• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.11
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• pp.4664-4670
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• 2010

Comparison of the classical mobile-immobile zone (MIM) model to the derived model led to several conclusions. If the MIM model is to be applied, the initial concentration in the immobile zone has to be down-scaled by a correction factor that is a function of pore geometry. The MIM model was valid only after sufficiently long time has passed, i.e., only after the diffusion front reaches the deepest pore wall in the immobile zone. The MIM mass-transfer coefficient $\alpha$, was inversely proportional to the square of the pore depth. Also it did not depend on the mobile-zone flow velocity, contrary to the number of laboratory and field observations. The classical MIM model displayed a rapid exponential decay of immobile-zone concentration. Meanwhile at large times, the newly derived model displayed similar exponential decay. This was contrary to the mounting evidence of power-law BTC tails observed in laboratory and field settings.

• Journal of the Korean Society of Combustion
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• v.7 no.4
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• pp.1-9
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• 2002

The morphology of deposits on $15-{\mu}m$ thin SiC filaments has been investigated with SEM and compared with UV-excited laser induced broadband fluorescences in co-flowing, propane laminar diffusion flames in a reduced oxidizer environment. The homogeneous morphology of droplet-like deposits inner flame zone and the agglomeration of condensed-phase deposits and the transition to soots from grown up droplet-like precursors with approaching the flame surface can be observed in a barely sooting flame. The average size of the mature soots deposited in the luminous flame edge is scarcely dependent on their axial position in a confined flame under reduced oxidizer condition. A double structure of PAH fluorescence is observed in near-extinction flames with further decreasing of oxidizer. A comparison of the PAH fluorescence with the morphologies of deposits indicates that appearance of the "dark" hollow zone is caused by a decreased number density of developed liquid-phase large molecules and the outer weak fluorescence zone is caused by the diffusion of gas-phase small molecules.

• Journal of the Korean Society of Combustion
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• v.7 no.3
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• pp.9-15
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• 2002

Soot generation by combustion process has been investigated with objective of understanding of chemical reaction responsible for its formation in a coaxial laminar propane jet diffusion flame. For the direct photos, as the coflowing air flow rate is reduced, the area of soot luminous zone increases at first, then becomes smaller and smaller, and even disappears. The aspects of soot deposition can be acquired by using nine $15{\mu}m$ thin SiC fibers are positioned horizontally across the flame. Deposited soots on SiC fibers show the soot inception point and growth and soot oxidation zone in a typical propane diffusion. Soot is not generated anymore in a oxidizer deficient conditions of near-extinction and flame is fully occupied by transparent blue flame. It suggests that nonsooting pyroligneous blue reaction is being dominant in a oxidizer deficient ambience. In comparison with luminosities of SiC fibers and flame itself, indirect evidence is found that the process of soot nucleation and growth is endothermic reaction. It is remarkable that there exists two adjacent regions to have antithesis characteristics; one is exothermic reaction of blue flame and another endothermic reaction zone of soot formation.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.12
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• pp.3344-3351
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• 1995

The stability of diffusion flame formed behind a bluff body with fuel injection slits was experimentally investigated in various fuel injection angles, fuel injection ratios, grids and extension ducts. The flame stability limits, temperature distributions and length of recirculation zones, direct photographs of flames were measured in order to discuss the stabilization mechanism of the diffusion flame. The results from this study are as follows. The fuel injection angle is an important factor in determining the flame stability. Stability limits can be improved by variety of the fuel injection ratio. When the grid and extension duct are set, stability characteristics are varied with the blockage ratios, grid intervals, and grid numbers. The recirculation zone not only serves as a steady ignition source of combustion stream but also governs the stabilization mechanism.

• Journal of Korean Vacuum Science & Technology
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• v.4 no.3
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• pp.73-77
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• 2000

Single crystal and polycrystalline Si thin films were doped with phosphorus by a 2-zone diffusion method to develop the low-resistivity polycrystalline Si electrode for a hemispherical grain. Solid phosphorus source was used in order to achieve uniformly and highly doped surface region of polycrystalline Si films having rough surface morphology. In case of 2-zone diffusion method, it is proved that the heavy doping near the surface area can be achieved even at a relatively low temperature. SIMS analysis revealed that phosphorus doping concentration in case of using solid P as a doping source was about 50 times as that of phosphine source at 750$^{\circ}C$. Also, ASR analysis revealed that the carrier concentration was about 50 times as that of phosphine. In order to evaluate the electrical characteristics of doped polycrystalline Si films for semiconductor devices, MOS capacitors were fabricated to measure capacitance of polycrystalline Si films. In ${\pm}$2 V measuring condition, Si films, doped with solid source, have 8% higher $C_{min}$ than that of unadditional doped Si films and 3% higher $C_{min}$ than that of Si films doped with $PH_3$ source. The leakage current of these films was a few fA/${\mu}m^2$. As a result, a 2-zone diffusion method is suggested as an effective method to achieve highly doped polycrystalline Si films even at low temperature.

