 다양한 아미노산과 알데히드의 1,3-dipolar cycloaddition 반응을 통해 pyrrolidine 고리를 도입하여 기능화된 탄소나노튜브를 합성하였다. 기능화된 탄소나노튜브에 메탈로센 촉매를 담지하였고 in-situ 에틸렌 중합을 통해 탄소나노튜브/폴리에틸렌 복합체를 합성하였다. 글리신과 벤즈알데히드로 기능화된 탄소나노튜브(Gly+BA-CNT)에 담지된 메탈로센 촉매는 낮은 지르코늄 함량에도 불구하고 높은 지르코늄 함량을 나타내는 N-benzyloxycarbonylglycine과 파라포름알데히드로 기능화된 탄소나노튜브(Z-Gly+PFA-CNT)에 담지된 촉매와 유사한 중합 활성을 보였다. N-Benzyloxycarbonylglycine과 파라포름알데히드로 기능화된 탄소나노튜브(Z-Gly+PFA-CNT)에 담지된 메탈로센 촉매의 경우 촉매 활성점의 분포가 조밀하여 에틸렌 중합 시 활성점으로 에틸렌 모노머와 공촉매 MAO가 확산하는데 입체적 방해를 주기 때문이다. 균일계 메탈로센 촉매로 생성된 폴리에틸렌과 비교하여 표면 기능화된 탄소나노튜브에 메탈로센을 담지한 촉매로 생성된 CNT/PE 복합체는 높은 분해 개시 온도($T_{onset}$)와 최대 중량 감소 온도($T_{max}$)를 가진다. 이는 pyrrolidine 고리가 기능화된 CNT는 PE 매트릭스 내에 균일하게 분산되고 CNT와 고분자 간의 강한 상호작용으로 인해 열적 안정성이 향상된 것으로 판단된다.

Synthesis of Perfluorinated Heterocyclic Compounds Having a Long Alkyl Chain Functionality by 1,3-Dipolar Cycloaddition

  • Lee, Chan-Woo;Hwang, Ho-Yun;Park, Joo-Yuen;Chi, Ki-Whan
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권5호
    • /
    • pp.1305-1308
    • /
    • 2010
  • Regioselective perfluorinated isoxazolidine (5 and 7), isoxazoline (9) and 1,2-addition products (6 and 8) having a long alkyl chain functionality have been prepared by 1,3-dipolar cycloaddition between a 1,3-dipole (NH-nitrone or nitrile oxide) and dipolarophile (perfluoro-2-methyl-2-pentene or styrene), respectively. Interestingly, unusual extended conjugated form of isoxazoline adduct (10) was obtained by dehydrofluorinated reaction from the corresponding perfluorinated isoxazoline adduct (9) which was derived from cycloadition between the perfluorinated long alkyl nitrile oxide 1,3-diplole and styrene olefin. This synthetic methodology of heterocyclic compound having a long alkyl chain functionality is useful for the designing of synthetic strategy and potential self-assembled monolayers (SAM) application. These derivatives were characterized by IR, $^1H$ and $^{19}F$ NMR, and MASS analysis.

Regioselective 1,3-Dipolar Cycloaddition and 1,2-Addition between Benzaldoxime NH-nitrone and Perfluoro-2-methyl-2-pentene

  • Lee, Chan-Woo;Park, Joo-Yuen;Kim, Hyun-Uk;Chi, Ki-Whan
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권5호
    • /
    • pp.1172-1176
    • /
    • 2010
  • Regioselective perfluorinated [3+2] cycloadducts and 1,2-adducts have been prepared by 1,3-dipolar cycloaddition between benzaldoxime NH-nitrone and perfluorinated alkene, perfluoro-2-methyl-2-pentene. Although the cycloaddition reaction is carried out at room temperature, the corresponding perfluorinated compounds are effectively produced in a high yield. In particular, the methoxy-substituted adducts (4 and 7a) show the self-assembled structure by intermolecular interactions. These derivatives were characterized by IR, $^1H$ and $^{19}F$ NMR, and the absolute structure of perfluorinated adducts was confirmed by X-ray crystallography.

1-나프틸메틸 할라이드의 할로겐 교환반응 (Kinetic Studies on Halogen Exchange of 1-Naphthyl Methyl Halides)

  • 이계수
    • 대한화학회지
    • /
    • 제13권2호
    • /
    • pp.115-120
    • /
    • 1969
  • 1-naphthyl methyl halide와 halide ion간의 反應을 無水 acetone에서 反應 速度論的으로 연구하였다. Substrate의 softness가 현저하게 增加하면 halide ion의 nuclepphilicity가 dipolar solvent 에서도 一般的으로 $I^->Br^->CI^-$의 순서를 갖는다는 것을 보여주고 있다. Leaving group bromide일 때는 symbiotic effect에 의해서 reaction center의 softness가 증가하여 soft halide ion과의 反應이 커질 것이나 perihydrogen atom의 steric effect때문에 chloride일 때에 비해서 약간 감소하고 있다.

