• Title/Summary/Keyword: Diffusion coating

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High temperature properties of surface-modified Hastelloy X alloy (표면처리에 따른 Hastelloy X 합금의 고온물성)

  • Cho, Hyun;Lee, Byeong-Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.4
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    • pp.183-189
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    • 2012
  • Surface treatments and their effects on high temperature properties for the Hastelloy X, which is a promising candidate alloy for high temperature heat-transport system, have been evaluated. For TiAlN and $Al_2O_3$ overlay coatings, the two different PVD (physical vapor deposition) methods using an arc discharge and a sputtering, were applied, respectively. In addition, a different surface treatment method of the diffusion coating by a pack cementation of Al (aluminiding) was also adopted in this study. To achieve enhanced thermal oxidation resistance at $1000^{\circ}C$ by suppressing the inhomogeneous formation of thick $Cr_2O_3$ crust at the surface region, a study for the surface modification methods on the morphological and structural properties of Hastelloy X substrates has been conducted. The structural and compositional properties of each sample were characterized before and after heat-treatment at $1000^{\circ}C$ under air and He environment. The results showed that the Al diffusion coating showed the more enhanced high temperature properties than the overlay coatings such as the suppressed thick $Cr_2O_3$ crust formation and lower wear loss.

Silicon Carbide Coating by Thermal Decomposition of tetramethylsilane

  • YOON Kyung-Hoon
    • Proceedings of the Korean Ceranic Society Conference
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    • 1986.12a
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    • pp.211-225
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    • 1986
  • Silicon carbide coating has been studied using a graphite substrate, a mixture of tetramethylsilane and hydrogen or argon at deposition temperature (T) of 950 to $1200^{\circ}C$ total pressure of 20 to 50 torr and carrier gas flow rate of 0 to 901/h. Deposition kinetic study has shown that a transition, from a surface reaction limited process to a diffusion limited one, takes place near $1100^{\circ}C$. Deposition rate depends directly upon the experimental parameters. The influence of the main process parameters is also discussed to relate the physiochemical properties of the coating to the deposition conditions.

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Chloride Penetration Resistance and UV Properties in Coating Materials Containing Various Slime-Forming Bacteria (슬라임 생성 박테리아를 혼입한 코팅재의 염해 저항성 및 초음파 특성)

  • Kwon, Seung-Jun;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.395-402
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    • 2017
  • Recently, many researches on crack healing and repairing technique using bacteria which can produce vital-reacted calcite have been proposed. This study is for a basic research on repair material with slime formation through bacteria and deals with durability evaluation for coating materials containing bacteria-forming slime. For the work, 4 types of bacteria (Rhodobacter capsulatus, Rhodopseudomonas palustris, Bacillus thuringiensis, and Bacillus subtilis) and 2 types of nutrient conditions are considered, and several tests covering strength evaluation under sulfate condition, accelerated chloride diffusion, and UV (Ultrasonic Velocity) measurement are performed. Strength improvement in coating materials containing bacteria is evaluated in spite of even exposure to sulfate attack to 7 days. Chloride diffusion coefficient and UV properties are also improved except for the case of Rhodopseudomonas palustris. With resistance of slime to long term exposure and aerobic conditions for bacteria longevity, the proposed bacteria shows an engineering feasibility for repair material of RC structure exposed harsh environment.

The Study on Surface Modification of Alumina Membrane by CVD (CVD에 의한 알루미나 멤브레인의 표면개질에 관한 연구)

  • 이동호;최두진;현상훈;고광백
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1349-1356
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    • 1995
  • The change of permeation mechanism from Knudsen diffusion to micropore diffusion was observed after CVD modification of an alumina-sol coated alumina support which was prepared by slip coating process. Permselectivities of He/N2, H2/N2, and CO2/N2 were 5.67, 5.02, and 1.44, respectively. These values were higher than those under Knudsen diffusion controlled region.

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Evaluation of Diffusion on Cement Mortar and Durability of Concrete Specimen Using Inorganic Coating Material and Surface Treatment System (무기질 도료 및 표면처리 시스템을 적용한 시멘트 모르타르와 콘크리트의 내구성 평가)

  • Kim, In-Seob;Lee, Jong-Kyu;Chu, Yong-Sik;Kim, Tae-Hyun;Shim, Kwang-Bo
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.522-528
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    • 2003
  • Concrete has been considered as a semi-permanent structural material, because its excellent durability. However, such high durable structure is often attacked by some environmental condition such as chloride diffusion, carbonation and so on. In order to prevent the deterioration behaviors of concrete structures. We estimated durability of concrete when used surface treatment system and coatings by new type inorganic coating materials. Base on the results of chloride ion's diffusion test, the coated cement mortar had smaller transmitted quantity.

