• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.11 no.1
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• pp.48-55
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• 2001

The purpose of this study was to evaluate the analytical accuracy and precision of microwave oven digestion/atomi absorption spectrophotometry (AAS) for analyzing airborne chromium collected on mixed cellulose ester membrane (M filter from the work environment, and to compare the accuracy and the precision with those of the National Institute for Occupational Safety and Health (NIOSH) Method #7024 hot plate digestion/AAS method. For this study, field air sample pairs were collected from a electroplating process, and spiked samples in a laboratory were prepared and using these samples. Two digestion methods were comp; and evaluated in terms of recovery rate and bias as indices of accuracy and coefficient of variation as a index of precision. The results and conclusions are as follows. In spiked samples, the accuracies (% mean recoveries) of hot plate/AAS and microwave oven/AAS method were 97.19%, 97.1%, respectively, and the precisions (pooled respectively, and the precisions (pooled coefficient of variance, $CV_{pooled}$) 6.93% and 3.88%, respectively. The biases of hot plate ani microwave oven methods were 4.56 - 14.7% and 2.22 - 7.42% respectively. There was no statistically significant difference between hot plate and microwave oven methods recovery rates of spiked samples (p>0,05). Also, no statistically significant difference was shown among the concentrations of air samples determined by two method (p>0.05). In conclusion, microwave oven/AAS method h excellent accuracy and precision, and advantages such as time-saving and simple procedure in comparison with the classical NIOSH method. Therefore, this method can be use widely to analyze airborne chromium collected on MCE filter from the work environments.

• Journal of Soil and Groundwater Environment
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• v.6 no.1
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• pp.63-83
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• 2001

Heavy metals are extracted from stream sediments, roadside soils and sediments and soils and tailings from mining area using partial extraction, acid digestion and HF-digestion. Compared to amounts of heavy metals extracted using partial extraction, those extracted using acid digestion are higher by 2.0∼221 times in Cu, 2.4∼2806 times in Pb, 1.3∼121 times in Cd, 14. 1∼1300885 times in Fe, 1.2∼272 times in Mn, 1.3∼373 times in Zn, 2.2∼1735 times in Cr. There is no special relationship between the extracted amounts of heavy metals using partial extraction and those using acid digestion. However, it is possible that there is a certain relationship between those using acid digestion and those using HF-digestion. Although partial extraction, which extracts less amounts of heavy metals (Cd, Cu, Pb) from soil compared to acid digestion, is used in domestic standard method for examination of soil, domestic soil standard for heavy metals in non-agricultural and industrial areas is higher than soil standard in foreign countries which use acid digestion. For improvement of the domestic standard method for assessment of soil, it is suggested to lower the domestic soil standard for heavy metals or to change pretreatment method for extracting heavy metals from partial extraction to acid digestion with modifying the soil standard.

• Analytical Science and Technology
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• v.14 no.4
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• pp.324-330
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• 2001

For the analysis of S, P and Zn in lubricating oil, microwave digestion method was studied by using inductively coupled plasma-atomic emission spectrometry(ICP-AES). Lubricating oil was completely decomposed with nitric acid or a mixture of nitric acid and hydrogen peroxide using and closed microwave digestion system. Digestions are completed within 50 min, a factor of at least 3~4 times faster than for the conventional digestion. A gradual heating program operated by the pulsed mode was found suitable for decomposing the lubricating oil matrix safely. The proposed method of digestion gave relative standard deviations(RSD) less than 3% for the elements determined.

• Journal of Radiation Protection and Research
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• v.37 no.4
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• pp.213-218
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• 2012

Alpha spectrometry has been typically used for determination of the uranium isotopes in soil. For a number of uranium analysis in soil samples, rapid sample digestion with limited quantities of mixed acid containing HF will give a contribution for effective management of uranium analysis. Microwave digestion system is evaluated for rapid sample digestion using reference uranium soil (IAEA-375 soil). For completion of 0.5 g of soil digestion by microwave, 3 ml of HF in a 10 ml of mixed acid is minimum requirement volume for completed soil digestion for 80 minutes. Microwave digestion is timely effective techniques for uranium measurement using alpha spectrometry compared to the other methods (open vessel digestion, closed vessel digestion) due to rapid sample digestion. In addition, it can be reduced the occurrence of hazardous substances by minimizing the amount of HF.

• Journal of Environmental Science International
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• v.10 no.1
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• pp.13-19
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• 2001

An on-line digestion system based on the flow injection analysis technique was presented for the determination of total phosphorus. The system converts condensed and organic phosphoruses into orthophosphate that can be analyzed spectrophotometically. The reaction between orthophosphate and ammonium molybdate in a strong acid medium forms the yellow complex of phosphomolybdate which is next reduced to a molybdic blue complex by stannous chloride. The quantitation of orthophosphate is based on the absorbance of the molybdic blue. To determine total phosphorus, the digestion system was installed between the sample injector and the reaction coil with the added lines of digestion solution(potassium persulfate+sulfuric acid) and the $H_2O$ carrier. The system has shown that the digestion efficiencies were greater than 95% for the typical condensed and organic phosphoruses. When tripolyphosphate standards were used, the calibration data showed that the linear dynamic range extended to a concentration of 1.5ppm with the detection limit of 25ppb total phosphorus. The typical relative standard deviation was less than 2%. The proposed system was successfully applied to lake water, wastewater, and streamwater. The analytical variables such as digestion efficiency, analysis time, and reproducibility were evaluated and compared with the manual digestion method.