  • PDF

Dielectrophoretic Technique for the Preparation of Density Gradient Polymers Doped with a Dipolar Modifier

  • Woo, Dong-Jin;Mun, Jeong-Min;Lee, Suck-Hyun;Suh, Moon-Ho
    • Macromolecular Research
    • /
    • 제11권6호
    • /
    • pp.467-470
    • /
    • 2003
  • The dielectrophoretic technique was used to prepare density gradient polymers, polystyrene doped with a dipolar modifier, diphenyl sulfide. We have measured concentration gradients of the dopant by UV/Nis spectroscopy as a function of time in a nonuniform electric field. Measured concentration data at different positions of the sample confirmed that a concentration gradient arose after a nonuniform electric field was applied to the system, these data were used to compare the concentration profile with that predicted by the dielectrophoresis equation.

Analyses of Two Different Versions of HETCOR Techniques for Solids

  • Kim, Se-Hun;Han, Doug-Young
    • 한국자기공명학회논문지
    • /
    • 제12권2호
    • /
    • pp.81-88
    • /
    • 2008
  • Solid HETCOR (Hetero-Correlation) requires homo-dipolar decoupling between proton spins during the evolution and the mixing period in 2D-NMR. There are two different ways of achieving it with pulse sequences. One is based on the multiple pulse (MP) sequence where thousands of intense radio frequency (rf) pulses are used to remove the homo-dipolar interaction between protons. The other is utilizing the so-called Lee-Goldburg (LG) off-resonance scheme where a continuous rf-irradiation is used. In this report, the advantage of one technique to the other, is analyzed. LG version is evaluated better in S/N and easier in setup procedure with the same experimental time.

Cooperative Spontaneous Emission from Nanocrystals to a Surface Plasmon Polariton in a Metallic Nanowire

  • Lee, Joong-Hag;Hong, Suc-Kyoung;Nam, Seog-Woo;Kim, Seog-Seong
    • Journal of the Optical Society of Korea
    • /
    • 제15권4호
    • /
    • pp.407-414
    • /
    • 2011
  • We analyze the cooperative spontaneous emission of optically excited nanocrystals into surface plasmon polaritons propagating on the surface of a cylindrical metallic nanowire. The spontaneous emission probability of the nanocrystals is obtained by perturbative expansions with and without dipole-dipole interaction among nanocrystals in order to see the cooperative effects. The spontaneous emission probability depends on the radial and axial distributions, as well as on the dipolar orientation of nanocrystals. It is shown that the spontaneous emission probability is strongly influenced by dipole-dipole interaction, axial distribution, and dipolar orientation of nanocrystals for closely spaced nanocrystals.

Novel Synthesis of Hydrophilic Dipolar Chromophores using Dendronized Sulfonates

  • Kim, Mi-Rae;Maheswara, Muchchintala;Do, Jung-Yun
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권2호
    • /
    • pp.664-672
    • /
    • 2011
  • A series of hydrophilic chromophores was synthesized through introduction of dendritic sulfonate anions using click chemistry. A dendron structure bearing several sulfonate groups enhances hydrophilicity of attached chromophores. A click triazole formation connects chromophores with hydrophilic groups. A neutral trichloroethyl sulfonate has versatile features such as easy introduction, chemical endurance for isolation or storage, and convenient transformation to a hydrophilic anion. Zinc and OH mediated cleavage of trichloroethyl group from the neutral sulfonate undergoes to generate a water-soluble sulfonate anion. The solubility was examined with different counter cations and in different pH media and thus increased with the number of attached sulfonate ion. Two hydrophilic chromophores of stilbene-derived and azobenzene-derived dipolar structures exhibit clear negative and positive solvatochromism in protic solvents, respectively.

LB 초박막의 전압발생 (Generation of Open Circuit Voltage in LB Ultra Thin Films)

  • 권영수;강도열
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
    • /
    • pp.796-798
    • /
    • 1988
  • Langmuir-Blodgett(LB) films of arachic acid and TCNQ(tetracyanoquinodimethane) were prepared in the sample of Al/LB film/Al type where Al are electrodes, and polarization in LB film and dipolar moment of molecules in the films were measured by themally stimulated current(TSC). It is ascertaind in our experiments that dipolar mament of $C_{12}$TCNQ molecule was about 13-15 debye and the moment was directed from the alkyle chain toward TCNQ. Generation of the open circuit voltage was investigated on the z-type and Hetero structure of LB films.

  • PDF

VDCN계 공중합체의 비선형 유전 특성 (Nonlinear Dielectric Properties of VDCN Copolymers)

  • 강대하;박상호
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제51권7호
    • /
    • pp.279-286
    • /
    • 2002
  • Linear and nonlinear complex permittivities were measured for copolymers of vinylidene cyanide(VDCN) with vinyl acetate(VAc), vinyl propionate(VPr), vinyl bezoate(VBz), styrene(St) and methyl methacrylate(MMA). Experimental results are well fitted by the function (equation omitted) except at low frequency where dc conduction dominates. The analysis of dielectric relaxation mechanism by combined knowledge about linear and nonlinear dielectric permittivities and dipoles give us informations about electrical and thermal motions in these copolymers. According to the analysis it could be found that the variation for temperature of the dielectric relaxation strength in these copolymers is related to the interaction between dipoles and the nonlinear dielectric effect factor R$_{s}$ is proportional to square of the dipolar correlation factor R$_{p}$././.