A Comprehensive Analysis of the Influence of Oxygen Diffusion on Concrete Cracks Triggered by Reinforcement Corrosion (철근 부식으로 인한 콘크리트 균열발생에 산소확산성의 영향에 대한 해석적 연구)

  • Nam, Min-Seok;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.2
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    • pp.123-131
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    • 2023
  • In this study, the analysis of concrete cracks was conducted with a total of three variables: coating thickness, oxygen diffusion rate, and reinforced diameter of reinforced concrete structures. Cracks occurred after about 3, 4, and 6 years at the coating thickness of 30, 40, and 50mm when the coating thickness was used as a variable, and cracks occurred after about 4, 5, and 10 years at oxygen diffusivity of 2e-9, 2e-11, and 2e-12(m2/s) when the oxygen diffusion rate was used as a variable. In the case of reinforcing bar diameters, cracks occurred after about 4, 3, and 2 years on the reinforcing bar diameters of D10, D19, and D25.

Microstructures and Cyclic Oxidation Resistance of Aluminide Coatings for Inconel 600 (Inconel 600에 있어서 Al抗散浸透 被覆層의 微細組織과 耐反復酸化性)

  • Chung, In-Sang;Byun, Chang-Suk
    • Journal of the Korean institute of surface engineering
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    • v.20 no.2
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    • pp.60-73
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    • 1987
  • For the purpose of improving the cyclic oxidation resistance of Ni-base superalloy, Inconel 600, aluminide coating methods are studied. The formation rate of aluminide coating layers is measured as a function of time and pack composition to find out the optimum coating condition. The evaluation of cyclic oxidation is established by the change in weight, the microphotography and EPMA of cross sectional area during $200^{\circ}C\;{\leftrightarrow}\;950^{\circ}C\;and\;200^{\circ}C\;{\leftrightarrow}\;1100^{\circ}C$, respectively. The thickness of coating layer and weight gains are parabolic behavior in propotion to time and Al contents. In pack of low aluminum contents, 2 wt%, however, weight gain is decreased when activator, $NH_4Cl$ is higher than 2 wt%. The cyclic oxidation resistance of the coating carried out at 1100$^{\circ}C$ are superior to those of the coating diffusion-treated after pack cementation at 800$^{\circ}C$. Aluminide oxide, which is formed in external scale, is barrier to the cyclic oxidation.

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Effects of hairline treatment on surface blackening and thermal diffusion of Zn-Al-Mg alloy-coated steel sheet (Zn-Al-Mg 합금도금강판의 헤어라인 처리가 표면흑색화 및 열확산도에 미치는 영향)

  • Jin Sung Park;Duck Bin Yun;Sang Heon Kim;Tae Yeob Kim;Sung Jin Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.1
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    • pp.69-76
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    • 2023
  • The effects of hairline treatment on surface blackening and thermal diffusion behaviors of Zn-Al-Mg alloy coated steel sheet were evaluated by the three-dimensional surface profiler and laser-flash technique. The metallographic observation of coating damages by hairline treatments showed that several cracks were initiated and propagated along the interface between primary Zn/eutectic phases. As the hairline processing became more severe, the crack occurrence frequency in eutectic phase of coating layer and the surface roughness increased, which had a proportional relationship with the level of blackening on the coating surface. In addition, the higher interfacial areas of the blackened coating surface, caused by the hairline process, led to an increase in thermal diffusivity and conductivity of the coated steel sheet. On the other hand, when the coating damage by hairline treatment was excessive and the steel substrate was exposed, there was little difference between the thermal diffusivity/conductivity of the untreated sample though the blackening degree was higher than that of untreated sample. This work suggests that the increase in the surface areas of the coating layer without exposure to steel substrate through hairline treatment can be one of the effective technical strategies for the development of Zn-Al-Mg alloy coated steel sheets with higher blackening level and thermal diffusivity.

New Fabrication Method of $Ti:LiNbO_3$ Waveguide with Suppressed Out-Diffusion ($Li_2O$의 삼출이 없는 $LiNbO_3$ 광도파로의 제조방법)

  • 김상혁;김상국;조재철;최상삼
    • Korean Journal of Optics and Photonics
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    • v.2 no.3
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    • pp.149-152
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    • 1991
  • We report a new method of fabricating a Ti:LiNb03 waveguide with no out-diffusion by coating the waveguide with $SiO_2$ thin film. It was coated before diffusion process, and the $LiO_2$ out-diffusion was prevented in the diffusion process. We compare the near field patterns of the guided modes between the typical waveguide and the waveguide fabricated by new method proposed here.

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