• 제목/요약/키워드: Diketo-pyrrolo-pyrrole (DPP)

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1,4-Diketopyrrolo-(3,4c)pyrrole계 고내구성 안료의 합성법 연구 및 유도체 합성 (Synthesis of weather fast 1,4-Diketo-pyrrolo(3,4c)-pyrrole and its derivatives)

  • Song, Hanchul;Lee, Soojong
    • 한국염색가공학회지
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    • 제9권1호
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    • pp.44-49
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    • 1997
  • Recent investigation and developments of A. Iqbal on diketo-pyrrolo-pyrrole (DPP) pigments has prompted us to synthesize and close observation of a few properties of these molecules. Described are synthesis, via 1-phenyl-2-ethoxycarbonyl-5-pyrrolinone intermediate, of asymmetric derivatives such as 1,4-Diketo-3-(4-chlorophenyl)-6-phenyl-pyrrolo-(3,4c)-pyrrole (4), 1,4-Diketo-3-(4-bromophenyl)-6-phenybpyrrolo-(3,4c)-pyrrole (5), 1,4-Diketo-3-(3-cyanophenyl)-6-phenyl-pyrrolo-(3,4c)-pyrrole (6), 1,4-Diketo-3-(4-cyanophenyl)-6-phenyl-pyrrolo-(3,4c)-pyrrole (7), 1,4-Diketo-3-(4-pyridyl)-6-phenyt-pyrrolo-(3,4c)-pyrrole (8), 1,4-Diketo-3-(3-pyridyl)-6-phenyl-pyrrolo-(3,4c)-pyrrole (9), 1,4-Diketo-3-(2-pyridyl)-6-phenyl-pyrrolo-(3,4c)-pyrrole (10), 1,4-Diketo-3-($\beta$-naphthyl)-6-phenyl-pyrrolo-(3,4c)-pyrrole (11), and UV-Vis absorption spectrum of the above compounds. Results from calculation of their absorption maxima using PISYSTEM are also described.

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고기능 EL소자용 고분자/유기 재료의 합성 및 전기 광학적 특성 I. 색소 도핑에 의한 EL소자의 특성 (( Syntheses of Improved Polymer/Organic Materials for Electroluminescence(EL) Device and Electro-Optical Characteristics I. Properties of Dye Doped Organic EL Device)

  • 김성훈
    • 한국인쇄학회지
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    • 제13권2호
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    • pp.33-45
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    • 1995
  • 1, 4-Diketo-3, 6-diphenyl-pyrrolo-[3, 4c]-pyrrole(abbriviated DPP) is a new heterocyclic pigment of red color whose chlorinated derivative is now on the market. DDP was synthesized from benzonitrile and diethylsuccinate. Pariser-parr-pople(PPP) molecular orbital calculations have been carried out on the DPP in other to study spectroscopically the DPP chromophore on deprotonation.

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1,4-Diketo-3,6-Diphenyl-Pyrrolo-[3,4c]-Pyrrole(DPP)계 유기안료의 합성 및 흡수스펙트라 (Synthesis and Absorption Spectra of 1,4-Diketo-3,6-Diphenyl-Pyrrolo-[3,4c]-Pyrrole)

  • 김성훈
    • 한국인쇄학회지
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    • 제14권1호
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    • pp.1-15
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    • 1996
  • In this paper, the preparation of lead zirconium titanate(PZT) thin film by sol-gel processing was descried. Thin film coated with thickness of 4${\mu}{\textrm}{m}$ on the stainless steel substrates using the multiple spin-coating process. The crystalline phases of PZT powder and film were investigated by X-ray diffraction pattern and PZT thin film has perovskite structure over 600 C annealing temperature. Corona charging characteristics of the ferroelectric PZT thin film at 600 C were investigated by electrophotographic measurement. A difference in the charging characteristics between positive and negative corona charging was found. The charge acceptance depended in the polarity of corona and the poling of film. According to the D-E hysteresis measurment, PZT thin film can be poled by corona charging without use of top electrode. The remnant polarization in the PZT thin film is generally in the order of 48$\mu$C/$\textrm{cm}^2$. From this results, the ferroelectric PZT thin film will be possible to apply for the add-on type imaging formation.

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