• Title/Summary/Keyword: Diffusion of $CO_2$

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Experimental Investigation on premixed combustion Characteristics with suction & blow fans (송풍기와 폐풍기를 이용한 연소기내의 부분 예혼합화염 연소 특성에 관한 실험적 연구)

  • Kang, B.K.;Oh, S.H.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.143-148
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    • 2001
  • We measured emission indices for $NO_x$, CO, temperature and radical characteristics for partially premixied flames formed by suction & blow fans air condition. At sufficiently high levels of partial premixing a double flame structure consisting of a rich premixed inner flame and outer diffusion flame was established similar to that previously observed in premixed flames. $NO_x$, Temperature, CO values were experimented with approximately constant air flow rate and decreasing equivalence ratios. The reduction in $NO_x$ and temperature at suction condition as compared with that for blow condition was approximately 20%, but on the contrary, CO emission was increased. In addition, We measured temperature distributions and found that temperature increased continuously with increasing partial premixing. We also estimated CH, $C_2$ radical intensity. CH and $C_2$ radicals provide evidence that, for the present measurement, CH and $C_2$ radicals intensity was associsated with their premixed component. And we observed stronger $C_2$, CH radicals intensity at suction conditions than blow conditions.

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The Effect of Metal-Oxide Coating on the Electrochemical Properties in Thin-Film $LiCoO_2$ Cathodes (금속산화물 코팅을 통한 박막 $LiCoO_2$양극의 전기화학적 특성 향상)

  • 김혜민;김병수;김용정;조재필;박병우
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.124-124
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    • 2003
  • To improve the electrochemical properties of thin-film LiCoO$_2$ cathodes, metal oxides were coated on the LiCoO$_2$ thin films using f sputtering. Galvanostatic charge-discharge experiments showed the enhanced cycling behaviors in the metal-oxide coated LiCoO$_2$ thin films than the uncoated ones. These results are because the metal-oxide coating layer suppresses the degradation of Li-diffusion kinetics during cycling, which is related to the protection of cathode surface from the electrolytes [l-3]. The variation in the metal-oxide coating thickness ranging from 10 to 300 nm did not affect the electrochemical properties. Changes of lattice constants in the coated and bare LiCoO$_2$ thin films at different charged states will also be discussed.

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An Experimental Study on the $CH_4{\;}/{\;}Air{\;}/{\;}CO_2$ Counterflow Diffusion Flame ($CH_4{\;}/{\;}Air{\;}/{\;}CO_2$ 대향류 확산화염에 대한 실험적 연구)

  • Lee, Chong-Won;Lee, Chun-Beom;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2001.06a
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    • pp.31-45
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    • 2001
  • The effect of adding carbon dioxide to methane-air flame was investigated experimentally. Measurements included extinction limits, flame temperature and photographic investigation of flame. A diffusion flame was stabilized between counterflowing streams of methane diluted with carbon dioxide and air diluted with carbon dioxide. Extinction limits and temperature for such flames were measured over a wide parametric range and were compared with those for other flames that fuel or oxidant was diluted with nitrogen or argon. The experimental results indicate that extinction phenomena can be explained by thermal effect and as an amount of carbon dioxide in fuel or oxidant increases, greatly as compared with other flames flame-temperature falls and flame-thickness is reduced.

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The Effects of $CO_2$ on Heat Transfer from Hydrogen Oxygen-enriched Flame (이산화탄소가 수소 산소부화 화염의 열전달에 미치는 영향)

  • Lee, Chang-Yeop;Choi, Joon-Won;Baek, Seung-Wook
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.261-266
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    • 2003
  • An experimental study has been conducted to evaluate the effects of $CO_{2}$ on heat transfer from hydrogen oxygen-enriched flame. Experiments were performed on flames stabilized by a co-flow swirl burner, which mounted on top of the furnace. Five composition conditions of oxidizer were chosen with replacing $N_{2}$ with $CO_{2}$. In a steady state, total and radiative heat flux rates from the flame to the wall of furnace has been measured using heat flux meters. Temperature distribution in furnace also has been checked. Increasing $CO_{2}$ ratio in the oxidizer, the dominant heat transfer mode was changed into convection from radiation. Temperature in the furnace decreased but total heat flux increased.

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Analysis of Soot Formation Characteristics in Diffusion Flames with Soot Particle Temperature Measurement (매연입자 온도 측정에의한 확산화염의 매연생성 특성 해석)

  • Lee, Won-Nam;Chung, Young-Hyun
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.241-249
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    • 1999
  • Soot particle temperatures in co-flow diffusion flames have been measured using a two-color pyrometry at the pressure of 0.2 MPa(2 atm). The measured soot particle temperatures along with the integrated soot volume fractions are analyzed to understand soot formation characteristics. At 0.2 MPa, the addition of small amount of air into ethylene do not change the soot particle temperature in soot formation regions. This result showed that the increase of soot formation with addition of air is mostly due to the chemical effect of the added air, such as the increased role of C3 chemistry during the early stage of soot inception process. The addition of sufficient air into ethylene, however, changes soot particle temperatures and the understanding of soot formation characteristics becomes complicated. Measured soot particle temperatures also showed that there is no significant temperature effect for the synergistic effect of ethylene/propane mixture on soot formation.