• Journal of Energy Engineering
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• v.10 no.3
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• pp.223-232
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• 2001

To study the stabilization characteristics of diffusion flame formed in the wake of a cylindrical bluff body with fuel injection, the flame stability limits, length and temperature of recirculation zone of flame, turbulence intensity distribution near the recirculation zone of flame were measured and analyzed. The length of recirculation zone is independent on main fuel injection quantity, but it is dependent on fuel injection angles, air stream velocity, and auxiliary fuel injection into recirculation zone. For diffusion flame, in general, the flame stabilization is deteriorated with increase of he length of recirculation zone, but if the turbulence generator is installed, the flame stabilization is improved with increase of the length of recirculation zone. The temperature of recirculation zone is dependent on fuel injection angles, auxiliary fuel injection into recirculation zone, turbulence generators, and it dependent on fuel injection angles, auxiliary fuel injection into recirculation zone, turbulence generators, and it has a maximum value at the condition of each theoretical mixture. In general, the more temperature of recirculation zone is low, the more flame is stable. But when the turbulence generator is installed, the more temperature of recirculation zone is low, the more flame is unstable. The turbulence intensity in the wake of bluff body is increased with increase of diameter or blockage ratio of grid. The more turbulence intensity is increased by installation of turbulence generator, the more flame is unstable. Finally, It is clear that the stabilization characteristics of diffuser flame can be controlled by some parameters such as fuel injection angles, auxiliary fuel injection into recirculation zone, turbulence generators.

• 한국연소학회:학술대회논문집
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• 1998.10a
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• pp.123-129
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• 1998

A numerical study has been conducted to investigate the effect of shock waves on the mixing and the recirculation zone of a hydrogen jet diffusion flame in a supersonic combustor. The general trends are compared with the experimental results obtained from the supersonic combustor at the University of Michigan. For the numerical simulation of supersonic diffusion flames, multi-species Navier-Stokes equations and detailed chemistry reaction equations of $H_2$-Air are considered. The $K-{\omega}/k-{\varepsilon}$ blended two equation turbulent model is used. Roe's FDS method and MUSCL method are used for convection fluxes in governing equations. Numerical results show that when slender wedges are mounted at the combustor wall the mixing and the combustion are enhanced and the size of recirculation zone is increased . The flame shape of supersonic flames is different in the flame-tip; it is not closed but open. The flame shape is shown to be greatly affected by shock waves.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.2
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• pp.509-518
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• 1995

A study for the flame stability and the combustion characteristics of coaxial diffusion flame was conducted. The fuel employed was natural gas. The experimental variables were rim thickness of fuel tube, blockage ratio of the outer diameter of fuel tube to the inner diameter of air tube, and momentum ratio of fuel to air. It was consequently found that the stability in the neighborhood of the fuel rim depended on the rim thickness, especially in the case of above 3 mm, and that the stable region of the flame extended remarkably due to the formation of recirculation zone above rim. The effect of the blockage ratio on the flame stability was found to be minor in the case of above 3 mm of rim thickness. Between the momentum ratio 2 and 3, the stable flame zone was widely established as well good combustion. With increasing the fuel-air momentum ratio, axial velocity, turbulence intensity, and Reynolds stress increased.

• Journal of Environmental Science International
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• v.11 no.12
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• pp.1321-1326
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• 2002

A numerical model is investigated to predict a behavior of the gaseous volatile organic compounds and a subsurface contamination caused by them in the unsaturated zone. Two dimensional advective-dispersion equation caused by a density difference and two dimensional diffusion equation are computed by a finite difference method in the numerical model. A laboratory experiment is also carried out to compare the results of the numerical model. The dimensions of the experimental plume are 1.2m in length, 0.5m in height, and 0.05m in thickness. In comparing the result of 2 methods used in the numerical model with the one of the experiment respectively, the one of the advective-dispersion equation shows better than the one the diffusion equation.

• Economic and Environmental Geology
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• v.53 no.1
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• pp.99-110
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• 2020

It is a global trend to consider contaminated low-permeability zones as one of the primary management targets for the remediation of DNAPL contaminated sites. In addition, studies on the persistence caused by back diffusion of DNAPLs from low-permeability zones have been actively conducted worldwide. On the other hand, the studies for domestic groundwater contamination with the low-permeability zones are insufficient. Therefore, this study introduces the forward and back diffusions of DNAPL through low-permeability zones and suggests the importance of them by reviewing representative previous studies, especially on back diffusion and plume persistence. We proposed six diffusion scenarios and analytical solutions based on various boundary conditions of low-permeability zones. FI (forward diffusion into infinite domain) and BI (back diffusion form infinite domain) scenarios illustrate forward and back diffusion in which the depths of a low-permeability layer are assumed to be infinite. FFN (forward diffusion into finite domain with no flux boundary) and BFN (back diffusion from finite domain with no flux boundary) scenarios describe forward and back diffusion for a finite domain of a low-permeability layer with no flux boundary at the bottom. When the bottom of a low-permeability layer is considered as flux boundary, forward and back diffusion scenarios correspond to FFF (forward diffusion into finite domain with flux boundary) and BFF (back diffusion from finite domain with flux boundary). The scenarios and analytical solutions in this study may contribute to the determination of an efficient remediation method based on site characteristics such as a thickness of low-permeability zones or duration of contamination exposure.