• Asian-Australasian Journal of Animal Sciences
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• v.21 no.10
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• pp.1522-1528
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• 2008

The objective of this study was to develop a model for simulating gastric digestion in the pig. The model was constructed to include the chemical and physical changes associated with gastric digestion such as enzyme release, digestion product removal and gastric emptying. Digesta was collected from the stomach cannula of pigs to establish system parameters and to document the ability of the model to simulate gastric digestion. The results showed that the average pH of gastric digesta increased significantly from 2.47 to 4.97 after feed consumption and then decreased 140 min postprandial. The model described the decrease in pH within the pigs' stomach as $pH_t=5.182e^{-0.0014t}$, where t represents the postprandial time in minutes. The cumulative distribution function of liquid digesta was $V_t=64.509e^{0.0109t}$. The average pepsin activity in the liquid digesta was 317Anson units/mL. There was significant gastric emptying 220 min after feed consumption. The cybernetic dynamic system of gastric digestion was set according to the above data in order to compare with in vivo changes. The time course of crude protein digestion predicted by the model was highly correlated with observed in vivo digestion (r = 0.97; p = 0.0001), Model prediction for protein digestion was higher than that observed for a traditional static in vitro method (r = 0.89; p = 0.0001).

• Asian-Australasian Journal of Animal Sciences
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• v.2 no.3
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• pp.404-406
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• 1989

• Journal of Korean Society of Water and Wastewater
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• v.31 no.1
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• pp.13-19
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• 2017

Relatively low efficiency in anaerobic digestion process is mainly caused by unproper mixing method. In this study, tray motion type agitator was applied in actual anaerobic digestion tank in order to improve the digestion efficiency, equalize the flow velocity distribution and energy saving. The impeller of tray motion type agitator was reciprocated vertically. Gas lift type agitator and tray motion type agitator appears almost same mixing efficiency include digestion rates. However, tray motion type agitator have shown that lower energy consumption compared to the conventional gas lift type agitator. Implementation of tray motion type agitator in the anaerobic digestion tanks contributed to the stabilization of mixing environment, efficiency and energy efficiency of the tank.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.1
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• pp.65-73
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• 2011

The fibrous raw materials in packaging-grade paper production in Korea were mainly obtained from waste paper. The use of recycled paper has both positive and negative impacts in papermaking process. The primary positive impacts are the environmental protection and manufacturing cost reduction, and the negative impacts are the quality reduction in paper quality and the accumulation of heavy metals and other pollutants in wet- and dry-end process. This study was carried out to consider the optimum acid decomposition system with the highest recovery rate for the analysis of heavy metals in packaging-grade paper. The open digestion system using Kjeldahl apparatus and the closed digestion system using microwave oven for decomposing the organic materials in paper were compared. In both open and closed digestion method, the combination of nitric acid, hydrochloric acid and hydrogen peroxide showed higher recovery rate than using only nitric acid alone because the presence of Cl- ions in hydrochloric acid stabilizes ligand formation with metal ions. KOCC was observed to have the highest heavy metal content among the recycled paper samples. The heavy metal contents decomposed with the closed digestion system were relatively higher than with open digestion system.

• Journal of Korea Society of Waste Management
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• v.35 no.8
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• pp.731-743
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• 2018

This study was performed to test the feasibility of thermophilic ($55^{\circ}$) co-digestion of municipal sewage sludge and food wastes. The management variables of co-digestion were the mixed ratios of municipal sewage sludge and food waste hydraulic retention times (HRTs). During the operation of thermophilic co-digestion, the reactor pH ranged from 7.0 to 7.5 and the reactor alkalinity remained above 3,200 to 4,000 mg/L as $CaCO_3$. The volatile fatty acids concentration increased as the HRT shortened from 20 days to 10 days and the mixture ratio increased to 1:4, but did not reach toxic levels for co-digestion of sewage sludge and food wastes. Methane productivity increased gradually as the organic loading rate increased. Maximum methane productivity reached 1.03v/v-d at an HRT of 10 days and at the mixture ratio of 1:4. The TVS removal efficiency decreased from 70.6% to 58.3% as the HRT shortened from 20 days to 10 days. TVS removal efficiency ranged from 57.0% to 77% during the entire operation. It is likely that thermophilic co-digestion of sewage sludge and food wastes is a very effective method both to environmentally treat food waste and to economically produce gas for energy.