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Electrochemical Reduction of High Pressure Carbon Dioxide on Metal Electrodes and Gas Diffusion Electrodes

  • Hara, Kohjiro;Sakata, Tadayoshi
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.683-689
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    • 1995
  • Electrochemical reduction of carbon dioxide under high pressure on Fe electrodes and a gas diffusion electrode containing Pt catalyst (Pt-GDE) had been investigated. Formic acid was formed on Fe electrode with a faradaic efficiency of 60% at a current density of $120mA\;cm^{-2}$ under 30 atm of $CO_2$. Hydrocarbons such as $CH_4$, $C_2H_6$, $C_3H_6$, $1-C_4H_8$, and $n-C_5H_{12}$ are also formed. The distribution of hydrocarbons followed well the Schultz-Flory distribution. $CH_4$ was formed efficiently as the main reduction product on Pt-GDE.

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Blow-off and Combustion Characteristics of a Lifted Coaxial Diffusion Flame (동축 확산 부상화염의 Blow-off와 연소 특성)

  • Kwark, Ji-Hyun;Jun, Chung-Hwan;Jang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1089-1096
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    • 2003
  • An experiment was performed to investigate lift-off, blow-off and combustion characteristics of a lifted coaxial diffusion flame according to fuel jet and air velocity. A jet diffusion flame which is attached on the nozzle rim begins to be lifted with increase of air velocity, and finally becomes blow-off at higher air velocity. In experiment, blow-off limit increased with increase of fuel jet velocity, however lift-off occurred at lower air velocity. Flame structure and combustion characteristics were examined by schlieren photos, temperature distributions and emission concentration distributions. Flame temperature became higher at midstream and its RMS became larger at up and downstream with increase of air velocity. Local NO concentration decreased but $CO_2$concentration increased with increase of air velocity, which shows combustion reaction becomes close to be stoichiometric at higher air velocity in spite of lift-off.

Synthesis of p-Type ZnO Thin Film Prepared by As Diffusion Method and Fabrication of ZnO p-n Homojunction

  • Kim, Deok Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.6
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    • pp.372-375
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    • 2017
  • ZnO thin films were deposited by RF magnetron sputtering and then diffused by using an As source in the ampouletube. Also, the ZnO p-n homojunction was made by using As-doped ZnO thin films, and its properties were analyzed. After the As doping, the surface roughness increased, the crystal quality deteriorated, and the full width at half maximum was increased. The As-doped ZnO thin films showed typical p-type properties, and their resistivity was as low as $2.19{\times}10^{-3}{\Omega}cm$, probably because of the in-diffusion from an external As source and out-diffusion from the GaAs substrate. Also, the ZnO p-n junction displayed the typical rectification properties of a p-n junction. Therefore, the As diffusion method is effective for obtaining ZnO films with p-type properties.

A Inquiry of Tracer Gas for Analysis of Dispersion and Prediction of Infection Possibility according to Airborne Viral Contaminants (건축공간에서 공기 감염균 확산을 해석하기 위한 추적가스 고찰과 농도에 따른 감염 위험성 예측 연구)

  • Lim, Tae-Seob;Kang, Seung-Mo;Kim, Byung-Seon
    • Korean Institute of Interior Design Journal
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    • v.18 no.3
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    • pp.102-113
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    • 2009
  • The SARS virus began to appear and spread in North America and Southeast Asia in the early 2000' s, infecting and harming many people. In the process of examining the causes for the virus, studies on the airborne SARS virus and the way it spread were carried out mainly in the medical field. In the field of architecture, studies were done on the diffusion of air pollutants in buildings using gases such as $CO_2$, $N_2O$, or $SF_6$, but research on virus diffusion was limited. There were also explanations of only the diffusion process without accurate information and discussion on virus characteristics. The aim of this study is to analyze the physical characteristics of airborne virus, consider the possibility of using coupled analysis model and tracer gas for analyzing virus diffusion in building space and, based on reports of how the infection spread in a hospital where SARS patients were discovered, analyze infection risk using tracer gas density and also diffusion patterns according to the location, shape, and volume of supply diffusers and exhaust grilles. This paper can provide standards and logical principles for evaluating various alternatives for making decisions on vertical or horizontal ward placement, air supply and exhaust installation and air volumes in medium or high story medical facilities.

Kinetic Parameter Analysis of Hydrogen Diffusion Reaction for Hydrogen Storage Alloy of Fuel Cell System (연료전지의 수소저장용 합금에 대한 수소확산반응의 속도론적 해석)

  • Kim, Ho-Sung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.2
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    • pp.45-49
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    • 2006
  • Electrochemical hydrogenation/dehydrogenation properties were studied for a single particle of a Mm-based(Mm : minh metal) hydrogen storage alloy($MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$) for fuel cell and Ni-MH batteries. A carbon fiber microelectrode was manipulated to make electrical contact with an alloy particle, and the potential-step experiment was carried out to determine the apparent chemical diffusion coefficient of hydrogen atom($D_{app}$) in the alloy. Since the alloy particle we used here was a dense, conductive sphere, the spherical diffusion model was employed for data analysis. $D_{app}$ was found to vary the order between $10^{-9}\;and\;10^{-10}[cm^2/s]$ over the course of hydrogenation and dehydrogenation process. Compared with the conventional composite film electrodes, the single particle measurements using the microelectrode gave more detailed, true information about the hydrogen storage alloy.